臺灣博碩士論文加值系統

摘要 I
Abstract III
致謝 V
目錄 VII
圖目錄 XI
表目錄 XXIV
第 1 章 緒論 1
1.1 前言 1
1.2 商業化鋰離子二次電池 2
1.3 全固態電池 3
1.4 全固態電池的未來發展及挑戰 5
第 2 章 全固態電池的電極設計 11
2.1 正極材料 11
2.2 固態電解質 19
2.2.1 高分子電解質 19
2.2.2 硫化物電解質 23
2.3 複合正極 28
2.3.1 導離子率和導電子率的量測 28
2.3.2 複合正極中之分解反應 31
2.4 固態電池之介面改善 38
2.5 合金型態之負極 42
2.6 研究動機與目的 44
第 3 章 實驗方法 47
3.1 儀器設備 47
3.2 實驗藥品 48
3.3 實驗步驟及實驗儀器 49
3.3.1 黏著劑配製 49
3.3.2 複合正極塗布 50
3.3.3 KP cell固態電池 51
3.4 電化學測試 52
3.4.1 充放電測試 52
3.4.2 交流阻抗分析 53
3.4.3 線性掃描伏安法分析 53
3.5 儀器分析與原理 54
3.5.1 X-ray繞射分析(XRD) 54
3.5.2 拉曼散射光譜分析儀(Raman spectroscopy) 54
3.5.3 X光射線光電子光譜(X-ray photon spectroscopy, XPS) 55
3.5.4 X光射線吸收光譜(X-ray absorption spectroscopy, XAS) 55
第 4 章 高分子複合正極平台建立及優化 59
4.1 導離子性高分子黏著劑 59
4.1.1 NCM811複合正極膜製程優化 59
4.1.2 全固態電池阻抗分析 63
4.2複合正極中導離子與導電子率 69
4.2.1高分子固態電解質特性 69
4.2.2導離子與導電子率分析 71
4.3 NCM811高分子複合正極應用混合型全固態電池 79
4.3.1 混合型全固態電池組裝優化 79
4.3.2 電化學與老化分析 80
4.3.3 XPS表面鑑定分析 86
4.4 LiFePO4高分子複合正極應用混合型全固態電池 93
4.4.1 混合型全固態電池優化 93
4.4.2 電化學與老化分析 94
4.4.3 XRF與XAS介面鑑定分析 97
第 5 章 結論 107
第 6 章 未來工作 111
參考資料 113

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