臺灣博碩士論文加值系統

本研究利用了不織布其多孔的性質，進行電漿活化處理 PP 表面並接枝 MAH，，改質後的 PP 不織布所具有的官能基，可以改善其親水性及染色性質，來提升 PP不織布在產業上的應用。此外經新制程之電漿改質後的聚丙烯不織布所具備的羧酸官能基 (-COOH)，可以利用金屬離子與—COOH 基之氫離子間形成的置換反應，所以我們將以含金屬離子溶液（如硝酸銀）對改質後之 PP 不織布進行浸漬處理加工，賦予 PP 不織布之抗菌性，增加其應用的層面。

This study considers the use of the porous property of nonwovens to use a new process
for plasma activation of PP surface treatment and grafting MAH. Compared to the
traditional plasma surface modification process, this can significantly minimize the time required for its reaction. The basic function of the modified PP nonwovens can
improve its hydrophilic and dyeing properties to enhance the PP non-woven applications in the industry. Additionally, the modified polypropylene nonwovens possess the carboxylic acid functional group (-COOH). This is important because through the reaction between metal ion and the hydrogen ion of the -COOH group, a metal ion solution is produced. We are able to use this metal ion solution (e.g. silver nitrate) on the modified PP nonwovens to create nonwovens with antibacterial properties and increase its application level.

摘 要 ...............................................................................................................................i
ABSTRACT.....................................................................................................................ii
誌謝 .................................................................................................................................iii
目錄 .................................................................................................................................iv
表目錄 ............................................................................................................................. vi
圖目錄 ............................................................................................................................vii
第一章 緒論 .............................................................................................................. 1
1.1 前言........................................................................................................................ 1
1.2 理論 .......................................................................................................................3
1.2.1 電漿改質理論 ................................................................................................. 3
1.2.2 親水性加工理論 ............................................................................................. 6
1.2.3 親水性加工理論 ............................................................................................. 6
1.3 研究動機與目的...................................................................................................8
第二章 材料介紹與文獻文顧 .................................................................................. 9
2.1 材料介紹................................................................................................................ 9
2.1.1 不織布的介紹 ................................................................................................ 9
2.1.2 聚丙烯不織布的特性與優缺點 ................................................................... 10
2.1.3 馬來酸酐的介紹 .......................................................................................... 10
2.1.4 馬來酸酐的結構與特性 ............................................................................... 11
2.2 文獻回顧 .............................................................................................................. 14

2.2.1 電漿在纖維高分子之應用研究 ................................................................... 14
2.2.2 材料表面的作用 ........................................................................................... 16
第三章 實驗部分 .................................................................................................... 18
3.1 實驗材料 .............................................................................................................. 18
3.2 實驗儀器與設備.................................................................................................. 18
3.3 實驗流程 .............................................................................................................. 19
3.3.1 實驗步驟 ....................................................................................................... 20
3.3.2 製程 ............................................................................................................... 20
3.4 分析...................................................................................................................... 24
3.4.1 DSC 熱學分析............................................................................................... 24
3.4.2 紅外線光譜 (FT-IR)性質分析..................................................................... 24
3.4.3 接觸角測試 ................................................................................................... 24
3.4.4EDX 元素分析 ............................................................................................... 24
3.4.5 KS 值測試 ..................................................................................................... 24
第四章 結果與討論 ................................................................................................ 25
4.1 染色分析 .............................................................................................................. 25
4.1.1 新製程於不同改質時間之染色分析 ........................................................... 25
4.1.2 新製程於之分散性染料染色分析 ............................................................... 29
4.1.3 新製程於之分散性染料染色分析 ............................................................... 30
4.1.4 傳統製程於之分散性染料染色分析 ........................................................... 31
4.1.5 KS 值表格分析 ............................................................................................. 33
4.2 DSC 熱學性質分析.............................................................................................. 34
4.2.1 MM 之熱學性質分析 ................................................................................... 34
4.2.2 MW 之熱學性質分析................................................................................... 35
4.2.3 含銀製程比較之熱學性質分析 ................................................................... 36

4.2 紅外光學性質分析 .............................................................................................. 40
4.4 接觸角分析 .......................................................................................................... 41
4.4.1 MM 接觸角分析 ........................................................................................... 41
4.4.2 MW 接觸角分析........................................................................................... 45
4.5 EDX 分析 ............................................................................................................. 48
4.6 抗菌之定性定量 .................................................................................................. 51
第五章 結論 ............................................................................................................ 53
參考文獻 ........................................................................................................................ 54

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