|
In this paper, based on the thin-wall moulding under high processingpressure. A theoretical model contains the pressure term is developed by combining the Williams-Landel-Ferry(WLF) semi-experiential equation and the weld-line strength model of the molecular chains crossing the interfaceand self-diffusion. Then applying optimal theory to find the optimal material. According to the theoretical model, the high pressure would lead to the high viscosity and low molecular diffusion and reduce the degree of bounding. However, the traditional weld-line theory can't modify this fact. Therefore,it would be more accurate for thin part to predict the degree of bounding byapplying the theoretical model adding the pressure term. According to the analytic result it was better for using higher melt temperature in the moulding process. For the thin-wall material, it is better for selecting lower density, lower plateau modulus, higher the ratio of mean-square end-to-end distance to average molecular weight, lower molecular weight andlower glass transition temperature matreial and must be permitted by mechanicalproperties.
|