臺灣博碩士論文加值系統

本研究以爐石粉為無機聚合物主要基材，以不同重量比之蔗渣灰0%、10%、20%、30%與40%取代，鹼活化劑採用混合水、氫氧化鈉及矽酸鈉溶液作為激發活性之激發劑，以三種水玻璃模數為0.6、0.8及1.2與三種鹼激發量為6%、8%及10%和兩種液固比0.35與0.4為主要試驗變數，以探討不同蔗渣灰取代量對蔗渣灰爐石基無機聚合物漿體之新拌性質與硬固工程性質。研究結果顯示：(1)蔗渣灰取代量越高，其工作性與流動性越差；(2)坍度與坍流度隨著水玻璃模數之增加而降低；(3)蔗渣灰取代量10%其抗壓強度與抗硫酸鹽能力為最佳，且耐熱性質較好、吸水率最低；(4)蔗渣灰取代量20%其乾縮量最小；(5)水中養護之抗壓強度低於大氣養護，而水中養護之乾縮量則較大氣養護低；(6) 蔗渣灰取代量0%~20%時，其耐水性之軟化係數皆大於0.85，故蔗渣灰取代量0%~20%適合做為耐水材料。

Research bagasse ash with Alkaline Solution as the main material to make Inorganic polymers. The modulus of sodium silicate 0.6, 0.8 and 1.2, various dosages of activator 6%, 8% and 10% and fixed water-solid ratios 0.35 and 0.4, to assess on the engineering properties. The research results show that: First, when bagasse ash replacement higher, its flowability gets worse. Second, when modulus of sodium silicate increases then the slump and slump flow decrease. Third, 10% of bagasse ash replacement which compressive strength and sulfate resistance’s effect is optimal. Forth, 20% bagasse ash replacement, its drying shrinkage phenomenon is the smallest. Fifth, curing into saturated limewater of compressive strength is less than curing at atmospheric conditions, then curing into saturated limewater of drying shrinkage phenomenon is lower than curing at atmospheric conditions. Finally, when bagasse ash replacement form 0% to 20%, its water resistance of softening coefficiency is greater than 0.85, therefore bagasse ash replacement form 0% to 20% is suitable for waterproof material.

摘要 I
Abstract II
致謝 III
目錄 IV
表目錄 VII
圖目錄 VIII
符號說明 XI
第一章 緒論 1
1.1 研究動機與背景 1
1.2 研究目的 3
1.3 研究方法 4
第二章 文獻回顧 5
2.1 廢棄物處理與再利用 5
2.1.1 廢棄物處理 5
2.1.2 農業廢棄物處理 7
2.1.3 廢棄物再利用 8
2.2 無機聚合物 12
2.2.1 無機聚合物之發展 12
2.2.2 無機聚合物之聚合反應機理 13
2.2.3 無機聚合物鹼活化之模式 14
2.2.4 無機聚合物之反應產物 14
2.2.5 爐石基無機聚合物與水泥之產物比較 14
2.3 無機聚合物硬固及特性之影響因子 22
2.3.1 鹼激發劑種類之影響 22
2.3.2 鹼激發濃度之影響 23
2.3.3 液固比之影響 23
2.3.4 養護環境之影響 24
2.3.5 材料特性與成分之影響 25
2.4 爐石粉來源與成份及特性 28
2.4.1 爐石生產 28
2.4.2 爐石粉成分 28
2.4.3 爐石化學與顆粒性質 29
2.4.4 爐石粉特性及優點 30
2.5 蔗渣灰來源與成份及特性 34
2.5.1 蔗渣灰來源 34
2.5.2 蔗渣成份 35
2.5.3 蔗渣灰的成份與特性 35
2.5.4 蔗渣灰應用於混凝土之相關研究 36
第三章 試驗計畫 40
3.1 試驗內容 40
3.2 試驗材料 40
3.3 試驗儀器與設備 46
3.4 試驗變數 51
3.4.1 試驗內容說明 51
3.4.2 試驗項目說明 52
3.4.3 無機聚合物試體之拌合與施作 52
3.5 試驗項目 56
3.5.1 初終凝時間試驗 56
3.5.2 坍度試驗 56
3.5.3 坍流度試驗 57
3.5.4 比重試驗 57
3.5.5 pH檢測試驗 57
3.5.6 抗壓強度 58
3.5.7 超音波波速檢測 59
3.5.8 熱傳導係數量測 60
3.5.9 試體乾縮長度變化量量測 61
3.5.10 硫酸鹽侵蝕 61
3.5.11 耐水性試驗 62
3.5.12 物性試驗試驗 63
第四章 結果與分析 65
4.1 新拌性質 65
4.1.1 凝結時間 65
4.1.2 坍度 67
4.1.3 坍流度 68
4.2 硬固性質 78
4.2.1 抗壓強度 78
4.2.2 超音波波速 81
4.2.3 體積穩定性 84
4.3 耐久性質 125
4.3.1 熱傳導係數 125
4.3.2 硫酸鹽侵蝕 127
4.4 物理性質 138
4.4.1 密度 138
4.4.2 吸水率 139
4.4.3 耐水性 140
第五章 結論與建議 149
5.1 結論 149
5.2 建議 151
參考文獻 152
簡歷 158

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