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研究生:邱樹國
論文名稱:環盤電極研究鎳鐵合金之動力行為
論文名稱(外文):Use Rotation Ring Disk To Study The Kinetic Behavior Of Nickel-Iron Alloy
指導教授:尹庚鳴
學位類別:碩士
校院名稱:元智大學
系所名稱:化學工程研究所
學門:工程學門
學類:化學工程學類
論文種類:學術論文
論文出版年:2001
畢業學年度:89
語文別:中文
中文關鍵詞:鎳鐵合金電鍍旋轉環盤電極錯合劑
外文關鍵詞:nickel-iron electrodepositionrotating ring-disk electrodecomplexing agent
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我們建立一套即時快速的鎳鐵合金電鍍過程分析工具。利用旋轉環盤電極(RRDE)之雙工作電極特性能分別操控環與盤電位,我們能對電鍍合金成份,以及鍍液穩定性做一分析。工作的內容包含:( i )以盤上合金鍍層剝離法,求取Ni-Fe合金電鍍之各分電流密度。部分剝除電荷會被環收集因為在環上Fe(Ⅱ)會被氧化成Fe(Ⅲ)。根據收集效率的觀念我們可以算出各別的反應速率; (ii) 在含錯合劑之剝離液中,剝離盤上鎳鐵合金鍍層方式來算出金屬離子錯合反應率。我們可以評估不同錯合劑對Fe(Ⅱ)或Ni(Ⅱ)之錯合效應,研究增進鑄液穩定性的方法。

We develop a fast analytical method for nickel-iron electrodeposition system. Due to the double working electrode nature characteristics of RRDE which can individually control ring and disk potential, we can evaluate the alloy composition and the stability of the plating bath. The content of the study includes : (i) Measurement of the Ni-Fe alloy partial current densities by stripping the deposited alloy on the disk. Part of the stripping charges are collected by the ring by oxidizing Fe(II) to Fe(III). With the concept of collection efficiency, one can calculate the individual reaction rates. (ii) Determine the complexation rate of the metal ions by stripping the disk nickel-iron alloy on the complexant-containing solution. We may evaluate the effects of various complexants on Fe(II) or Ni(II) and to find the method to improve the bath stability.

中文摘要
英文摘要
目錄
圖目錄
第一章緒論…………………………………………………………….1
1-1文獻回顧……………………………………………………….1
1-2 實驗目的………………………………………………………2
第二章 利用環盤電極快速分析添加劑對鎳鐵合金電鍍影響 ………3
2-1 前言……………………………………………………………3
2-2 原理……………………………………………………………4
2-3 實驗部分………………………………………………………7
2-3-1 實驗藥品…………………………………………………7
2-3-2 儀器與設備………………………………………………8
2-3-3 實驗步驟………………………………………………….9
2-4 結果與討論…………………………………………………...11
第三章 鍍液穩定鍍分析………………………………………………35
3-1 前言…………………………………………………………..35
3-2 原理…………………………………………………………..36
3-3 實驗步驟……………………………………………………..37
3-4 結果與討論…………………………………………………….39
3-5 結論…………………………………………………………….43
第四章線性掃描(LSV,Linear sweep voltammetry)研究鍍液特性..56
4-1前言及原理………………………………………………………56
4-2 實驗步驟………………………………………………………..56
4-3 結果與討論……………………………………………………...58
4-4 結論……………………………………………………………...61
第五章 未來發展與方向………………………………………………74

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