跳到主要內容

臺灣博碩士論文加值系統

(216.73.216.66) 您好!臺灣時間:2026/08/16 12:41
字體大小: 字級放大   字級縮小   預設字形  
回查詢結果 :::

詳目顯示

我願授權國圖
: 
twitterline
研究生:沈育任
研究生(外文):Yu-Ran Shan
論文名稱:丙二醇甲醚與臭氧反應之探討
論文名稱(外文):The study of reaction of propylene glycol methyl ether with ozone
指導教授:黃美利黃美利引用關係
指導教授(外文):Mei-Lee Hwang
學位類別:碩士
校院名稱:義守大學
系所名稱:化學工程學系暨生物技術與化學工程研究所
學門:工程學門
學類:化學工程學類
論文種類:學術論文
論文出版年:2018
畢業學年度:106
語文別:中文
論文頁數:82
中文關鍵詞:丙二醇甲醚臭氧沸石
外文關鍵詞:PGMEozonezeolite
相關次數:
  • 被引用被引用:1
  • 點閱點閱:338
  • 評分評分:
  • 下載下載:0
  • 收藏至我的研究室書目清單書目收藏:0
本研究是利用臭氧高氧化力與ZSM-5沸石的吸附能力來降解丙二醇甲醚,探討丙二醇甲醚氧化後的中間產物及產物,以了解可能的反應機制。O3通入PGME樣品在不同時間後,IR圖上發現C=O振動吸收波峰,分析比對GC/MS圖譜推測產物為CO2、乙醛、甲酸甲酯、異丙醇、丙烯酸、丙二醇、乙酸甲酯及乳酸甲酯。臭氧與Air/PGME混合氣體通過30℃~50℃的沸石,顯示50℃沸石得到較佳降解率為58%。出口氣體冷凝液與沸石萃取液之FTIR光譜圖,顯示C=O伸縮振動吸收波峰有明顯的變化,再以GC/MS圖譜分析,偵測到新的產物為1-甲氧基乙醇。比對O3與PGME反應可能路徑之產物,推測臭氧會以氧原子或O3形式參與反應,先形成CH3CH(OH)CH(OH)OCH3,再形成CH(O)OCH3、CH3CH(O)、CH2C(OH)C(O)OH及CH3CH(OH)CH3,再進一步形成CH3CH(OH)CH2(OH)、CH3CH(OH)OCH3、CH3CH(O)OCH3及CH3OH,最後形成CH3CH(OH)C(O)OCH3。
This research was applied the high oxidation of ozone and high absorption capacity of ZSM-5 zeolite to study the degradation of PGME. The identification of reaction intermediate and products were useful to understand the possible mechanism. There were new absorptions of C=O vibrational mode were observed after the ozone passed through PGME sample. Compared with GC/MS spectrum, suggested that the products included carbon dioxide, acetaldehyde, methyl formate, isopropyl alcohol, acrylic acid, propylene glycol, methyl acetate, and methyl lactate. Mixed gas of O3/air/PGME passed through 30 ℃~50 ℃ zeolite, indicated 50 ℃ zeolite would get better degradation (58%). The FTIR spectrum of condensed liquid of output gases and extracted liquid of zeolite shows apparent change of C=O stretching mode, accompanied with the analysis of GC/MS spectrum, newproductdetected was1-methoxyethanol. Compared with the products of possible reaction path, suggested that oxygen atom or ozone was involved in the reaction to form CH3CH(OH)CH(OH)OCH3first, then formed CH(O)OCH3, CH3CH(O), CH2C(OH)C(O)OH, CH3CH(OH)CH3, further formed CH3CH(OH)CH2(OH), CH3CH(OH)OCH3, CH3CH(O)OCH3 and CH3OH, and final product is methyl lactate.
致謝Ⅰ
中文摘要Ⅱ
英文摘要Ⅲ
圖目錄Ⅶ
表目錄Ⅹ
第一章前言1
1-1 揮發性有機物2
1-2 臭氧5
1-2.1 臭氧的物理性質7
1-3 沸石9
1-3.1 沸石的分類及應用10
1-4 文獻回顧14
第二章理論基礎16
2-1 臭氧氧化過程16
2-2 紅外線光譜17
2-2.1 紅外線光譜的特性18
2-2.2 分子振動18
2-2.3 官能基與紅外線光譜19
2-2.4傅立葉轉換型紅外線光譜儀21
2-2.5 定性分析23
2-3 層析法與氣相層析質譜儀25
2-3.1 層析法介紹25
2-3.2 層析法的分類25
2-3.3氣相層析質譜析儀(GC/MS)27
2-3.4氣相層析法的優點27
第三章實驗29
3-1.儀器與藥品29
3-2.實驗步驟30
第四章結果與討論33
4.1 臭氧/PGME反應33
4.1.1 臭氧通入PGME樣品不同時間反應溶液之分析33
4-1.2 O3通入PGME樣品溶液在不同時間的出口氣體冷液收集液之
分析41
4-2 臭氧/PGME通過沸石反應45
4-2.1 臭氧與Air/PGME分別通過沸石之貫穿曲線45
4-2.2 臭氧與Air/PGME混合氣體通過沸石之貫穿曲線48
4-2.3 Air/O3/PGME、Air/PGME與O3分別通過沸石(50 ℃)出口氣體的貫穿曲線49
4-2.4 臭氧/Air/PGME混合氣體通過沸石之IR光譜圖50
4-3 Air/O3/PGME通過沸石的出口氣體冷凝收集液與沸石萃取液之
分析52
4-3.1 Air/O3/PGME通過沸石的出口氣體冷凝液之GC圖譜52
4-3.2 Air/O3/PGME通過沸石後的萃取沸石之萃取液之分析52
4-4 反應機制之探討57
第五章結論63
參考文獻 65
附錄68
[1].林文川,“製程VOCs廢棄之收集與處理”,2009,工業汙染防治,第110期。
[2]. Roberto Andreozzi , “Advanced oxidation processes (AOP) for water purification and recovery”, 1991, Catalysis Today, 53, 51-59.
[3]. Xiang Li, Minghua Zhou, “Highly efficient advanced oxidation processes (AOPs) based on pre-magnetization Fe0 for wastewater treatment” , 2017, Separation and Purification Technology, 178, 49-55.
[4]. J.J. Rueda-Marquez , “Post-treatment of refinery wastewater effluent using a combination of AOPs for possible water reuse comparison of low and medium pressure lamp performance”, 2016, Water Research 91, 86-96.
[5]. L. Bilinska, “Textile wastewater treatment by AOPs for brine reuse”, 2017, Process Safety and Environmental Protection 109, 420-428.
[6]. Huu D Doan, “Biological treatment of wastewater from a polymer coating process”, 2002, Journal of Chemical Technology and Biotechnology 77, 1076-1083.
[7]. Richard D. Stewart MD, “Experimental Human Exposure to Vapor of Propylene Glycol Monomethyl Ether”, Archives of Environmental Health: An International Journal, 20, 1970.
[8].許朝翔,“以粒狀觸媒氧化甲苯之研究”,中山大學,環境工程研究所碩士論文 ,2007,pp 17。
[9].羅卓卿,“油品儲運站鄰近空氣中揮發性有機汙染物之特性研究”,國立中山大學環境工程研究所碩士論文,2001, pp 6。
[10].劉勝男,“消費產品中揮發性有機化合物檢測技術研習報告” ,行政院及所屬各機關出國報告,2010,pp 10。
[11].席勁瑛、武俊良、胡洪營,“工業VOCs排放源廢氣排放特徵調查與分析”,2010,pp 1558-1562。
[12].李汀,“晴空下看不見的健康殺手”,中國科學大氣物理研究所,2015,pp 7。
[13].顧洋,“高級氧化程序在沸水處理上的應用”,工業防治技術水冊,經濟部工業局,1994。
[14]. J. M. Thomas, “Structure and Catalytic performance of Zeolites, Chemistry and Physics of Solid Surfaces VI”, 1986, 115.
[15].Harold Ellis, “Zeolites”, Seminar presentations, 2016, pp 10.
[16].徐榮彬,“沸石的種類、基本特性及應用簡介”,南區水產動物防疫簡訊71,行政院農業委員會家畜農業試驗所,2017,pp 19-22。
[17].Huanhao Chen, Huiping Zhang, Ying Yan, “Fabrication of porous copper/manganese binary oxides modified ZSM-5 membrane catalyst and potential application in the removal of VOCs”, 2014, Chemical Engineering journal 254, 133-142.
[18]. Hirotaka Fujita, “Adsorption and decomposition of water-dissolved ozone on high silica zeolites”, 2004, Water Research 38, 159-165.
[19]. H. D. Doana , A. Weli, J. Wu, “A combined photocatalytic and electrochemical treatment of wastewater containing propylene glycol methyl ether and metal ions”, 2009, Chemical Engineering journal 151, 51-58.
[20]. HichamZaitan, “Application of high silica zeolite ZSM-5 in a hybrid treatment process based on sequential adsorption and ozonation for VOCs elimination”, 2016, Journal of Environmental Sciences 41, 59-68.
[21].張豐堂,“溫變式蜂巢狀沸石轉輪吸附揮發性有機排氣的特性研究”,2005,環境保護學會期刊,28。
[22]. P. Konova, “Catalytic oxidation of VOCs and CO by ozone over alumina supported cobalt oxide”2006, Applied Cataysis A: General 298 109-114.
[23]. J. Liu, R. E. Smalley, “Infrared Spectral Evidence for the Etching of Carbon Nanotubes: Ozone Oxidation at 298K”, 2000, J. Am. Chem. Soc .122, 2383-2384.
[24].司洪濤、呂冠霖、黃香玟,“氧化技術在高濃度COD廢水處理之應用”,中國科學大氣物理研究所,2003,pp 1-21。
[25].劉興鑑、孫逸民、陳玉舜、趙敏勳、謝明學,“儀器分析”,初版,2007,台北,全威圖書有限公司。
[26].鄭新讚,“儀器分析Ⅱ”,2003,台北,全華科技圖書股份有限公司。
[27].劉立行,“儀器分析”,1990,北京,中國石化出版社。
[28].上海物競化工科技有限公司“WinChembase”2009-2017。
[29]. da SilveiraPetruciJF,FortesPR ,“Real-time monitoring of ozone in air using substrate-integrated hollow waveguide mid-infrared sensors”, 2013, Sci Rep, 11, pp 1-4.
[30] Oliver R. Wulf, RichardC. Tolman , “The Thermal Decomposition of Ozone.111.The Temperature Coefficiont of reaction rate”, 1927, Am. Chem. Soc. 49(7), 1650-1664.
[31] YoushimasaTakezaki and Sadayuk Mori, “The Reaction of Oxygen Atoms with Dimethyl Ether”, 1966, Bulletin of the chemical society of japan, 1643-1650.
[32] Philip S. Bailey and Duane A. Lerdal, “Ozonation of Nucleophiles.10.Ethers”, 1978, Journal of the Americam Chemical Society, pp 5820-5825.
QRCODE
 
 
 
 
 
                                                                                                                                                                                                                                                                                                                                                                                                               
第一頁 上一頁 下一頁 最後一頁 top
無相關期刊