臺灣博碩士論文加值系統

本研究採用新開發之捲氣式反應器，探討臭氧與臭氧/過氧化氫程序處理含酚水溶液之特性，內容中包括在不同pH值、酚初始濃度、臭氧進口濃度及過氧化氫劑量條件下，對酚之分解效果、臭氧利用率、以及反應過程中ADMI與TOC值之變化情形。
結果顯示在臭氧程序中，提高pH值、臭氧劑量，對於酚的去除率，均有明顯的上升，唯在pH值高於11時有抑制現象產生。實驗中亦發現臭氧利用率隨pH值之增加而上升，且在不同酚水溶液初濃度下，仍可維持高臭氧利用率。至於TOC之去除隨pH值與臭氧進口濃度之升高而有較佳之處理結果。溶液pH值與臭氧進口濃度影響反應過程中ADMI色度之變化：提高pH值會有較大的ADMI值出現，而增加臭氧進口濃度可以加速反應過程最大ADMI峰值之出現。在臭氧/過氧化氫程序中，適量添加過氧化氫，可加速酚濃度之降解與TOC之去除，並提高臭氧利用率。添加過氧化氫對於酚濃度降解與TOC去除之增進效果，隨pH值之提高，而快速遞減。過高的pH值或添加過量之過氧化氫，不但無法促進分解反應的作用，反而降低處理的效率。
在操作成本評估方面，以臭氧分解含酚廢水，在酚初始濃度約為600 mg/L與pH 9條件下，所需之成本最多約為 36.7 NT＄/ton。

A newly developed gas-induced reactor was used in this study to investigate the behavior for the ozonation of phenol aqueous solution by means of O3 and O3/H2O2 processes. This paper investigated the decomposition effect of phenol, ozone utilization rate, and the variation of ADMI and TOC values during reaction, under the conditions of different pH values, phenol initial concentrations, ozone input concentrations and hydrogen peroxide dosages.
Experimental results of ozonation process demonstrated that there was clearly an uprising in the elimination of phenol with the increased in both pH value and ozone dosage, except for an occurrence of a restriction effect under pH 11. It was also found in this study that ozone utilization rate rose with the increase in pH value and still maintained at high values under various initial concentrations of phenol aqueous solution. A better treatment of TOC was attributed to the increase in both pH values and ozone input concentrations. During the reaction, ADMI value varied with the changes in pH value and ozone input concentration, and a higher ADMI value was resulted from the increase in pH value. Moreover, the increase in ozone input concentration could accelerate the occurrence of the maximum ADMI peak. In O3/H2O2 process, phenol decomposition, TOC removal, and ozone utilization rate were promoted by the proper addition of hydrogen peroxide. However, the improvement efficiencies of phenol decomposition and TOC removal showed a rapid decreased with increasing in pH value. Higher pH value or excess hydrogen peroxide dosage would not improve the ozonation but rather lower the treatment efficiency.
In operation costs, the highest cost needed for ozonation of phenolic wastewater at the phenol initial concentration of 600 mg/L and pH 9 is about 36.7 NT＄/ton.

摘要……………………………………………………………I
英文摘要………………………………………………………III
致謝……………………………………………………………V
目錄……………………………………………………………VI
圖表索引………………………………………………………IX
第一章 緒論……………………………………………………1
第二章 文獻回顧………………………………………………4
2.1 臭氧與臭氧化反應……………………………………4
2.1.1 臭氧之一般性質……………………………………4
2.1.2 臭氧之製造…………………………………………7
2.1.3 臭氧自解反應機制及動力學………………………8
2.1.4 臭氧化反應之機制…………………………………12
2.2 臭氧/過氧化氫程序之反應機制………………………16
2.3 酚類有機化合物的一般性質……………………………18
2.4 酚之臭氧化反應機制……………………………………25
2.5 臭氧反應器種類………………………………………30
2.5.1 一般傳統反應器…………………………………30
2.5.2 本研究設備之基本構造及原理…………………31
第三章 實驗設備與方法………………………………………34
3.1 實驗設備………………………………………………39
3.2 實驗藥品與配製方法.…………………………………44
3.3 分析測定方法…………………………………………47
3.3.1 過氧化氫之定量……………………………………47
3.3.2 臭氧利用率…………………………………………48
3.3.3 總有機碳(TOC)分析…………………………………52
3.3.4 ADMI色度值 之分析………………………………53
3.4 實驗步驟………………………………………………55
3.4.1 預備實驗……………………………………………55
3.4.2 背景實驗……………………………………………60
3.4.3 以臭氧程序處理含酚水溶液實驗…………………61
3.4.4 以臭氧/過氧化氫程序處理含酚水溶液實驗………62
第四章 結果與討論……………………………………………64
4.1 背景實驗…………………………………………………65
4.1.1 酚水溶液揮發解離實驗……………………………65
4.1.2 過氧化氫之穩定性實驗……………………………66
4.1.3 以過氧氫分解酚水溶液實驗………………………66
4.2 以臭氧程序處理酚水溶液……………………………71
4.2.1 pH之影響……………………………………………71
4.2.1.A pH值對臭氧分解酚水溶液效果之影響………72
4.2.1.B pH值對TOC去除之影響……………………83
4.2.1.C pH值對臭氧利用率之影響…………………88
4.2.2 臭氧進口濃度效應…………………………………93
4.2.2.A 臭氧進口濃度與酚初濃度劑量比對酚水溶液分
解之影響………………………………………93
4.2.2.B 臭氧進口濃度對臭氧利用率…………………99
4.2.2.C 臭氧進口濃度對TOC值之影響………………102
4.2.3 反應過程中ADMI色度值變化情形………………105
4.3 以臭氧過氧化氫程序處理含酚水溶液之反應特性…116
4.3.1 酚水溶液濃度降解之動力分析……………………116
4.3.2 加入過氧化氫對酚水溶液降解之影響…………122
4.3.3 加入過氧化氫對於TOC去除之影響………………125
4.3.4 加入過氧化氫對於臭氧利用率之影響…………131
4.4 操作成本評估………………………………………135
第五章 結論與建議…………………………………………136
5.1 結論……………………………………………………136
5.2 建議………………………………………………139
第六章參考文獻……………………………………………140
第七章符號索引………………………………………………152
作者簡介 ………………………………………………………153

環保通訊社，「環保法令」，(1993)
阮國棟，「廢水中各種酚類(Phenols)去除之理論與實務」，工業污染防治，第三卷，第三期，第88-103頁，(1984)
姚俊宇，「廢水中含酚的去除技術」，石油通訊技術篇，第三卷第二期，第18-22頁，(1991)
顧洋，「紫外線/臭氧氧化程序在廢水處理上之應用」，工業污染防治，第56期，第248-261頁，(1995)
顧洋，「化學氧化在廢水處理上之應用」，化工技術，第四卷第六期，第179-184頁，(1996)
徐永錢，黃全億，毛玉麟，「捲氣式攪拌槽中臭氧對有色水溶液脫色之研究」，第十九屆廢水處理技術研討會論文集，台中，第172-182頁,(1994)
徐永錢，黃全億，鍾大華，「改善傳統氣液攪拌槽中臭氧處理模擬染整廢水之研究」，第二十屆廢水處理技術研討會論文集，台南，第6-141~6-148頁，(1995)
徐永錢，黃全億，「捲氣式臭氧處理設備之最佳幾何因子及臭氧質傳係數」，第二十一屆廢水處理技術研討會論文集，台北，第465-472頁，(1996)
徐永錢，方長福，「新捲氣式設備中以臭氧處理數種染料水溶液」，第二十一屆廢水處理技術研討會論文集，台北，第148-154頁，(1996)
徐永錢、方長福、陳佳存、黃全億，「染料水溶液在捲氣反應器中之臭氧脫色及其質傳」，第二十二屆廢水研討會，台中，第261-268頁，(1997)
劉鎮宗，「酚類化合物檢測方法比較」，環境工程會刊，第六卷第一期，(1995)
行政院環境保護署環境檢驗所，「水質檢驗方法彙編」，第161-166頁 (1992)
Anderson, G. L., ”Ozonation of High Levels of Phenol in Water”, AIChE Symp., Vol. 73, No. 166, p. 265-271 (1977).
Andreozzi, R., V. Caprio, M. G., D’Amore, and A. Insola, “Quinoxaline Ozonation in Aqueous Solution”, Ozone Sci. Eng., Vol. 11, p.329-335 (1989).
Abrardi, V., G. Rovero, G. Baldi, S. Sicorai and R. Conti, “Hydrodynamic of a Gas-Liquid reactor Stirred with a Multi-Impeller System”, Trans. IChemE., Vol. 68, pp. 517-522 (1990)
APHA, AWWA and WPCF, “Standard method for the examination of wastewater”, 18th, Ed, pp. 2-1~2-8 2120 method (1992).
Bader, H. and J. Hoigne, “Determination of Ozone in Water by the Indigo Method”, Water Res., Vol. 15, pp. 449-456 (1981).
Bailey, P. S., Ozonation in Organic Chemistry: Volume Ⅱ-Nonolefinic Compounds, Academic Press, New York (1982)
Bellamy, W. D., G. T. Hick, P. A Mueller and N. Ziemba, “Treatment of VOC-Contaminated Groundwater by Hydrogen Peroxide and Ozone Oxidation “, Res. J. WPCF, Vol. 63, No. 2, pp. 120-128 (1991)
Beltran, F. J., J. M. Encinar and J. F.Garcia-Araya, “Ozonation of o-Cresol in Aqueous Solutions”, Water Res., Vol. 24, p.1309-1316 (1990)
Beltran, F. J.; V. Gomez-Serrano and A. Duran, “Degradation Kinetics of p-Nitrophenol Ozonation in Water”, Water Res., Vol. 26, pp. 9-17 (1992).
Beltran, F. J., J. M. Encinar and J. F. Garcia-Araya, “Absorption Kinetics of Ozone in Aqueous o-Cresol Solutions”, Can. J. Chem. Eng., Vol. 70, p. 141 (1992).
Beltran, F. J., M. Gonzalez, F. J. Rivas and M. Marin, “Oxidation of Mecoprop in Water with Ozone and Ozone Combined with Hydrogen Peroxide”, Ind. Eng. Chem. Res., Vol. 33, pp. 125-136 (1994)
Beltran, F. J., O. Gabriel and J. Rivas, “Oxidation of Polynuclear Aromatic Hydrocarbons in water 4. Ozone Combined with Hydrogen Peroxide”, Ind. Eng. Chem. Res., Vol. 35, pp. 891-898 (1996)
Beltran, F. J., J. M. Encinar and J. M. Gonzalez, “Industrial Wastewater Advanced Oxidation. Part 2. Ozone Combined with Hydrogen Peroxide or UV Radiation”, Water Res., Vol. 31, No. 10, pp. 2415-2428 (1997)
Belschkov, V., G. Bardarska, H. Gulyas and I. Sekoulov, “ Degrdation of Triethylene Glycol Ether by Ozonation Combined with UV Irradiation or Hydrogen Peroxide Addition”, Water Sci. Technol., Vol. 36, No. 2-3, pp. 131-138 (1997)
Benitez, F. J., J. Beltran de Heredia , J. L. Acero and M. L. Pinilla, “Ozonation Kinetics of Phenolic Acids Present in Wastewaters from Olive Oil Mills”, Ind. Eng. Chem. Res., Vol. 36, pp. 638-644 (1997)
Benitez, F. J., M. Encinar and J. F. Garcia-Araya, “Ozone Treatment of Methylene Blue in Aqueous Solution”, Chem. Eng. Commun., Vol. 119, pp. 151-165 (1993)
Boari, G., A. Brunetti, R. Passino and A. Rozzi, “Anaerobic Digestion of Plive Oil Mill Wastewaters”, Agric. Wastes., Vol. 10, pp. 161-175 (1984)
Bollyky, L. J., "The Mass Transfer of Ozone into water: Energy Requirements-State of the Art", Ozone Sci. Eng., Vol. 3, pp.181-210 (1981)
Bridle, A. P. and A. K. Sachdev, “Thermal Destruction of Chlorophenol Residues”, 38th Purdue Industrial Waste Conference Proceedings, pp.299-309 (1984)
Bujalski, W. and A. W. Nienow, "The Use of Upward Pumping 45o Pitched Blade Turbine Impeller in Three-Phase Reactors", Chem. Eng. Sci., Vol. 45, pp. 415-421 (1990)
Buston, G. V., C. L. Greenstock, W. P. Helman and A. B. Rose, “Critical Review of Data Constants for Reaction of Hydrated Electrons, Hydrogen Atoms and Hydroxyl Radicals in Aqueous Solutions”, J. Phys. Chem. Ref. Data, Vol. 17, pp. 513-886 (1988)
Calvosa, L., A. Monteverdi, B. Rindone and G. Riva, "Ozone Oxidation of Compounds Resistant to Biological Degradation", Water Res., Vol. 25, No. 8, pp. 985-993 (1991)
Carpenter, K. J., " Fluid Processing in Agitated Vessels", Chem. Eng. Res. Des., Vol. 64, pp. 3-9 (1986)
Chapman C. M., A. W. Nienow, M. Cooke and J. C. Middletor, "Particle-Gas-Liquid Mixing in Stirred Vessels. Part Ⅱ: Gas-liquid Mixing", Chem. Eng. Des., Vol. 61, pp. 82-95 (1983)
Charpentier, J. C., "Mass Transfer Rates in Gas Liquid Absorbers and Reactor", In Advances in Chemical Eng., Vol. 11, pp. 3-133, Academic Press, New York (1981)
Christensen, H. S., H. Sehensted and H. Corfitzan, “Reactions of Hydroxyl Radicals with Hydrogen Peroxide at Ambient and Elevated Temperatures”, J. Phys. Chem., Vol. 86, pp. 55-68 (1982)
Cotton, F. A., Wilkinson, G., Advanced Inorganic Chemistry, 2nd, Interscience Publishers, a division of John Wiley & sons, Inc., New York, pp. 365-367 (1966)
Davis, A. P. and C. P. Huang, “The Removal of Substituted Phenols by a Photocatalytic Oxidation Process with Cadimium Sulfide”, Water Res., Vol. 24, No.5, pp. 543-550 (1990)
Dore, M., B. Langlais and B. Legube, “Mechanism of the Reaction of Ozone with Soluble Aromatic Pollutants”, Ozone Sci. Eng., Vol. 2, p. 39-54 (1980).
Eisenhauer, H. R., “Dephenolization by Ozonolysis”, Water Res., Vol. 5,
p.467-476 (1971)
Eisenhauer, H. R., “The Ozonization of Phenolic Wastes”, J. WPCF., Vol.
40, p.1887-1899 (1968)
Farhataziz and A. B. Ross, “Selected Specific of Reactions of Transients
from Water in Aqueous Solution”, National Bureau of Standards:
Washington DC, NSRDS-NBS59 (1977)
Forrester, S. E. and C. D. Rielly, Chem. Eng. Sci., Vol. 49(24B), pp. 5709-
5718 (1994).
Forni, L., D. Bahnemann and E. J. Hart, “Mechanism of the Hydroxid Ion
Initiated Decomposition of Ozone in Aqueous Solution”, J. Phys.
Chem., Vol. 86, pp. 255-261, (1982)
Gilbert, E. “Ozonation of Aromatic Compounds pH-Dependence”, Water Sci. Technol., Vol. 14, p. 849-861 (1982)
Gilbert, E. and S. Hoffmann-Glewe, “Ozonation of Sulfur-Containing Aliphatic Compounds in Aqueous Solution. I”, Ozone Sci. Eng., Vol. 11, p. 315-323 (1989).
Glaze, W. H. and J. W. Wang, “Advanced Oxidation Process. Description of Kinetic Model for the Oxidation of Harzardous Materials in Aqueous Media with Ozone and Hydrogen Peroxide in a Semibatch Reactor”, Ind. Eng. Chem. Res., Vol. 28, pp. 1573-1580 (1989)
Greaves, M. K., A. H. Kobbacy and G. G. Millington, "Gassed Power Dynamics of Disc Turbine Impeller ", Chem. Eng. Sci., Vol. 38, pp. 1909-1916 (1983)
Grau, P., “Textile Industry Wastewaters Treatment”, Water Sci. Tech., Vol. 24, No. 1, pp. 97-103 (1991)
Grigoropoulou, H. and C. Philippopoulos, “Homogeneous of Phenols in Aqueous Solution with Hydrogen Peroxide and Ferric Ions”, Water Sci. Tech., Vol. 36, No 2-3, pp. 151-154 (1997)
Gurol, M. D. and S. Nekouinaini, “Kinetic Behavior of Ozone in Aqueous Solution of Substituted Phenols”, Ind. Eng. Chem. Fundamentals, Vol. 23, p. 54-60 (1984)
Gurol, M. D., "Factors Controlling the Removal of Organic Pollutions in Ozone Reactors", J. American Water works Association, Vol. 77, No. 8, pp. 55-60 (1985)
Gurol, M. D. and R. Vatistas, “Oxidation of Phenolic Compounds by Ozone and Ozone + UV Radiation : A Comparative Study”, Water Res., Vol. 21, p. 895-900 (1987)
Hamdi, M., “Toxicity and Biodegradability of Olive Mill Wastewaters in Batch an Anaerobic Digestion.”, Appl. Biochem. & Biotech., Vol. 37, No. 2, pp. 155-163 (1992)
Han, S.-K., K. Ichikawa and H. Utsumi, “Quantitaive Analysis for the Enhancement of Hydroxyl Radical Generation by Phenols during Ozonation of Water”, Water Res., Vol. 32, No. 11, pp.3261-3266 (1998)
Heim, A. et al., ”Aeration of Bioreactor by Self-Aspirating Impellers “,
Chem. Eng. J. Biochem. Eng. J., Vol. 58, pp. 59-63 (1995).
Hews, C. G. and R. R. Davidson, “The Kinetics of Ozone Decomposition
and Reaction with Organics in Water”, AIChE J., Vol. 17, pp. 141-147
(1971)
Hoigne, J. and H. Bader, “The Role of Hydroxyl Radical Reactions in Ozonation Processes in Aqueous Solutions”, Water Res., Vol. 10, pp. 377-386(1976).
Hoigne, J. and H. Bader, "Ozone Initiated Oxidations of Solutes in Waster: A Reaction Kinetic Approach ", Prog. Wat. Technol., Vol. 10, pp. 657-671 (1978)
Hoigne, J. and H. Bader, "Ozonation of Water: Kinetics of Oxidation of Ammonia by Ozone and Hydroxyl Radicals", Environ. Sci. Technol., Vol. 12, pp. 79-84 (1978)
Hoigne, J. and H. Bader, "Rate Constant of Reactions of Ozone with Organic and Inorganic Compounds in Water－Ⅰ. Nondissociating Organic Compounds", Water Res., Vol. 17, pp. 185-194 (1983)
Hoigne, J. and H. Bader, "Rate Constant of Reactions of Ozone with Organic and Inorganic Compounds in Water－Ⅱ. Dissociating Organic Compounds", Water Res., Vol. 17, pp.185-194 (1983)
Hoigne, J., H. Bader, W. R. Haag and J. Staehelin, Water Res., Vol. 19, pp.993-1004 (1985)
Huang. C. P., C. Dong and Z. Tang, “Advanced Chemical Oxidation : Its Present Role and Potential Future in Hazardous waste Wreatment”, Waste Management, Vol. 13, pp.361-377 (1993).
Hsu, Y.-C. and C.-J. Huang, “Characteristics of a New Gas-Induced Reactor”, AIChE J., Vol. 42, No. 11, pp. 3146-3152 (1996).
Hsu, Y. C. and K. F. Huang, “Effects of Geometrical Factors on Liquid Mixing in a Gas-Induced Agitated Tank”, J. Chem. Tech. Biotechnol., Vol. 68, pp. 222-228 (1997a).
Hsu, Y.-C., and C.-J. Huang, “Ozone Transfer with Optimal Design of a New Gas-Induced Reactor”, AIChE J., Vol.43, No. 9, pp. 2336-2342 (1997b).
Hsu, Y. C., C. J. Huang and K. P. Chiang, “A Correlation of Mixing in an Agitated Tank with Gas Induction”, J. Chem. Eng. Japan, Vol. 30, No. 5, pp. 819-824 (1997a).
Hsu, Y. C., Robert Y. Peng and C. J. Huang, “Onset of Gas Induction, Power Consumption, Gas Holdup and Mass Transfer in a New Gas-Induced Reactor”, Chem. Eng. Sci., Vol. 52, No. 21/22, pp. 3883-3891 (1997b).
Hsu, Y. C., C. J. Huang, W. H. Yen and R. Y. Peng, “Onset of Gas-Induction and Power Consumption in an Agitated Tank Having Shortened Narrower Baffles”, J. Chem. Tech. Biotechnol., Vol. 71, No. 3, pp. 187-196 (1998a).
Joglekar, H. S., S. D. Sament and J. B. Joshi, “Kinetics of Wet Air Oxidation of Phenol and Substituted Phenols”, Water Res., Vol. 25, No. 2, pp. 135-145 (1991)
Joshi, J. B., A. B. Pandit and M. M. Sharma, "Mechanically Agitated Gas-liquid Reactors", Chem. Eng. Sci., Vol. 37, No. 6, pp. 813-844 (1982)
Joshi, J. B. and A. B. Pandit, "Mixing in Mechanically Agitated Gas Liquid Contactors, Bubble Column and Modified Bubble Column", Chem. Eng. Sci., Vol. 38, No. 8, pp. 1189-1215 (1983)
Joshi, J.B. and A. B. Pandit, "Mixing in Mechanically Agitated Gas Liquid Contactors, Bubble Column and Modified Bubble Column", Chem. Eng. Sci., Vol. 38, No. 8, pp. 1189-1215 (1983)
Kuo, C. H. and J. L. Weeks, ”A Kinetic Study of Ozone-Phenol Reaction in Aqueous Solutions”, AIChE J., Vol.25, pp. 583-592 (1979)
Masschelein, W. J., Ozonation Manual for Water and Wastewater Treatment, John Wiley & Sons, New York (1982)
Matsumura, M., H. Masunaga, K. Haraya and J. Kobayashi, "Effect of Gas Entrainment on the Power Requirement and Gas Holdup in an Aerated Stirred Tank", J. Frement. Technol., Vol. 56, pp. 128-138 (1978)
Matsumura, M., H. Masunaga and J. Kobayashi ,"Gas Absorption in an Aerated Stirred Tank at High Power Input ", J. Ferment. Technol., Vol. 57, pp. 107-116 (1979)
Mersmann, A., G. Schneider, H. Volt and E. Wenzig, "Selection and Design of Aerobic Bioreactors", Chem. Eng. Technol., Vol. 13, pp. 357-370 (1990)
Munter, R., S. Preis, S. Kamenev and E. Siirde, “Methodology of Ozone Introduction into Water and Wastewater Treatment”, Ozone Sci. Eng., Vol. 15, pp. 1993 (1993)
Murakami, Y., T. Hirose, M. Takao, T. Yamato and H. Fujiwara, "Flow Pattern in a Dual Mode Agitator with Simultaneous Up-and-Down and Rotational Motion of Impeller", J. Chem. Eng. Japan, Vol. 14, pp.498-499 (1981)
Nadezhdin, A. D., “ Mechanism of Ozone Decomposition in Water. The Role of Termination”, Ind. Chem. Res., Vol. 27, pp. 548-550 (1988)
Nakhla, G., S. Abuzaid and S. Farooq, “Activated Carbon Adsorption of Phenolics in Oxic system: Effect of pH and Temperature Variations”, Water Env. Res., Vol. 66, No. 6, pp.842-850 (1994)
Namboodri, C. G., W. S. Parkins and W. K. Walsh, “Decolorizing Dyes with Chlorine and Ozone : part I”, American Dyestuff Reporter, pp.17-22, march (1994).
Namboodri, C. G., W. S. Parkins and W. K. Walsh, “Decolorizing Dyes with Chlorine and Ozone : part II”, American Dyestuff Reporter, pp.17-26, April (1994).
Nocentini, M., F. Magelli and G. Fajner, "A Fluid-Dynamic Study of a Gas-Liquid, Non-Standard Vessel Stirred by Multiple Impellers", The Chem. Eng. Journal, Vol. 37, pp. 53-59, (1988)
Oldshue, J. Y., Fluid mixing technology, McGraw-Hill publications Co., New York (1983)
Ormad, P.; S. Cortes; A. Puig and T. L. Overlleiro, “Degradation of Organochloride Compound by O3 and O3/H2O2. “, Water Res., Vol. 31, No. 9, pp. 2387-2391 (1997)
Ouederni, A., J. C. Mora and R. S. Bes, "Ozone Absorption in Water: Mass Transfer and Solubility", Ozone Sci. Eng., Vol. 9, pp. 1-12 (1987)
Paillard, H., R. Brunet and M. Dore, “Optimal Conditions for Applying an Ozone-Hydrogen Peroxide Oxidizing system”, Water Res., Vol. 22, pp. 91-103 (1988)
Rice, R. G. and M. E. Browning, Ozone treatment of industrial wastewater, Noyes Data Corporation, New Jersey (1980)
Roth, J. A. and D. E. Sallivan, "Solubility of Ozone in Water", Ind. Eng. Chem. Fundam., Vol. 20, pp. 137-140 (1981)
Saravanan, K. and J. B. Joshi, “Gas Inducing Type Mechanically Agitated Contactors”, Ind. Eng. Chem. Res., Vol. 33, pp. 2226-2241 (1994).
Saravanan, K. and J. B. Joshi, “Gas Inducing Type Mechanically Agitated Contactors: Hydrodynamic Characteristics of Multiple Impellers”, Ind. Eng. Chem. Res., Vol. 34, pp. 2499-2514 (1995).
Saravanan, K., V. D. Mundale, A. W. Patwardhan and J. B. Joshi, “Mass Transfer and Hydrodynamic Characteristics of the Wemco Type of Flotation Cell”, Ind. Eng. Chem. Res., Vol. 35, pp. 1583-1602 (1996).
Sawant, S. B., and J. B. Joshi, “Onset Impeller Speed for Onset of Gas Induction in Gas-Inducing Types of Agitated Contacts”, Chem. Eng. J., Vol. 55, p. 338 (1979)
Shah, Y. T., B. G. Kelkar, S. P. Godbole and W. D. Deckwer, "Design Parameter Estimations for Bubble Column Reactors", AIChE J., Vol. 28, pp. 353-379 (1982)
Sharma, M. M. and P. V. Danckwerts, "Chemical Methods of Measuring Interfacial Area and Mass Transfer Coefficients in Two Fluid System", Br. Chem. Eng., Vol. 15, pp. 522-528 (1970)
Singer, P. C. and M. D. Gurol, “Dynamics of the Ozonation of Phenols-I. Experimental Observations”, Water Sci. Technol., Vol. 17, pp. 1163-1171 (1983)
Sotelo, J. L., F. J. Beltran, F. J. Benitez and J. Beltran-Heredia, "Henry's Law Constant for the Ozone-Water System", Water Res., Vol. 23, No. 10, pp. 1239-1246 (1989)
Sotelo, J. L., F. J. Beltran and M. Gonzalez, "Ozonation of Aqueous Solutions of Resorcinol and Phloroglucinol －Ⅰ.Stoichiometry and Absorption Kinetic Regime", Ind. Eng. Chem. Res., Vol. 29, pp. 2358-2367 (1990)
Sotelo, J. L., F. J. Beltran, M. Gonzalez and J. F. Garcia-Araya, "Ozonation of Aqueous Solutions of Resorcinol and Phloroglucinol －Ⅱ. Kinetics study", Ind. Eng. Chem. Res., Vol. 30, pp. 222-227 (1991)
Staehelin, J. and J. Hoigne, “Decomposition of Ozone in Water: Rate of Initiation by Hydroxide Ions and Hydrogen Peroxide”, J. Environ. Sci. Technol., Vol. 16, pp. 676-682 (1982)
Staehelin, J. and J. Hoigne, "Decomposition of Ozone in Water in the Presence of Organic Solutes Acting as Promoters and Inhibitors of Radical Chain Reactions", Environ. Sci. Technol., Vol. 19, No. 12, pp. 1206-1213 (1985)
Stowell, J. P., J. N. Jensen and A. S. Weber, “Sequential Chemical / Biological Oxidation of 2-Chlorophenol”, Water Sci. Technol., Vol. 26, No. 9-11, pp. 2085-2087 (1992).
Sverak, S. and M. Hruby, "Gases Entrainment from the Liquid Surface of Vessels with Mechanical Agitators", Int. Chem. Eng., Vol. 21, pp. 519-526 (1981)
Takahashi, N., T. Nakai, Y. Satoh and Y. Katoh, “Variation of Biodegradability of Nitrogenous Organic Compounds by Ozonation”, Water Sci. Tech., Vol. 28, No. 7, pp. 1563-1570 (1994).
Tanaka, M. and T. Izumi, "Gas Entrainment in Stirred-tank Reactors ", Chem. Eng. Res. Des., Vol. 65, pp. 195-198 (1987)
Tzitzi, M., D. V. Vayenas, and G. Lyberators, “Pretreatment of Textile Industry Wastewaters with Ozone”, Water Sci. Technol., Vol. 29, No. 9, pp. 195-198 (1994)
Ulberceft, Jaromir J. and Gary K. Patterson, Mixing of liquids by mechanical agitation, Gordon and Breach science Publishers, New York London Montreux Tokyo. (1985)
Van't Riet, K., "Review of Measuring Methods and Result in Non-viscous Gas-Liquid Mass Transfer in Stirred Vessels", Ind. Eng. Chem. Process Des. Dev., Vol. 18, pp. 357-364 (1979)
Warmoeskerken, Marijn M. C. G. and M. Jahn. Smith, "Gas-Liquid Dispersion with Pitched Blade Turbine", Chem. Eng. Commun., Vol. 25, pp. 11-29 (1984)
Warmoeskerken, M. M. C. G. and J. M. Smith, "The Hollow Blade Agitator for Dispersion and Transfer", Chem. Eng. Res. Des., Vol. 67, pp. 193-198 (1889)
White, D. A. and J. U. De. Villiers, "Rate of Induced Aeration in Agitated Vessels ", The Chem. Eng. J., Vol. 14, pp. 113-118 (1977).
Xu, S. C., H. D. Zhou, X. Y. Wei and J. Lu, “The pH Dependence and Effects of the Oxidative Products of some Aromatic Compounds in Ozonation under UV Irradiation”, Ozone Sci. Eng., Vol. 11, No.3 pp.281~296 (1989).
Yurteri, C. and M. D. Gurol, "Evaluation of Kinetic Parameter for the Ozonation of Organic Micropollutants", Water Sci. Technol., Vol. 21, Brighton, pp. 465-476 (1989)