臺灣博碩士論文加值系統

本論文主要探討，利用奈米球微影術(Nanosphere lithography，NSL)結合反應式離子蝕刻(Reactive Ion Etching，RIE)與感應耦合電漿蝕刻(Inductively Coupled Plasma，ICP) 在矽基板上製作出三維中空奈米陣列圓柱，藉此討論相關實驗量測。
本實驗曾嘗試使用聚焦離子束系統（Focus ion beam，FIB）在S1813光阻基板上作中空奈米圓柱結構，但因成本較高且製程較不容易，故改使用奈米球微影術。量測方面，為了確認結構的光吸收(Absorption)波段，先蒸鍍上30nm的銀(Ag)，再使用反射式光譜分析儀(Reflection spectrometer，RS)量測樣品的光吸收波長，藉此探討結合金屬與介電質的三維奈米結構所具備的電漿性與對於表面電漿（Surface Plasmon，SP）的影響。
實驗過程中使用掃描式電子顯微鏡（Scanning Electron Microscope；SEM）觀察每個實驗步驟，實驗樣品的表面結構以及結構排列的完整與均勻性。

In this paper, Nanosphere lithography (NSL) combined with Reactive Ion Etching (RIE) and Inductively Coupled Plasma (ICP) has been used to fabricate a three-dimensional hollow nanorod array on a silicon substrate.
In the early experiment, focused ion beam system (FIB) had been used to make a hollow nanorod structure on a S1813 photoresist substrate. Since the cost was higher and the process was difficult, the nano sphere lithography was used instead.
In order to confirm the light absorption band of the structure, 30nm of silver (Ag) is deposited and the absorption wavelength is measured by reflection spectrometer (RS). We investigate the surface plasmonic properties of the three-dimensional nanostructures composed of metal and dielectric.
Scanning Electron Microscope (SEM) is used to observe each experiment step, the sample surface structure, integrity and uniformity of the structure.

目錄
第一章 序論 1
1-1研究動機 1
1-2表面電漿理論 5
1-2-1簡介 5
1-2-2介電質與金屬表面之表面電漿共振 5
1-2-3侷域性表面電漿共振[30] 6
1-3 奈米球微影術 10
第二章 實驗儀器介紹 12
2-1 奈米球塗布機 12
2-2 旋轉塗佈機(Spin Coating) 14
2-3反應式離子蝕刻(Reactive-Ion Etching，RIE) 15
2-4感應耦合電漿離子蝕刻 (Inductively-Coupled Plasma，ICP) 17
2-5電子束蒸鍍機(Electron Beam Evaporation) 19
2-6 紫外線/可見光光譜儀(UV/VIS spectrometers) 22
2-7 傅立葉轉換紅外線光譜儀 23
（Fourier Transform Infrared Spectroscopy，FTIR） 23
2-8掃描式電子顯微鏡(Scanning Electron Microscope，SEM) 24
2-9 COMSOL軟體模擬(COMSOL Multiphysics)[43-45] 25
第三章 樣品製作 27
3-1實驗過程圖 27
3-2奈米球基板製作 28
3-2-1清洗基板 28
3-2-2奈米球調配 28
3-2-3奈米球塗佈 29
3-3氧電漿蝕刻 30
3-4對基板加熱 30
3-5感應耦合電漿離子蝕刻 31
3-6電子束蒸鍍 31
第四章 實驗結果與討論 32
4-1先前實驗架構[21] 32
4-2奈米球基板製作 34
4-3奈米柱製作 37
4-4蒸鍍鎳或銀顆粒 41
4-5 Comsol模擬 43
4-5-1奈米實心圓柱 43
4-5-2中空奈米圓柱 48
第五章 結論 51
參考文獻 52

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