臺灣博碩士論文加值系統

本論文主要以4-Cyanobenzyl bromide做為alkylation reagent與碳氮異位紫質反應，得到2-NCH2-p-C6H4-CNNCTPPH(2)，並與金屬試劑Ni、Pt、Cu和Co反應可得到Ni(2-NCH2-p-C6H4-CNNCTPP)(3)、Pt(2-NCH2-p-C6H4-CNNCTPP)(4)、Cu(2-NCH2-p-C6H4-CNNCTPPO)(5)和
Co(2-NCH2-p-C6H4-CN-21-CH2C6H4CH3NCTPP)(6)，這四種金屬紫質錯化合物。
我們利用13C以及1H NMR光譜鑑定金屬紫質錯化物構形，在X - Ray晶體結構數據中也發現利用N(4)-C(19)鍵長亦可判斷金屬紫質錯化物之構形。並討論1H NMR光譜中195Pt之衛星訊號形狀受chemical shift anisotropy(CSA)影響而改變。

We use 4-Cyanobenzyl bromide as alkylation reagent to react with N-confsed porphyrin to get 2-NCH2-p-C6H4-CNNCTPPH(2)，and using Ni、Pt、Cu、Co as metal reagent to get Ni(2-NCH2-p-C6H4-CNNCTPP) (3)、Pt(2-NCH2-p-C6H4-CNNCTPP)(4)、Cu(2-NCH2-p-C6H4-CNNCTPPO) (5) and
Co(2-NCH2-p-C6H4-CN-21-CH2C6H4CH3NCTPP)(6)。
To develop the correlations between δ13C [C(3)], δ1H [H(3)] and dipolar (canonical form II) in 3 and4, this work also thoroughly examines the 13C and 1H NMR of N+ = CH(Ar) fragment on metal complexes of 2-N substituted N-confused porphyrin。The shape of195Pt satellite lines in the 1H spectra vary with the magnetic field owing to CSA relaxation of 195Pt。

摘要.....I
Abstract.....II
圖目錄.....V
表目錄.....VIII
附錄.....IX
第一章 緒論.....1
一、 引言.....2
二、 N-confused porphyrin(NCP)的形式.....4
三、 N-confused porphyrin(NCP)的合成.....6
四、 N-confused porphyrin(NCP)的alkylation反應......7
五、 實驗室研究發展.....8
第二章 空環2-NCH2-p-C6H4-CNNCTPPH(2)及金屬鎳、鉑之紫質錯合物Ni(2-NCH2-p-C6H4-CNNCTPP)(3)；Pt(2-NCH2-p-C6H4-CNNCTPP)(4)的合成與分子結構探討.....9
一、 實驗步驟.....10
二、 X-Ray晶體結構資料及1HNMR光譜數據.....15
三、 結果討論.....36

第三章 金屬銅、鈷之順磁性紫質錯合物，Cu(2-NCH2-p-C6H4-CNNCTPPO)(5)；Co(2-NCH2-p-C6H4-CN-21-CH2C6H4CH3NCTPP)Cl(6) 的合成與分子結構探討.....48
一、 實驗步驟.....49
二、 X-Ray晶體資料及UV/vis、ESR數據資料.....53
三、 結果與討論......63
總結.....66
參考文獻.....67
第四章 附錄.....69
附錄一、試藥及溶劑.....70
附錄二、儀器之測定方式.....72
附錄三、晶體CIFCheck資料、MS及UV-vis.....74
附錄四、元素分析之數據.....89

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