臺灣博碩士論文加值系統

本研究利用偏光顯微鏡 (polarized optical microscopy POM)、原子力顯微鏡 (atomic force microscopy AFM)、掃描式電子顯微鏡 (scanning electron microscopies SEM)、微分掃描熱卡計 (differential scanning calorimeter DSC)、廣角X光繞射儀 (wide-angle X-ray diffraction WAXD)、小角度X光散射儀 (small angle X-ray scattering SAXS) 等分析聚羥基丁酸酯 [poly(3-hydroxybutyrate) PHB]與聚己二酸丁二醇酯[poly(1,4-butylene adipate) PBA] 雙結晶混摻系統中，球晶型態之轉變與晶板自組裝、相分離相域、球晶雙折射性質之間的關係。在PHB/PBA (50/50) 混摻系統中，結晶行為與相分離行為同時發生，晶板組裝的結果受此兩種互為競爭關係的行為所影響，在PHB結晶過程中，PBA相分離相域的形成會去影響球晶的雙折射性質，兩高分子PHB與PBA之間的相行為是球晶型態轉變的重要因素。PBA相分離相域的尺寸與數量不同，會不同程度地去影響球晶型態 (正型 vs 負型)，在Tc = 90 °C時所形成的PHB原始的正型球晶，會在Tc = 45 °C時轉變為其相反類型的負型球晶。此外，在樣品降至室溫後進行第二階段結晶，球晶型態隨著PBA的結晶，從PHB原始的正型轉變為PBA的負型球晶。故本實驗將針對相域如何影響晶板組裝進一步改變球晶型態做深入的分析與機制探討。

By using polarized optical, atomic force, and scanning electron microscopies (POM, AFM, SEM), wide-angle and small-angle X-ray diffraction (WAXD and SAXS), and differential scanning calorimeter (DSC) characterization, mechanisms and correlations between lamellar reassembly, phase separation domains, and birefringence types in poly(3-hydroxybutyrate) (PHB)/poly(1,4-butylene adipate) (PBA) crystalline/crystalline system were investigated in detail. In PHB/PBA (50/50) blend system, crystallization and phase separation occur spontaneously; and the lamellar patterns are governed by two competing processes. The formation of the PBA phase-separated domains could affect the birefringence types of spherulites; and the phase behavior between PHB and PBA is a key factor for the transition of birefringence types. Depending on the sizes and numbers of the PBA phase-separated domains, the optical birefringence (positive v.s negative types) of PHB spherulites may change reversely from the original positive-type spherulite at Tc = 90 °C to negative-type spherulite at Tc = 45 °C. Moreover, during the second-step crystallization at RT, the optical sign of birefringence alters from PHB positive type to PBA negative type due to the crystallization of PBA. A new mechanism of how the phase domains affect the lamellae assembly and further change the birefringence types of spherulites in polymers has been clarified upon.

目錄
中文摘要 I
英文延伸摘要 II
誌謝 XI
目錄 XIII
圖目錄 XIV
表目錄 XVII
第一章 簡介 1
1.1 前言 1
1.2 研究動機與目的 2
1.3 研究方向 3
第二章 文獻回顧 4
2.1 偏光顯微鏡之相關原理 4
2.2 正、負型球晶之相關研究 7
2.3 正、異常球晶之相關研究 15
2.4 PHB、PBA之相關研究 18
第三章 實驗 22
3.1 實驗所使用之高分子及溶劑 22
3.2 實驗樣品製備 24
3.3 實驗儀器 24
第四章 結果與討論 27
4.1 相容性與球晶型態之分析 27
4.2 影響球晶型態轉變之因素 28
4.3 熱行為分析 31
4.4 廣角X光繞射之分析 31
4.5 小角度散射之分析 32
4.6 原子力顯微鏡與電子顯微鏡之分析 35
第五章 結論 41
參考文獻 69
附錄 (supporting information) 77

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