臺灣博碩士論文加值系統

This thesis discuss the MnO2 nanomaterials composited zinc ion on nickel foam as cathode electrode in Zinc Ion Battery. The materials fabricated by electrodechemical deposition from aqueouse 1 M Na2SO4 solution and 0.01 M MnSO4 solution as soure of MnO2 and ZnSO4 solution as source of zinc ion on nickel foam substrate. The electrodeposited MnO2 composite zinc (Zn-MnO2) result MnO2 gamma plane. The Zn-MnO2 electrochemical properties has been characterize by using cyclic votammetry and galvanostic charge/discharge analysis on coin cell 2032 type with potential range 1.0-1.8 V. The cyclic voltammograms shows of Zn-MnO2 is higher than pristine MnO2 as cathode on Zinc ion battery. Galvanostatic charge shows specific capacity of Zn-MnO2 ( 77.59 mAh/g) almost three times higher than pristine MnO2 (28.34 mAh/g) at current density 0.05 mA/cm2. The zinc composite improving the electrochemical activity of MnO2 conduce the specific capacity in Zinc Ion Battery. The Zn-MnO2 is a promissing cathode material for used in Zinc ion batteries.

ABSTRACT i
TABLE OF CONTENTS ii
LIST OF FIGURES iv
LIST OF TABLES vi
CHAPTER I INTRODUCTION 1
1.1 Background. 1
CHAPTER II LITERATURE STUDY 3
2.1 Manganesse dioxide 3
2.2 Zinc Ion Batteries 4
2.2.1 Cathode for ZIBs 5
2.2.2 Electrolyte for ZIBs 6
2.2.3 Anode for ZIBs 7
2.3 Nickel Foam 8
2.4 Electrochemical Deposition Method 8
2.5 Zinc Composite 9
CHAPTER III RESEARCH MOTIVATION 11
3.1 Research Motivation 11
CHAPTER IV METHOD AND EXPERIMENTAL SECTION 12
4.1 Method 12
4.2 Materials and Instrument 13
4.2.1 Materials 13
4.2.2 Instruments 13
4.3 Experimental Section 14
4.3.1 Synthesis of MnO2/ Nickel foam 14
4.3.2 Synthesis of Zn-MnO2/ Nickel foam 14
4.3.3 Characterization of Zn-MnO2/ Nickel foam 14
CHAPTER V RESULT AND DISCUSSION 16
5.1 Scaning Electron Microscope (SEM) 16
5.2 X-Ray Diffaction (XRD) 19
5.3 X-Ray Photoelectron Spectroscopy (XPS) 20
5.5 Raman Spectra 23
5.6 Electrochemical properties by Supercapacitor 24
5.7 Electrochemical Properties on Coin Cell 29
CHAPTER VI CONCLUSION 33
CHAPTER VII FUTURE WORK APPLICATION 34
REFERENCES 35

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