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研究生:張永泰
研究生(外文):Yung-T'ai Chang
論文名稱:重金屬離子與有機物多成份系統之活性碳吸附研究
論文名稱(外文):Activated Carbon Adsorption of Multicomponent Containing Heavy Metal Ions and Organics
指導教授:王文竹;許道平
指導教授(外文):Wen-Jwu Wang;Tao-P'ing Shu
學位類別:碩士
校院名稱:淡江大學
系所名稱:水資源及環境工程所
學門:工程學門
學類:環境工程學類
論文種類:學術論文
論文出版年:1995
畢業學年度:83
語文別:中文
論文頁數:93
中文關鍵詞:活性碳多成份系統重金屬離子麩胺酸吸附
外文關鍵詞:Actitaved CarbonMulticomponent SystemMetal IonsGultamic
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  本研究之主題為含有機物及重金屬之多成份系統中活性碳吸附重金屬
離子 (Cu2+ Cd2+) 受有機物的影響, 我們選用酚及麩胺酸為代表性有機
物在不同性質及濃度條件下, 造成吸附特性的改變, 各項試驗均控制
於 pH=2.5,以金屬離子吸附之系統為基礎研究多成份系統中活性碳處理
單元之效益。  實驗包括兩個部份, 一為吸附等溫試驗, 金屬離子
之吸附均較符 Freurdlich 模式。 且試驗中金屬離子 200 ∼ 500mg/L
,添加酚及麩胺酸 0 ∼ 2000mg/L 。 添加酚溶液 1/n 值 -0.3605 ∼
-0.3160 、 K 值 34.04∼ 978.6 。 添加麩胺酸溶液 1/n 值 -0.4094
∼ 0.2106 、 K 值 92.4 ∼ 75.86 , 綜合看來濃度次均很小即與濃度
之關係不大而 K 值除銅離子添加麩胺酸相反外,其餘均有隨添加有機物
增加而變大之趨勢。另一為吸附速率試驗經分析檢定發現單一反應大多不
符而建立式 C(t)=A0+A1e-k1t+A2e-k2t 此反應動力式表示吸附反應為兩
個平行的反應同時進行,本研究動力吸附試驗中,除銅離子吸附麩胺酸外
,其第一速率 k1 值 3.321 ∼ 0.01994 均有隨添加物增加而變小之趨勢
。 第二速率常數 k2 值 3.630 ∼ 0.04419 除銅離子加酚之試驗外均隨
添加物濃度增加而增大。由各項試驗發現酚與麩胺酸在本研究試驗條件下
,均有較金屬離子強之吸附傾向及較大之吸附速率。麩胺酸和金屬離子有
較強之錯合能力甚至能排除已吸附之金屬離子。銅離子加麩胺酸系列試驗
之特異行為乃在於有麩胺酸銅錯合物產生。

The characters of activated carbon adsorption of heavy
metals (Cu2+,Cd2+) in a multicomponent system were studies
is this experiment. The adsorption was affected by
addition different conccentration, reactivity organics in
pH=2. 5. The findings in this experiment can be used for
extimate the better operation condititons in order to
increasing the efficacy of water and wastewater treatment. 
  This paper contains the isotherms experiment and rate
kinetics experiment. In regard to isotherms
adsorption experiment, the results comply with
Freundlich adsorption theory. The multicomponent
system, metals: 200~500 mg/L, organics: 0~2000 mg/L, the 1/n
and K which addition phenol are -0.3605~0.3160, 34.04~978.6
respectively; and addition glutamic acid are -0.4094~.02106,
22.4 0~75.86. It is founded that 1/n value are small, and no
apparrent relationship with organics concentration, but K
was increasing with organics concentration except Cu2+/
glutamic acid system.   The rate models were estimated
after data analysis. The model is C(t)=A0+A1*exp(-k1t)+A2*
exp(-k2t) which represent paralle realtions (simultaneously)
occur at different period. The rate constants in thhe Kinetic
model. The k1 value range are 3.321~0.01994, which decrease
with orgamics concentration increasing except Cu2+/phenol
system.   In addition to metalions and organics
adsorption onto activated carbon. It is founded the rate
of adsorption for organics is more than metalions. Glutamic
acid has very strong chelating ability with metal ions,
the chelating can even happend between glutamic acid
and metal ions which were adsorption on activated
carbon. The K, 1/n, k1, k2, of Cu2+/glutamic acid
system differ from other systems due to the chelating complex
was formed.

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