雙鐵錯合物[[Fe2(CO)4(η5-C5H5)2]與含磷雙牙配子Ph2P-(CH2)nPPh2 (n=1,dppm; n=2, dppe; and n=3, dppp)，經由熱裂法反應，共得到四個二取代的錯合物：[{Fe(CO)(η5-C5H5)}2dppm](1), [{Fe(CO)(η5-C5H5)}2dppe](2),[{Fe(CO)(η5-C5H5)}2dppp](3)及[{Fe(η5-C5H5)C1}dppp](4)。
十二羥四銥[Ir4(CO)12]與含磷雙牙配子{Fe(C5H4PPh2)2}(dppf)經由熱裂法反應共得到五個錯合物：[HIr4(CO)7{Fe(C5H4PPh2)2}{Fe(C5H4PPh2)-(C5H3PPh2)}](5), [H2Ir4(CO)6-{Fe(C5H4PPh2)(C5H3PPh2)}2](6), [H3Ir4(CO)4{Fe(C5H4PPh2)(C5H3PPh2)}-{Fe(C5H4)(C5H4P(Ph)(C6H4)}{P(Ph)(C6H4)}](7), [H4Ir4(CO)4{Fe(C5H3PPh2)-(C5H4P(Ph)(C6H4)}2](8)及[Ir4(CO)8(dppf)2](9)。
六羥金屬 M(CO)6(M: Cr, Mo, W)及鎳鹽 NiX2(X: C1, Br, I)與六磷配子[(Ph2PC2CH2)2P(CH2)2P(CH2CH2PPh2)2(P2(-Pf)4)及[(Ph2PCH2CH2)2P(CH2)3P(CH2CH2PPH2)2](P2(-Pf)4'')經由化學氧化法及熱裂法共得到九個錯合物：[{W(CO)5}6P2(-Pf)4](10), [{Cr(CO)3}2P2(-Pf)4](ll), [{Mo(CO)3}2-P2(-Pf)4''](12), [(NiC1)2P2(-Pf)4][PF6]2(13), [(NiC1)2P2(-Pf)4''][PF6]2(14),[(NiBr2)2P2(-Pf)4](15), [(NiBr)(NiBr2)P2(-Pf)4][PF6](16), [(NiBr)2-P2(-Pf)4[PF6]2(17) and [(NiI2)2P2(-Pf)4''](18)。錯合物(l)~(8)，(10)~(18)以X射線單晶繞射的方法獲得單晶結構解析。晶體數據整理如表 0.1。

Treatments of [Fe2(CO)4(η5-C5H5)2] with diphosphine ligands, Ph2P-(CH2)nPPh2 (n=1, dppm; n=2, dppe; and n=3, dppp), via thermoiyticmethod afford four disubstituted compounds: [{Fe(CO)(η5-C5H5)}2dppm](1), [{Fe(CO)(η5-C5H5)}2dppe](2), [{Fe(CO)(η5-C5H5)}2dppp](3) and[{Fe(η5-C5H5)C1}dppp](4). The reactions of [Ir4(CO)12] with{Fe(C5H4PPh2)2}(dppf) by thermolytic method yield five compounds:[HIr4(CO)7{Fe(C5H4PPh2)2}{Fe(C5H4PPh2)(C5H3PPh2)}](5), [H2Ir4(CO)6-{Fe(C5H4PPh2)(C5H3PPh2)}2](6), [H3Ir4(CO)4{Fe(C5H4PPh2)(C5H3PPh2)}-{Fe(C5H4)(C5H4P(Ph)(C6H4)}{P(Ph)(C6H4)}](7), [H4Ir4(CO)4{Fe(C5H3PPh2)-(C5H4P(Ph)(C6H4)}2](8) and [Ir4(CO)8(dppf)2](9).
By chemical oxidation and thermoiytic methods, the reactions of M(CO)6(M: Cr, Mo, W) and NiX2(X: C1, Br, I) with hexadentate phosphine ligands [(Ph2PC2CH2)2P(CH2)2P(CH2CH2PPh2)2(P2(-Pf)4) and [(Ph2PCH2CH2)2P(CH2)3P(CH2CH2PPH2)2](P2(-Pf)4''), yield nine compounds: [{W(CO)5}6P2(-Pf)4](10), [{Cr(CO)3}2P2(-Pf)4](ll), [{Mo(CO)3}2- P2(-Pf)4''](12), [(NiC1)2P2(-Pf)4][PF6]2(13), [(NiC1)2P2(-Pf)4''][PF6]2(14), [(NiBr2)2P2(-Pf)4](15), [(NiBr)(NiBr2)P2(-Pf)4][PF6](16), [(NiBr)2-P2(-Pf)4[PF6]2(17) and [(NiI2)2P2(-Pf)4''](18).
All compounds except (9) have been characterized by X-ray diffraction method and their crystal data are listed on Table 0.1.

封面
目錄
中文摘要
英文摘要
表次
圖次
第一章 緒論
第一節 合成與結構
第二節 紅外線光譜
第三節 X光單晶結構解析原理
第二章 實驗
第一節 儀器和藥品
第二節 合成
第三節 結構解析
第三章 討論
第一節 ﹝Fe2(CO)4(n5-C5H5)2﹞衍生物
第二節 ﹝Ir4(CO)12﹞衍生物
第三節 六磷配子之合成
第四節 含六磷配子錯合物
第四章 結論與展望
參考文獻
附錄一 紅外線光譜與核磁共振光譜圖