臺灣博碩士論文加值系統

本研究已廢棄發泡聚苯乙烯為原料，二氯甲烷為溶劑，以濃硝酸與濃硫
酸體積比例為1:1的混酸硝化為硝化程度不同之硝基聚苯乙烯(Nitro-
Polystyrene;NPS)，進而以混酸用量來調節硝化度，而以苯將其硝基還
原成胺基 (Amino-Polystyrene;AMPS)後，再磺化為磺酸-胺基聚苯乙烯(
Sulfonic Acid-AminoPolystyrene;SA-AMPS)，也將硝基聚苯乙烯磺化為
硝基聚苯乙烯-聚苯乙烯磺酸(NPS-PSSA;Nitropolystyrene-polystyrene
sulfonic acid)，再以苯還原成胺基聚苯乙烯-磺酸聚苯乙烯(AMPS-
PSSA)，此兩種不同的流程皆可使聚苯乙烯成為同時具有胺基及磺酸根之
雙官能基之化合物，再將其重氮化後與N-1-基次乙基二胺‧二鹽酸鹽(
N-1- Naphthylethylenediamine Dihydrochloride)(NEDA)偶合成高分子
偶氮染料，並與單體Sulfanilamide，Orthanilic Acid，P-toluidine，
Aniline等重氮化溶液和NEDA偶合所得染料之U.V吸收度比較其相似之結構
下相同吸收光譜，再由其最大吸收波長強度對聚苯乙烯之硝化、還原作定
量。

In this study ,waste foaming polystyrene is used for raw
material .The nitration reaction proceeds to use the mixed
nitric acid and sulfuric acid ,then use the mixed acid to
control the degree of the nitration.The NPS is reduced to use
the phenyl-hydrazine to get the Amino-polystyrene(AMPS),then
amino-polystyrene after sulfonation gets the Amino-polystyrene
sulfonic acid(SA-PSSA),or NPS after sulfonation gets the nitro-
polystyrene sulfonic acid (NPS-PSSA),the NPS-PSSA is reduced to
use the phenylhydrazine to get the amino-polystyrene-polystyrnen
sulfonic acid.It can get the polymer-azo-dye by diazotiation
coupling with N-1-Naphthylethyldiamine Dihydrochloride(NEDA),and
compared the UV spectrum to sulfanilamide,orthanilic acid,p-
toluidine,aniline with the analogous structure.