跳到主要內容

臺灣博碩士論文加值系統

(216.73.216.171) 您好!臺灣時間:2026/07/23 07:22
字體大小: 字級放大   字級縮小   預設字形  
回查詢結果 :::

詳目顯示

: 
twitterline
研究生:陳氏妙玄
研究生(外文):TRAN THI DIEU HUYEN
論文名稱(外文):Preparation of Activated Carbons Derived from Oil Palm Empty Fruit Bunch and Their Modification by N-doped Treatment for Supercapacitor
指導教授:李元堯李元堯引用關係
指導教授(外文):LI, YUAN-YAO
口試委員(外文):WANG, CHURNG-REN; HUNG, WEI-HSUAN
口試日期:2019-07-29
學位類別:碩士
校院名稱:國立中正大學
系所名稱:化學工程研究所
學門:工程學門
學類:化學工程學類
論文種類:學術論文
論文出版年:2019
畢業學年度:107
語文別:英文
論文頁數:47
外文關鍵詞:Supercapacitoractivated carbonchemical activationbiomassoil palm empty fruit bunch
相關次數:
  • 被引用被引用:0
  • 點閱點閱:135
  • 評分評分:
  • 下載下載:1
  • 收藏至我的研究室書目清單書目收藏:0
Activated carbon (AC) is regarded as one of the most promising active materials for high performance supercapacitor (SC) owning to its high specific surface area and theoretical specific capacity. In this study, oil palm empty fruit bunch (EFB) which is the agricultural residue was employed as precursor to produce ACs which were fabricated by a series of cleaning, carbonization and chemical activation processes. The as-produced AC possesses a specific surface area of 2774 m2/g, which is very high among the AC produced from biomass materials. In order to enhance the performance of SC, the AC was modified by nitrogen doping treatment. The specific capacity of AC and nitrogen-doped AC were 182 to 215 F/g, respectively, at a current density of 0.5 A/g in 6M KOH aqueous electrolyte. We demonstrated that the agriculture waste can be processed to become activated carbon with a high specific surface area for SC application.
Content
1. Introduction 1
2. Experimental 4
2.1. Preparation of activated carbon 4
2.2. Material characterization 5
2.3. Electrochemical measurements 5
3. Results and Discussion 7
3.1. Structure and Morphology of activated carbon and N-doped activated carbon derived from Oil palm empty fruit bunch 7
3.2. Electrochemical Characterization 17
4. Conclusion 21
References 22
Supplementary Information 31


References

[1] L.H. Liu, J. Lyu, T.H. Li, T.K. Zhao, Well-constructed silicon-based materials as high-performance lithium-ion battery anodes, Nanoscale 8(2) (2016) 701-722.
[2] Q. Wang, J. Yan, Z.J. Fan, Carbon materials for high volumetric performance supercapacitors: design, progress, challenges and opportunities, Energy Environ. Sci. 9(3) (2016) 729-762.
[3] X.H. Lu, M.H. Yu, G.M. Wang, Y.X. Tong, Y. Li, Flexible solid-state supercapacitors: design, fabrication and applications, Energy Environ. Sci. 7(7) (2014) 2160-2181.
[4] P. Simon, Y. Gogotsi, Materials for electrochemical capacitors, Nat. Mater. 7(11) (2008) 845-854.
[5] R. Farma, M. Deraman, A. Awitdrus, I.A. Talib, E. Taer, N.H. Basri, J.G. Manjunatha, M.M. Ishak, B.N. Dollah, S.A. Hashmi, Preparation of highly porous binderless activated carbon electrodes from fibres of oil palm empty fruit bunches for application in supercapacitors, Bioresource technology 132 (2013) 254-61.
[6] G.P. Wang, L. Zhang, J.J. Zhang, A review of electrode materials for electrochemical supercapacitors, Chem. Soc. Rev. 41(2) (2012) 797-828.
[7] Z.Y. Cao, B.Q. Wei, A perspective: carbon nanotube macro-films for energy storage, Energy Environ. Sci. 6(11) (2013) 3183-3201.
[8] J.R. Miller, P. Simon, Materials science - Electrochemical capacitors for energy management, Science 321(5889) (2008) 651-652.
[9] L.L. Zhang, X.S. Zhao, Carbon-based materials as supercapacitor electrodes, Chem. Soc. Rev. 38(9) (2009) 2520-2531.
[10] J.T. Zhang, X.S. Zhao, On the Configuration of Supercapacitors for Maximizing Electrochemical Performance, ChemSusChem 5(5) (2012) 818-841.
[11] F. Beguin, V. Presser, A. Balducci, E. Frackowiak, Carbons and Electrolytes for Advanced Supercapacitors, Adv. Mater. 26(14) (2014) 2219-2251.
[12] L.L. Liu, Z.Q. Niu, J. Chen, Unconventional supercapacitors from nanocarbon-based electrode materials to device configurations, Chem. Soc. Rev. 45(15) (2016) 4340-4363.
[13] R. Kotz, M. Carlen, Principles and applications of electrochemical capacitors, Electrochim. Acta 45(15-16) (2000) 2483-2498.
[14] Y.W. Cheng, H.B. Zhang, S.T. Lu, C.V. Varanasiad, J. Liu, Flexible asymmetric supercapacitors with high energy and high power density in aqueous electrolytes, Nanoscale 5(3) (2013) 1067-1073.
[15] Z. Kavaliauskas, L. Marcinauskas, P. Valatkevicius, Formation and Characterization of Carbon and Nickel Oxide/Carbon Composites for Supercapacitors, Acta Phys. Pol. A 119(2) (2011) 253-255.
[16] C.C. Lai, C.T. Lo, Preparation of Nanostructural Carbon Nanofibers and Their Electrochemical Performance for Supercapacitors, Electrochim. Acta 183 (2015) 85-93.
[17] Y. Zhao, Y.N. Meng, P. Jiang, Carbon@MnO2 core-shell nanospheres for flexible high-performance supercapacitor electrode materials, J. Power Sources 259 (2014) 219-226.
[18] Z.Y. Li, J. Cai, P. Cizek, H.T. Niu, Y. Dua, T. Lin, A self-supported, flexible, binder-free pseudo-supercapacitor electrode material with high capacitance and cycling stability from hollow, capsular polypyrrole fibers, J. Mater. Chem. A 3(31) (2015) 16162-16167.
[19] M.J. Zhi, F. Yang, F.K. Meng, M.Q. Li, A. Manivannan, N.Q. Wu, Effects of Pore Structure on Performance of An Activated-Carbon Supercapacitor Electrode Recycled from Scrap Waste Tires, Acs Sustainable Chemistry & Engineering 2(7) (2014) 1592-1598.
[20] W. Li, F. Zhang, Y.Q. Dou, Z.X. Wu, H.J. Liu, X.F. Qian, D. Gu, Y.Y. Xia, B. Tu, D.Y. Zhao, A Self-Template Strategy for the Synthesis of Mesoporous Carbon Nanofibers as Advanced Supercapacitor Electrodes, Adv. Energy Mater. 1(3) (2011) 382-386.
[21] J. Li, X.Y. Wang, Q.H. Huang, S. Gamboa, P.J. Sebastian, Studies on preparation and performances of carbon aerogel electrodes for the application of supercapacitor, J. Power Sources 158(1) (2006) 784-788.
[22] L.L. Zhang, R. Zhou, X.S. Zhao, Graphene-based materials as supercapacitor electrodes, J. Mater. Chem. 20(29) (2010) 5983-5992.
[23] E. Frackowiak, K. Metenier, V. Bertagna, F. Beguin, Supercapacitor electrodes from multiwalled carbon nanotubes, Appl. Phys. Lett. 77(15) (2000) 2421-2423.
[24] Y.G. Wang, Y.Y. Xia, Recent Progress in Supercapacitors: From Materials Design to System Construction, Adv. Mater. 25(37) (2013) 5336-5342.
[25] A.G. Pandolfo, A.F. Hollenkamp, Carbon properties and their role in supercapacitors, J. Power Sources 157(1) (2006) 11-27.
[26] B.A. Simon P, Nanostructured carbons: double-layer capacitance and more, The electrochemical society interface 17(1) (2008) 38.
[27] J.C. Wang, S. Kaskel, KOH activation of carbon-based materials for energy storage, J. Mater. Chem. 22(45) (2012) 23710-23725.
[28] P. Gonzalez-Garcia, Activated carbon from lignocellulosics precursors: A review of the synthesis methods, characterization techniques and applications, Renew. Sust. Energ. Rev. 82 (2018) 1393-1414.
[29] Z.H. Hu, M.P. Srinivasan, Y.M. Ni, Novel activation process for preparing highly microporous and mesoporous activated carbons, Carbon 39(6) (2001) 877-886.
[30] Ioannidou O, Z. A, Agricultural residues as precursors for activated carbon produciton - A review, Renewable Sustainable Energy Review 11 (2007) 1966-205.
[31] W.C. Lim, C. Srinivasakannan, N. Balasubramanian, Activation of palm shells by phosphoric acid impregnation for high yielding activated carbon, Journal of Analytical and Applied Pyrolysis 88(2) (2010) 181-186.
[32] R.L. Tseng, S.K. Tseng, F.C. Wu, C.C. Hu, C.C. Wang, Effects of micropore development on the physicochemical properties of KOH-activated carbons, J. Chin. Inst. Chem. Eng. 39(1) (2008) 37-47.
[33] A.M. Abioye, F.N. Ani, Recent development in the production of activated carbon electrodes from agricultural waste biomass for supercapacitors: A review, Renewable and Sustainable Energy Reviews 52 (2015) 1282-1293.
[34] Y.M. Sun, R.B. Sills, X.L. Hu, Z.W. Seh, X. Xiao, H.H. Xui, W. Luo, H.Y. Jin, Y. Xin, T.Q. Li, Z.L. Zhang, J. Zhou, W. Cai, Y.H. Huang, Y. Cui, A Bamboo-Inspired Nanostructure Design for Flexible, Foldable, and Twistable Energy Storage Devices, Nano Lett. 15(6) (2015) 3899-3906.
[35] J. Ding, H.L. Wang, Z. Li, K. Cui, D. Karpuzov, X.H. Tan, A. Kohandehghan, D. Mitlin, Peanut shell hybrid sodium ion capacitor with extreme energy-power rivals lithium ion capacitors, Energy Environ. Sci. 8(3) (2015) 941-955.
[36] X.P. Liu, C.M. Zhang, Z. Geng, M. Cai, High-pressure hydrogen storage and optimizing fabrication of corncob-derived activated carbon, Microporous Mesoporous Mat. 194 (2014) 60-65.
[37] A.E. Ismanto, S. Wang, F.E. Soetaredjo, S. Ismadji, Preparation of capacitor's electrode from cassava peel waste, Bioresource technology 101(10) (2010) 3534-3540.
[38] T.E. Rufford, D. Hulicova-Jurcakova, Z.H. Zhu, G.Q. Lu, Nanoporous carbon electrode from waste coffee beans for high performance supercapacitors, Electrochemistry Communications 10(10) (2008) 1594-1597.
[39] N.A. Echeverry-Montoya, J.J. Prías-Barragán, L. Tirado-Mejía, C. Agudelo, G. Fonthal, H. Ariza-Calderón, Fabrication and electrical response of flexible supercapacitor based on activated carbon from bamboo, physica status solidi c 14(3-4) (2017) 1600258.
[40] P. Hao, Z. Zhao, J. Tian, H. Li, Y. Sang, G. Yu, H. Cai, H. Liu, C.P. Wong, A. Umar, Hierarchical porous carbon aerogel derived from bagasse for high performance supercapacitor electrode, Nanoscale 6(20) (2014) 12120-9.
[41] W.J. Si, X.Z. Wu, W. Xing, J. Zhou, S.P. Zhuo, Bagasse-based Nanoporous Carbon for Supercapacitor Application, J. Inorg. Mater. 26(1) (2011) 107-112.
[42] R. Wirasnita, T. Hadibarata, A.R.M. Yusoff, Z.M. Lazim, Preparation and characterization of activated carbon from oil palm empty fruit bunch wastes using zinc chloride, J. Teknol. 74(11) (2015) 77-81.
[43] T. Lee, Z.A. Zubir, F.M. Jamil, A. Matsumoto, F.Y. Yeoh, Combustion and pyrolysis of activated carbon fibre from oil palm empty fruit bunch fibre assisted through chemical activation with acid treatment, Journal of Analytical and Applied Pyrolysis 110 (2014) 408-418.
[44] W. Li, K. Yang, J. Peng, L. Zhang, S. Guo, H. Xia, Effects of carbonization temperatures on characteristics of porosity in coconut shell chars and activated carbons derived from carbonized coconut shell chars, Industrial Crops and Products 28(2) (2008) 190-198.
[45] M.J. Saad, C.H. Chia, S. Zakaria, M.S. Sajab, S. Misran, M.H. Abdul Rahman, S.X. Chin, Physical and Chemical Properties of the Rice Straw Activated Carbon Produced from Carbonization and KOH Activation Processes, Sains Malaysiana 48(2) (2019) 385-391.
[46] H. Nam, W. Choi, D.A. Genuino, S.C. Capareda, Development of rice straw activated carbon and its utilizations, Journal of Environmental Chemical Engineering 6(4) (2018) 5221-5229.
[47] D. Hulicova-Jurcakova, M. Seredych, G.Q. Lu, N. Kodiweera, P.E. Stallworth, S. Greenbaum, T.J. Bandosz, Effect of surface phosphorus functionalities of activated carbons containing oxygen and nitrogen on electrochemical capacitance, Carbon 47(6) (2009) 1576-1584.
[48] B. Li, F. Dai, Q.F. Xiao, L. Yang, J.M. Shen, C.M. Zhang, M. Cai, Nitrogen-doped activated carbon for a high energy hybrid supercapacitor, Energy Environ. Sci. 9(1) (2016) 102-106.
[49] X.L. Han, H.X. Jiang, Y. Zhou, W.F. Hong, Y.F. Zhou, P. Gao, R. Ding, E.H. Liu, A high performance nitrogen-doped porous activated carbon for supercapacitor derived from pueraria, Journal of Alloys and Compounds 744 (2018) 544-551.
[50] S. Ahmed, A. Ahmed, M. Rafat, Nitrogen doped activated carbon from pea skin for high performance supercapacitor, Mater. Res. Express 5(4) (2018) 10.
[51] M.A. Mohammed, A. Salmiaton, W.A. Wan Azlina, M.S. Mohamad Amran, Gasification of oil palm empty fruit bunches: a characterization and kinetic study, Bioresource technology 110 (2012) 628-36.
[52] M.G. Alriols, A. Tejado, M. Blanco, I. Mondragon, J. Labidi, Agricultural palm oil tree residues as raw material for cellulose, lignin and hemicelluloses production by ethylene glycol pulping process, Chem. Eng. J. 148(1) (2009) 106-114.
[53] A. Skreiberg, Ø. Skreiberg, J. Sandquist, L. Sørum, TGA and macro-TGA characterisation of biomass fuels and fuel mixtures, Fuel 90(6) (2011) 2182-2197.
[54] A. Hassan, A.A. Salema, F.N. Ani, A. Abu Baker, A Review on Oil Palm Empty Fruit Bunch Fiber-Reinforced Polymer Composite Materials, Polym. Compos. 31(12) (2010) 2079-2101.
[55] O.W. Achaw, G. Afrane, The evolution of the pore structure of coconut shells during the preparation of coconut shell-based activated carbons, Microporous Mesoporous Mat. 112(1-3) (2008) 284-290.
[56] K.S.W. Sing, surface area and rorosity.pdf>, Pure Appl. Chem. 54(11) (1982) 2201 - 2218.
[57] W. Du, X.N. Wang, X.Q. Sun, J. Zhan, H.D. Zhang, X.J. Zhao, Nitrogen-doped hierarchical porous carbon using biomass-derived activated carbon/carbonized polyaniline composites for supercapacitor electrodes, J. Electroanal. Chem. 827 (2018) 213-220.
[58] S. Pujiasih, Kurnia, A. Masykur, T. Kusumaningsih, O.A. Saputra, Silylation and characterization of microcrystalline cellulose isolated from indonesian native oil palm empty fruit bunch, Carbohydrate polymers 184 (2018) 74-81.
[59] B.B. Chang, S.R. Zhang, H. Yin, B.C. Yang, Convenient and large-scale synthesis of nitrogen-rich hierarchical porous carbon spheres for supercapacitors and CO2 capture, Appl. Surf. Sci. 412 (2017) 606-615.
[60] S. Yu, D. Liu, S.Y. Zhao, B.F. Bao, C.D. Jin, W.J. Huang, H. Chen, Z.H. Shen, Synthesis of wood derived nitrogen-doped porous carbon-polyaniline composites for supercapacitor electrode materials, RSC Adv. 5(39) (2015) 30943-30949.
[61] H.X. Zhong, H.M. Zhang, S.S. Liu, C.W. Deng, M.R. Wang, Nitrogen-Enriched Carbon from Melamine Resins with Superior Oxygen Reduction Reaction Activity, ChemSusChem 6(5) (2013) 807-812.
[62] D. Wang, S. Liu, L. Jiao, G. Fang, G. Geng, J. Ma, Unconventional mesopore carbon nanomesh prepared through explosion–assisted activation approach: A robust electrode material for ultrafast organic electrolyte supercapacitors, Carbon 119 (2017) 30-39.
[63] W. Du, X.N. Wang, X.Y. Ju, K. Xu, M.J. Gao, X.T. Zhang, Carbonized Enteromorpha prolifera with porous architecture and its polyaniline composites as high-performance electrode materials for supercapacitors, J. Electroanal. Chem. 802 (2017) 15-21.
[64] J.L. Chang, Z.Y. Gao, W.Q. Zhao, L.Y. Guo, M.E. Chu, Y.D. Tang, D.P. Wu, F. Xu, K. Jiang, Nitrogen Doped Microporous Carbons with Tunable and Selective performances in Supercapacitor and Heterogeneous Catalysis, Electrochim. Acta 190 (2016) 912-922.
[65] A. Gomez-Martin, R. Chacartegui, J. Ramirez-Rico, J. Martinez-Fernandez, Performance improvement in olive stone's combustion from a previous carbonization transformation, Fuel 228 (2018) 254-262.
[66] A. Rabbi, F. Dadashian, Simultaneous improvement in tensile strength and adsorption capacity of activated carbon fibers during stabilization and activation of acrylic fibers, Diamond and Related Materials 95 (2019) 174-184.
[67] A. Concheso, R. Santamaría, M. Granda, R. Menéndez, J.M. Jiménez-Mateos, R. Alcántara, P. Lavela, J.L. Tirado, Influence of oxidative stabilization on the electrochemical behaviour of coal tar pitch derived carbons in lithium batteries, Electrochim. Acta 50(5) (2005) 1225-1232.
[68] Q. Cao, K.C. Xie, Y.K. Lv, W.R. Bao, Process effects on activated carbon with large specific surface area from corn cob, Bioresource technology 97(1) (2006) 110-5.
[69] G.G. Stavropoulos, A.A. Zabaniotou, Production and characterization of activated carbons from olive-seed waste residue, Microporous Mesoporous Mat. 82(1-2) (2005) 79-85.
[70] Y. Sudaryanto, S.B. Hartono, W. Irawaty, H. Hindarso, S. Ismadji, High surface area activated carbon prepared from cassava peel by chemical activation, Bioresource technology 97(5) (2006) 734-9.
[71] K.Y. Foo, B.H. Hameed, Preparation of oil palm (Elaeis) empty fruit bunch activated carbon by microwave-assisted KOH activation for the adsorption of methylene blue, Desalination 275(1-3) (2011) 302-305.
[72] Aik Chong Lua, J. Guo, Activated carbon prepared from oil palm stone by one-step CO2 activation for gaseous pollutant removal Carbon 38 (2000) 1089-1097.


QRCODE
 
 
 
 
 
                                                                                                                                                                                                                                                                                                                                                                                                               
第一頁 上一頁 下一頁 最後一頁 top
無相關期刊