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研究生:杜全盛
研究生(外文):Du, Chuan-Sheng
論文名稱:溶劑對聚甲基丙烯酸甲酯的機械性質和光學性質的影響
論文名稱(外文):Solvent-Induced Mechanical and Optical Property Changes in Poly(methyl methacrylate)
指導教授:李三保李三保引用關係
指導教授(外文):Lee, Sanboh
學位類別:碩士
校院名稱:國立清華大學
系所名稱:材料科學工程學系
學門:工程學門
學類:材料工程學類
論文種類:學術論文
論文出版年:1997
畢業學年度:85
語文別:中文
論文頁數:79
中文關鍵詞:溶劑
外文關鍵詞:Optical Property
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The mechanical property of solvent-welded poly (methyl methacrylate) (PMMA) under γ-ray irradiation has been investigated. Morphologies of cleavage. tear, tensile and shear fracture are observed. Effect of temperature, dosage, and solubility parameter on mechanical strength are discussed. Methanol, ethanol, and N, N-Dimethylformamide (DMF) used are the bonding solvents. DMF is good solvent for PMMA. The solvent-selded PMMA showed the high mechanical strength at high temperature and dosage. The solvent affected zone (SAZ) is not directly related to the mechanical strength.
The effect of methanol on optical property of irradiated and un-irradiated PMMA has been investigated. The transmittance of un-irradiated PMMA for different times of exposure to methanol at temperatures at 45℃~60℃ are observed. The scattering light intensity varies as λ-df. where df is in the range between 2.1 and 2.9. When irradiated PMMA immerses into methanol at longer time, the transmittance gradually recovery to the virgin PMMA.

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