本研究中已成功合成出新型分支狀聚醚醇，以BPA、BPZ這兩類雙酚類化合物與環氧樹脂（D.E.R. 332）進行開環聚合，並藉由三官能基酚類化合物（TPA）的加入，產生分支狀結構，得到高分支狀之熱可塑性聚醚醇。藉由ASTM E698動力學分析可以得到最適化的反應條件參數，分支點的導入可以得到截然不同的流動行為，輕微的分支結構能有效改善其流動性質，隨著分支點漸漸的增多，分支結構更趨於複雜化，而此高度的物理性交聯大大降低了流動性。BPZ單體的引入，雖然使得聚醚醇流動性變差，但卻能有效改善其氣體障蔽能力，而分支狀結構不利於氣體障蔽能力。BPZ系統聚醚醇的熱膨脹性會較BPA系統聚醚醇為低。分支結構對於熱膨脹性質的影響，與聚醚醇流動行為有著類似的趨勢。根據薄膜拉伸機械性質分析，BPA系統聚醚醇與BPZ系統聚醚醇其延展性皆不甚高，而BPZ系統聚醚醇會有較高之拉伸模數。

In the study, poly hydroxy ether has been prepared by reacting a dihydric phenol (BPA, BPZ) with a diepoxide (D.E.R. 332) in the presence of Ethyl triphenylphosphonium bromide (ETPB) catalyst. The reaction between the dihydric phenol and the diepoxide is conducted in bulk system. By adding tri-functional phenol (TPA), highly branching poly hydroxy ether has been prepared by the new process. The optimal synthesis parameter can be calculated by dynamical analysis. Slightly branching mechanism improved fluid property, but highly branching mechanism decreased fluid property. BPZ-type poly hydroxy ethers have lower oxygen permeability than BPA-type poly hydroxy ethers. The linear thermal expansion properties of poly hydroxy ethers have the same trend with fluid properties. All of these poly hydroxy ethers have low elongation. BPZ-type poly hydroxy ethers have higher tensile modulus.

中文摘要…………………………………………………………………Ⅰ
英文摘要………………………………………………………………....Ⅱ
謝誌……………………………………………………………………....Ⅲ
目錄……………………………………………………………………....Ⅳ
圖目錄…………………………………………………………………....Ⅵ
表目錄……………………………………………………………………Ⅷ
一、 緒論…………………………………………………………………..1
二、 文獻回顧…….…………………………………………………….…5
2-1 合成聚醚醇之相關文獻..…………………………………………..…5
2-2 合成分支狀聚醚醇之相關文獻………………………………….….11
2-3 聚醚醇應用之相關專利………………………………………….….12
三、 研究目的與內容……………………………….……………………14
3-1 研究目的……………………………………………………….…….14
3-2 研究內容……….…………………………………………………….15
3-2-1 聚醚醇合成法…………...………….………………………...15
3-2-2 聚醚醇性質分析……………………….……………………..16
四、 實驗部分….…………………………………………………………18
4-1 實驗藥品與溶劑…………….…………………...…………………..18
4-2 實驗設備與儀器………………….………………………………….20
4-3 實驗方法………………….………………………………………….22
4-3-1 動力學實驗…………………………….……………………..23
4-3-2 聚醚醇合成實驗……………………….……………………..24
4-3-2-1 合成直鏈狀聚醚醇……………………………...….24
4-3-2-2 合成分支狀聚醚醇……………………………...….25
4-3-3 成膜實驗……………………………….……………………..26
4-5 實驗流程圖……….……………………………….…………………29
五、 結果與討論…………………………………………………………30
5-1 反應動力學分析….……………………………….…………………30
5-2 凝膠滲透層析分析.……………………………….…………………36
5-3 核磁共振光譜分析.……………………………….…………………36
5-4 玻璃轉移溫度比較.……………………………….…………………37
5-5 熔融指數分析…….……………………………….…………………38
5-6 毛細管流變行為分析……………………………..…………………40
5-7 薄膜透氣性分析…………………………………..…………………42
5-8 薄膜熱膨脹性分析………………………………..…………………44
5-9 薄膜機械性質分析………………………………..…………………45
六、 結論…….……………………………………………………………47
七、 參考文獻……………………………………………………………49

1. K. C. Teng and F. C. Chang, Polymer, Vol. 34, No. 20, pp. 4291-4299 (1993).
2. Q. Guo, Polymer, Vol. 36, No. 25, pp. 4753-4760 (1995).
3. J. C. Kim, T. Yamada, C. Ruslim, K. Iwata, T. Watanabe and S. Miyata, Macromolecules, Vol. 29, No. 12, pp. 7177-7185 (1996).
4. O. Sugihara, H. Nakayama, N. Okamoto, T. Sakakibara and Y. Taketani, Japan Journal Applied Physics: Part 2, Vol. 33, No. 3A, pp. 321-323 (1994).
5. Y. Fujiwara, K. Naito and T. Odajima, United States Patent No. 3873637, 1975.
6. L. Biorcio and C. Mensi, United States Patent No. 4526912, 1985.
7. L. Biorcio and C. Mensi, United States Patent No. 4578312, 1986.
8. O. Hayashi, K. Okahashi and H. One, United States Patent No. 4212960, 1980.
9. P. S. Sheih and J. L. Massingill, Journal of Coatings Technology, Vol. 62, No. 781, pp. 25-30 (1990).
10. J. L. Massingill, P. S. Sheih, R. C. Whiteside, D. E. Benton and D. K. Morisse-Arnold, Journal of Coatings Technology, Vol. 62, No. 781, pp. 25-30 (1990).
11. R. A. Dubois, H. Ohnishi and A. J. Malzman, United States Patent No. 5654382, 1997.
12. Y. Kamekura, T. Ihara and K. Morita, Metal Finishing, Vol. 96, No. 11, pp. 119 (1998).
13. R. C. White, P. S. Sheih and J. L. Massingill, Journal of Coatings Technology, Vol. 62, No. 788, pp. 61-67 (1990).
14. K. D. Weiss, Progress in Polymer Science, Vol. 22, No. 2, pp. 203-245 (1997).
15. Y. Kamekura, T. Ihara and K. Morita, United States Patent No. 5767175, 1998.
16. D. J. Brennan, H. C. Silvis, J. E. White and C. N. Brown, Macromolecules, Vol. 28, No. 19, pp. 6694-6696 (1995).
17. N. H. Reinking, A. E. Barnabeo and W. F. Hale, Journal of Applied Polymer Science, Vol. 7, No. 6, pp. 2153-2160 (1963).
18. N. H. Reinking, A. E. Barnabeo and W. F. Hale, Journal of Applied Polymer Science, Vol. 7, No. 6, pp. 2145-2152 (1963).
19. N. H. Reinking, A. E. Barnabeo and W. F. Hale, Journal of Applied Polymer Science, Vol. 7, No. 6, pp. 2135-2144 (1963).
20. E. G. Olsen and J. Jackson Jr. , United States Patent No. 4267301, 1981.
21. E. G. Olsen and J. Jackson Jr. , United States Patent No. 4383101, 1983.
22. H. C. Silvis, J. R. Berman and L. Jackson, United States Patent No. 4647648, 1987.
23. H. C. Silvis and T. A. Morgan, United States Patent No. 4672102, 1987.
24. M. Ochi, H. Kageyama and M. Shimbo, Polymer, Vol. 29, No. 2, pp. 320-324 (1988).
25. K. Watanabe and Y. Fukuyama, United States Patent No. 4657954, 1987.
26. H. V. Hoorn, Journal of Applied Polymer Science, Vol. 12, No. 4, pp. 871-888 (1968).
27. F. B. Alvey, Journal of Applied Polymer Science, Vol. 13, No. 7, pp. 1473-1486 (1969).
28. P. N. Son and C. D. Weber, Journal of Applied Polymer Science, Vol. 17, No. 7, pp. 2415-2426 (1973).
29. H. Batzer and S. A. Zahir, Journal of Applied Polymer Science, Vol. 19, No. 2, pp. 585-600 (1975).
30. H. Batzer and S. A. Zahir, Journal of Applied Polymer Science, Vol. 19, No. 2, pp. 601-607 (1975).
31. H. Batzer and S. A. Zahir, Journal of Applied Polymer Science, Vol. 19, No. 2, pp. 609-617 (1975).
32. H. C. Silvis, J. E. White and S. P. Crain, Journal of Applied Polymer Science, Vol. 44, No. 10, pp. 1751-1757 (1992).
33. J. A. Schomaker, J. E. White and A. P. Haag, United States Patent No. 5401814, 1995.
34. H. C. Silvis and J. E. White, Polymer News, Vol. 23, No. 1, pp. 6-10 (1998).
35. J. E. White, H. C. Silvis, M. N. Mang, D. J. Brennan, J. A. Schomaker, A. P. Haag, S. L. Kram and C. N. Brown, Polymer Preprints, Vol. 34, No. 1, pp. 904-905 (1993).
36. J. E. White, A. P. Haag, R. G. Pews, S. L. Kram, C. E. Pawloaki and C. N. Brown, Journal of Polymer Science: Part A: Polymer Chemistry, Vol. 34, No. 14, pp. 2967-2973 (1996).
37. D. J. Brennan, J. E. White, A. P. Haag, S. L. Kram, C. N. Brown and S. Pikulin, Polymer Preprints, Vol. 34, No. 1, pp. 906-909 (1993).
38. D. J. Brennan, J. E. White, A. P. Haag, S. L. Kram, M. N. Mang, S. Pikulin and C. N. Brown, Macromolecules, Vol. 29, No. 11, pp. 3707-3716 (1996).
39. D. J. Brennan, A. P. Haag, J. E. White and C. N. Brown, Macromolecules, Vol. 31, No. 8, pp. 2622-2630 (1998).
40. J. S. McHattie, W. J. Koros and D. R. Paul, Journal of Polymer Science: Part B: Polymer Physics, Vol. 29, No. 6, pp. 731-746 (1991).
41. J. S. McHattie, W. J. Koros and D. R. Paul, Polymer, Vol. 32, No. 14, pp. 2618-2625 (1991).
42. J. C. Lee, M. H. Litt and C. E. Rogers, Journal of Polymer Science: Part B: Polymer Physics, Vol. 36, No. 1, pp. 75-83 (1991).
43. C. J. Carriere and H. C. Silvis, Journal of Applied Polymer Science, Vol. 66, No. 6, pp. 1175-1181 (1997).
44. D. N. Bikiaris and G. P. Karayannidis, Journal of Polymer Science: Part A: Polymer Chemistry, Vol. 33, No. 10, pp. 1705-1714 (1995).
45. H. Inata and S. Matsumura, Journal of Applied Polymer Science, Vol. 33, No. 10, pp. 3069-3079 (1987).
46. H. Inata and S. Matsumura, Journal of Applied Polymer Science, Vol. 34, No. 10, pp. 2769-2776 (1987).
47. L. E. Nielsen, " Polymer Rheology" , Ch. 4, Elsevier, New York, 1982.
48. U. W. Gedde, " Polymer Physics" , Ch. 6, Chapman & Hall, London, 1995.
49. R. R. Light and R. W. Seymour, Polymer Engineering and Science, Vol. 22, No. 14, pp. 857-864 (1982).
50. M. Salame, Polymer Engineering and Science, Vol. 26, No. 22, pp. 1543-1546 (1986).