臺灣博碩士論文加值系統

僅靠單一種類分子的核化，需要在相當大的過飽和狀況下才能達到有效的核化速率，這在實際大氣中不太可能發生。若考慮雙(多)組分的情況下，則此核化過程在相對濕度、相對酸度均小於100%的狀況下就能發生。即在一般大氣條件下，新粒子的產生主要是經由雙(多)組分核化過程。而在計算新粒子生成的核化速率上所需要的核化參數在溫度變化上也已做良好的處理，模式結果顯示，在相對濕度和相對酸度愈大且溫度愈低時，核化速率愈大。
並將此雙組分核化理論應用在汽車污染排放上，考慮H2SO4-H2O的核化。同時並提出假說，認為經由汽車引擎的高溫燃燒會蒸發大氣中原有的氣懸粒子，釋放出核化所需要的酸氣，不需要經由空氣中的光化學作用而生成。模式中首先考慮廢氣傳導冷卻和混合冷卻這兩種狀況，並分別考慮核化消耗與否，結果均顯示新粒子的生成經由排放廢氣和周圍空氣的混合冷卻就能生成，此假設並有加熱管實驗和引擎溫度足以蒸發氣懸粒子之調查以資佐證。
此研究已對氣懸粒子的核化過程做一完整模擬，且已建立一個雙組份核化速率模式，可計算出任何溫度下，各相對濕度與相對酸度的核化速率。在空氣污染日漸嚴重和汽機車、飛機數量日漸增加的情況下，其應用的價值十分高，因此此初步的核化過程模擬可說十分重要。

陳正平，1996：局部地區凝結核粒徑分佈之觀測及其對雲物理結構之影響的理論研究。NSC-85-2111-M-002-006，90 pp.。
陳正平，1998：氣懸粒子的觀測與模擬（Ι）。國科會專題研究報告。NSC-87-2111-M-002-007。
陳宏榆，1997：氣懸粒子物理特性之研究：核模粒子生成機制的探討。台灣大學大氣科學所碩士論文。
Appleman, H., 1953: The formation of exhaust condensation trails by jet aircraft. Bull. Meteorol. Soc., 34, 14-20.
Ayers, G. P., R. W. Gillett, and J. L. Gras. 1980: On the vapor pressure of sufuric acid. Geophys. Res. Lett., 17, 433-436.
Charlson, R.J., Langner, H. Rodhe, C. B. Leovy, and S. G. Warren, 1991: Perturbation of the Northern Hemisphere radiative balance by back-scattering from anthropogenic sulfate aerosol. Tellus, 43A, 152-163.
Charlson, R.J., S.E. Schwartz, J.M. Hales, R.D. Cess, J.A. Coakley, Jr., J.E. Hansen, and D.J. Hofmann, 1992: Climate forcing by Authropogenic aerosols. Science, 255, 423-430.
Chen, J.-P., and P.J. Crutzen, 1994: Solute effects on the evaporation of ice particles. J. Geophys. Res., 99, 18847-18859.
Chow, J.-C., 1995: Measurment method to determine compliance with ambient air quality standards for suspended particles. J. Air and Waste management Association., 45, 320-382.
Coakley, J. A. Jr., Bernstein, R. L., and Durkee, P. A.(1987). Science, 237, 1020-1022.
Conver, J. H., 1966. J. Atmos. Sci. 23, 778-785.
Cowling, E. B., 1982: Acid precipitation in historical perspective. Environ. Sci. Technol., 16, 110A.
Doyle, G. J., 1961: Self-nucleation in the sulfuric acid-water systems. J. Chem. Phys, 125, 236-242.
Flood, H., 1934: Tropfenbildung in ubersattigten dampfen, Z. Phys. Chem., A170, 286-294.
Giauque, W. F., Hornung, E. W., Kunzler, J. E., and Rubin, T. R. (1959): The thermodynamic properties of Aqueous sufuric acid solution and Hydrates from 15K to 300K. J. Phys. Chem. 82. 62-70.
Handbook of Chemistry and Physics 1977: 53rd edition, The chemical Rubber Company Press, 18901 Cranwood Parkway Cleveland OH 44123, USA.
Harshvadhan, 1993: Aerosol-climate interaction. In Aerosol-Cloud-Climate Interactions, edited by P.V. Hobbs, Academic Press, London, 75-95.
Heist, R. H. and Reiss, H. 1974: Hydrates in supersaturated binary sulfuric acid-water vapor, J. Chem. Phys, 61, 573-581.
Jaecker-Voirol, A., and P. Mirabel, Homogeneous nucleation in the sufuric acid-water system, Atmos. Environ., 23, 2053-2057,1989.
Jaecker-Voirol, A., Ponche, J. L. and P. Mirabel, (1990): Vapor pressure in the ternary system water-nitric acid-sufuric acid at low temperature. J. Geoph. Researth. 95, 11857-11863.
van der Waals. J. D., 1894 : Zeit. Phys. Chem. 13, 657
Karcher, B., 1995 : A trajectory box model for aircraft exhaust plumes, J. Geophys. Res. 100, 18835-18844.
Kiang, C. S. And D. Stauffer, 1973: Faraday Symp. Chem. Soc. 6, 26.
King, M. D., L. F. Radke., and P. V. Hobbs., 1993: J. Geophys. Res. 98, 2729-2739.
Klingenberg, H., and H. Winneke, 1990: Studies on health effects of automotive exhaust-emissions. How dangerous are diesel emission? Sci. Total Environ. 93, 95-105.
Kreindenweis, S. M., and J. H. Seinfeld, 1988: Nucleation of sulfuric acid-water and methanesulfonic acid-water solution particles: Implications for the atmospheric chemistry of organosulfur species. Atmos. Environ., 22, 283-296.
Mirabel, P. and Katz, J. L. 1974: Binary homogeneous nucleation as a mechanism for the formation of aerosol, J. Chem. Phys., 60, 1138-1144.
Mirabel, P. and Clavelin, J. L,. 1978: J. Chem. Phys. 68, 5020.
Morgan, J. L. R., and C. E. Davis. 1916: J. Am. Chem. Soc. 38, 555.
Nair, P. V. N. and Vohra, K. G. 1975: J. Aerosol. Sci. 6, 265.
Pendis, S. N., and J. H. Seinfeld, 1989: Mathematical modeling of acid deposition due to radiation fog. J. Geophys. Res., 94, 12911-12923.
Radke, L. F., and Hobbs, P. V. 1969: J. Atmos. Sci. 26, 281-288
Reiss, H. 1950 : The kinetics of phase transition in binary systems, J. Chem. Phys., 18, 840-848.
Rood, M.J., and R.M. Currie., 1989: Absorption of NH3 and SO2 during activation of atmospheric cloud condensation nuclei. Atmos. Environ., 23, 2847-2854.
Schumann, U., 1994: On the effect of emissions from aircraft engines on the state of the atmosphere. Ann. Geophys., 12, 365-384.
Stauffer, D., 1976 : Kinetic theory of two-component ("heteromolecular") nucleation and condensation, J. Aerosol Sci, 7, 319-333.
Tabata, S., 1973: A simple but accurate formula for the saturation vapor pressure over liquid water, J. Appl. Meteorol., 12, 1410-1412.
Toon, O.B., R.P. Turco, J. Joudan, J. Goodman, and G. Ferry, 1989: Physical processed in polar stratospheric ice clouds. J. Geophys. Ress., 94, 11359-11380.
Twomey, S. A., 1977: The influence of pollution on the shortwave albedo of clouds. J. Atmos. Sci., 34, 1149-1152.
Twomey, S.A., M. Piepgrass, and T.L. Wolfe, 1984: An assessment of the impact of pollution on global cloud abedo. Tellus, 36B, 355-356.
Yue, G.K., and P. Hamill, 1979: The homogeneous uncleation rates of H2SO4-H2O aerosol particles in air. J. Aerosol. Sci., 10, 609-614.