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研究生:侯勝雄
研究生(外文):Hou, Shung-Hsiung
論文名稱:由溶膠-凝膠法製備之摻銻氧化錫微粉粒與薄膜的結構及性質之研究
論文名稱(外文):Structure and Properties of the Sb-doped SnO2 Fine Powder and Thin Films by the Sol-Gel Method
指導教授:胡毅胡毅引用關係
指導教授(外文):Yi-Hu
學位類別:碩士
校院名稱:大同工學院
系所名稱:材料工程學系
學門:工程學門
學類:材料工程學類
論文種類:學術論文
論文出版年:1996
畢業學年度:84
語文別:中文
論文頁數:73
中文關鍵詞:溶膠-凝膠法二氧化錫抗靜電薄膜
外文關鍵詞:sol-gelSnO2antistatic filmSb
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二氧化錫薄膜具有良好的導電性及可見光穿透率,可應用於螢幕之
抗靜塗層。本研究乃利用溶膠-凝膠法,以含結晶水之四氯化錫為起始材
料,以三氯化銻為摻質來源,並添不同成份比的尿素經沸騰回流合成懸浮
液,懸浮液經水洗後以玻璃為基板進行薄膜浸鍍以及烘乾處理製成微粉。
研究內容分別研究討論微粉及薄膜兩者之特性。微粉晶粒粒徑隨尿素的增
加而有減小的趨勢,且微粉未經熱處理即具有正方晶之氧化錫晶相。由電
子顯微鏡觀察得知微粉顆粒大小隨熱處理溫度提高而有變大的現像。薄膜
其表面塗佈均勻,經測試有具有80﹪以上的可見光穿透率。不同的浸鍍次
數可改變薄膜導電度,十次浸鍍之薄膜其表面電阻介於10E6∼10E7Ω/□


Tin oxide film has been well development as antistatic
coating on the monitor because of well conductivity and high
transparency in visible lightrange. Sol-gel method was used in
this study and the precursor was made fromSnCl4.XH2O, SbCl3
which is the source of dopant, and different fractional ofurea
by refluxed for two hours to form SnO2 colloidal solution.
Colloidal solution was washed by distilled water and dried to
become gel powders. Thin films were prepared by dipping the
glass substrate into the colloidal solution.The characteristics
of the fine powders decreased as increasing the amount of urea.
These crystal size of the fine powders decreased as increasing
the amountof urea. these gel powders have the tetragonal crystal
structure before heat treatment. From TEM investigation, the
particle size of the powders increased as increasing the heating
temperature. The resultant films showed a uniform microstructure
and have higher than 80﹪ transmission of visible light.
Resistivity of the films was decreased by increasing the dipping
layers. The sheet resistance of the ten-layers films was in the
range of 10E6∼10E7 Ω/□.

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