臺灣博碩士論文加值系統

本研究將N-甲基咪唑、N-甲基吡咯、三氟甲基苯、三氟甲氧基苯及N-苯基咔唑以亞胺基連接於二噻吩一吡咯上，分別命名為MIA、PMA、TFA、FOA和CBA，再利用電化學聚合法製備對應的五種導電高分子薄膜(P(MIA)、P(PMA)、P(TFA)、P(FOA)和P(CBA))。P(MIA)在被施予不同電壓下呈現多種顏色變化，在-0.6 V下呈現柳橙黃色、0.4 V下呈現茶色、0.8 V下呈現黃昏藍和1.4 V下呈現海軍藍。P(MIA)導電高分子薄膜於離子液體([EPI+][TFSI-])中，波長位於880 nm處擁有最大的穿透度差值為53.8%，且P(PMA)在波長位於902 nm 處具有最大的著色效率為202.04 cm2/C。此外，將五種陽極材料(MIA、PMA、TFA、FOA或CBA)搭配三種不同的陰極材料(PProDOT-Et2、PProDOT-Bz2或PProDOT-Bu2)組成雙層元件進行測試，P(TFA)/PProDOT-Et2元件於波長594 nm處擁有最大的穿透度差值(46.0%)，且P(TFA)/PProDOT-Et2元件在被施予不同電壓時呈現多種顏色變化，-0.6 V時為深象牙色、0.4 V時為鴿子藍、0.8 V時為鈷藍色和1.4 V時為龍膽藍。此外，P(MIA)/PProDOT-Bz2元件在波長位於625 nm處擁有最大著色效率(561.84 cm2/C)。

In this study, N-methylimidazole, N-methylpyrrole, trifluoromethylbenzene, trifluoromethoxybenzene and N-phenylcarbazole groups are attached to dithienylpyrroles by an imine linkage, which are denominated as MIA, PMA, TFA, FOA, and CBA, respectively. Their corresponding polydithienylpyrroles (P(MIA), P(PMA), P(TFA), P(FOA), and P(CBA)) are synthesized electrochemically. In the neutral state, P(MIA) film is tangerine at -0.6 V, it turns into tea (0.4 V), dusk (0.8V), and navy blue (1.4 V) at doped state upon oxidation. The ∆Tmax of P(MIA) film is 53.8 % at 880 nm in an ionic liquid solution, and the maximum coloration efficiency of the P(PMA) film is 202.04 cm2 C-1 at the wavelength of 902 nm. Moreover, dual type electrochromic devices (ECDs) employ P(MIA), P(PMA), P(TFA), P(FOA), or P(CBA) as anodic layer, and PProDOT-Et2, PProDOT-Bz2, or PProDOT-Bu2 as cathodic layer are fabricated. The ∆Tmax of P(TFA)/PProDOT-Et2 ECD is 46.0% at 594 nm. P(TFA)/PProDOT-Et2 ECD is dark ivory at -0.6 V, it turns into pigeon blue (0.4 V), cobalt blue (0.8V), and gentian blue (1.4 V) from the bleached state to the colored state. In addition, P(MIA)/PProDOT-Bz2 ECD shows the maximum coloration efficiency (561.84 cm2/C) at 625 nm.

摘要 i
Abstract ii
誌謝 iii
目錄 iv
表目錄 vi
圖目錄 ix
第一章 緒論 1
1-1前言 1
1-2電致變色簡介 3
1-2-1電致變色材料之種類 3
1-2-2有機導電高分子之導電機制 5
1-2-3電致變色材料之應用 7
1-2-4固態型電致變色元件之組成 10
1-2-5電致變色之基本參數 11
1-3研究動機 15
第二章 文獻回顧 17
第三章 實驗方法 28
3-1實驗流程圖 28
3-2實驗藥品 29
3-3實驗設備、儀器與分析方法 30
3-3-1合成用設備、儀器與分析方法 30
3-3-2光學及電化學性質測試用設備、儀器與分析方法 33
3-4實驗合成 35
3-4-1陽極材料SNS系列導電高分子之單體合成 35
3-4-2陰極材料ProDOT系列導電高分子之單體合成 49
3-4-3離子液體之合成 55
3-5光學及電化學性質測試及實驗裝置 57
3-5-1 ITO玻璃前處理 57
3-5-2電化學聚合 57
3-5-3在液態環境下高分子薄膜之電化學與光學性質測試 58
3-5-4高分子電解質膜的製備 59
3-5-5在固態環境下高分子薄膜之電化學與光學性質測試 60
第四章 結果與討論 61
4-1導電高分子薄膜之電化學性質測試及探討 61
4-1-1起始氧化電位 61
4-1-2定電位法電化學聚合 64
4-1-3五種SNS陽極導電高分子薄膜之氧化還原能力分析 67
4-2五種SNS導電高分子薄膜在液態環境下之光學性質測試及探討 73
4-2-1五種SNS導電高分子薄膜在液態環境下之In-situ光學吸收值 73
4-2-2五種SNS導電高分子薄膜之穿透度變化、應答時間、著色效率及穩定性探討 91
4-3五種陽極導電高分子薄膜與三種陰極導電高分子薄膜組成元件後在固態環境下之光學性質測試及探討 111
4-3-1十五種元件在固態環境下之In-situ光學吸收值 111
4-3-2十五種元件在固態環境下之穿透度變化、應答時間、著色效率及穩定性探討 146
4-3-3十五種元件之光學記憶效應 166
4-3-4十五種元件之多圈循環壽命 175
第五章 結論 184
參考文獻 185

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