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Production of fine or special chemicals via anodic oxidation
and paired electro-oxidation is studied. The purpose of this
study is to provide some important basic information for
research and development of the electroorganic synthesis
process which is high economy and no pollution. Applying redox
mediators to electroorganic synthesis process is to use
mediators as "electron-carrier" between electrodes and
reactants. The emphasizes on the understanding of the
surface character of electrodes, reaction mechanism and
reaction kinetics of single and paired electrolysis in the
presence of redox mediators so as to widen the application of
this new technique.The commerical competence of electroorganic
synthesis process is upgraded when the same product is obtained
on both anode and cathode paired oxidation being invented,more
efficient of power comsumption, more simplified equipment and
separation skill has been acquired. Two type of electroorganic
synthesis processes, i.e. anodic oxidation and paired electro-
oxidation process using Ag(I)/Ag(II), Mn(II)/Mn(III) and V(IV)
/V(V) as redox mediators in both divided and undivided cells
are studied. Effect of operation conditions on the current
efficiency and selectivity, the mass transfer phenomenon and
the reaction kinetics between mediators and reactants are
systematically investigated. (more.......)
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