臺灣博碩士論文加值系統

本實驗使用電漿輔助化學氣相沈積法研製密封碳鍍層光纖。碳鍍層厚度固定為100 nm，研究不同的氫氣/甲烷流量混合比對密封碳鍍層性質的影響。實驗期間分別使用雷射拉曼光譜儀及原子力顯微鏡來量測碳鍍層之結構及其表面粗度。然後使用拉伸試驗機量測碳鍍層光纖之拉伸強度，最後將完成鍍膜的光纖浸泡於液態氮中進行低溫試驗，並利用光學顯微鏡觀察碳鍍層表面之裂縫分佈情形。結果顯示，由於氫氣/甲烷氣體流量比增加，氫原子蝕刻碳鍍層表面而有利於類鑽相的成長並使碳鍍層之表面粗度值降低。另外，拉伸強度隨氣體流量比增加而增加，而應力誘發之裂縫密度則隨氣體流量比增加而降低。研究亦發現，應力誘發裂縫的密度與拉伸強度兩者的變化受到碳鍍層之結構及表面粗度的影響。

Hermetically carbon-coated optical fibers were prepared by Plasma enhanced chemical vapor deposition. The effect of hydrogen/methane ration on properties of carbon coatings with thickness 100 nm was researched. During the experiment, the structures and surface roughness of carbon coatings were determined by Laser Raman Spectrometry and atom force microscopy, respectively. Then, the tensile strengths of carbon-coated optical fibers were measured by the tensile machine. Finally, carbon-coated optical fibers were immersed in the liquid nitrogen for one day and stress induced cracks on the surface of carbon coatings were observed using the optical microscope. As a result, because of the increase of hydrogen/methane ratio, the effect of hydrogen etching advantaged the growth of diamond-like phase and decreased the surface roughness of carbon coatings. Alternatively, the tensile strength increased with hydrogen/methane ratio increased, but the density of stressed cracks decreased with hydrogen/methane ratio increased. From this experiment, we also found the changes of the density of stressed cracks and tensile strength were effected by structures and surface roughness of carbon coatings.

中文摘要
英文摘要
總目錄
圖目錄
表目錄
第一章 緒論
第二章 實驗原理
第三章 實驗步驟
第四章 結果與討論
第五章 結論
參考資料
誌謝
作者簡介

參考資料1.K. C. Kao and G. A. Hockham,〝Dielectric-fiber Surface Waveguides for Optical Fiber〞, Proc. IEE, 133, 1966.2.W. A. Gambling,〝The Rise and Rise of Optical Fibers〞, IEEE Journal on Selected Topics in Quantum Electronics, Vol. 6, No. 6, pp. 1084, 2000.3.Gred Keiser,〝Optical Fiber Communication〞, Second Edition, McGraw-Hill, New York, 1991.4.Charles K. Kao, 〝Optical Fiber System： Technology, Design, and Applications〞, McGraw-Hill, New York, 1982.5.吳曜東,〝光纖原理與應用〞, 全華科技圖書公司, 1997.6.龔祖德, 〝光纖通訊技術〞, 全華科技圖書公司, 1997.7.P. C. P. Bouten and G. deWith, 〝Crack Nucleation at The Surface of Stressed Fibers〞, Journal of Applied Physics, Vol. 64, No. 8, pp. 3890, 1988.8.Akira Iino, Masahide Kuwabara, and Kunio Kokura,〝Mechanisms of Hydrogen-induced Losses in Silica-based Optical Fibers〞, Journal of Lightwave Technology, Vol. 8, No. 11, pp. 1675, 1990.9.Janet L. (Armstrong) Mrotek, M. John Matthewson, and Charles R. Kurkjian,〝Diffusion of Moisture Through Optical Fiber Coatings 〞, Journal of Lightwave Technology, Vol. 19, No. 7, pp. 988, 2001.10.Allen H. Cherin, 〝An Introduction to Optical Fibers〞, McGraw-Hill, New York, 1983.11.汪建民,〝陶瓷技術手冊(下) 〞, 中華民國粉末冶金協會, pp. 677, 1994.12.C. R. Kurkjian, J. T. Krause, and M. J. Mattewson,〝Strength and Fatigue of Silica Optical Fibers〞, Journal of Lightwave Technology, Vol. 7, No.9, pp. 1360, 1989.13.M. M. Bubnov, E. M. Dianov, and S. L. Semjonov, 〝Maximum Value of Fatigue Parameter n for Hermetically Coated Silica Glass Fibers〞, Tech. Dig. Optical Fiber Commun. Conf., paper ThF2, 1992.14.K. E. Lu, G. S. Glaesemann, R. V. Vandewoestine, and G. Kar, 〝Recent Development in Hermetically Coated Optical Fiber〞, Journal of Lightwave Technology, Vol. 6, No. 2, pp, 240, 1988.15.S. Aisenberg, 〝Properties and Application of Diamond-like Carbon Films〞, Journal of Vacuum and Science Technology, Vol. 2, No. 2, pp. 369, 1984.16.John P. Powers, 〝An Introduction to Fiber Optic Systems〞, Aksen Associates, Boston, 1993.17.T. Nozawa, D. Tanaka, A. Wada, and R. Yamauchi, 〝Novel Metal-coated Solderable Optical Fibers〞, Tech. Dig. Optical Fiber Commun. Conf., Paper ThF3, 1992.18.D. R. Biswas, 〝Optical Fiber Coatings of Biomedical Applications〞, Optical Engineerings, Vol. 31, No. 7, pp. 1400, 1992.19.D. L. Griscom, K. M. Golant, A. L. Tomashuk, D. V. Pavlov, and Yu. A. Tarabrin,〝γ-radiation Resistance of Aluminum-coated All-silica Optical Fibers Fabricated Using Different Type of Silica in The Core〞, Applied Physics Letter, Vol. 69, pp. 322, 1996.20.Vasken Hagopian,〝Radiation Damage of Quartz Fibers〞, Nuclear Physics B, Vol. 78, pp. 635, 1999.21.H. S. Seo, U. C. Paek, K. Oh, and C. R. Kurkjian, 〝Melt Coating of Tin on Silica Optical Fiber〞, Journal of Lightwave Technology, Vol. 16, No.12, pp. 2355, 1998.22.Sara M. Chen, 〝Electroplated Hermetic Fiber〞, Electronic Components and Tech. Conf., 48th, pp. 418, 1998.23.S. L. Semjonov, M. M. Bubnov, N. B. Kurinov, and A. G. Schebuniaev,〝Stability of Mechanical Properties of Silica Based Optical Fibers under γ-radiation〞, Radecs 97 4th European conf., 1998.24.Boonsong Sutapun, Massood Tabib-Azar, and Alex Kazemi, 〝Elasto Optic Fiber Optic Bragg Grating Sensors for Multiplexed Hydrogen Sensing Pd-coated〞, Sensors and Actuators B, Vol. 60, pp. 27, 1999.25.Miroslav Sedlar and Ladislav Pust, 〝Preparation of Cobalt Doped Nickel Ferrite Thin Films on Optical Fibers by Dip-coating Technique〞, Ceramics International, Vol. 21, pp. 21, 1995.26.N. Yoshizawa, H. Tada, and Y. Katsuyama, 〝Strength Improvement and Fusion Splicing for Carbon-coated Optical Fibers〞, Journal of Lightwave Technology, Vol. 9, No.4, pp. 417, 1991.27.Y. Katsuyama, N. Yoshizawa, and T. Yashiro, 〝Field Evaluation Result on Hermetically Coated Optical Fiber Cables for Practical Application〞, Journal of Lightwave Technology, Vol. 9, pp. 1041, 1991.28.D. P. Dowling, K. Donnelly, T. P. O'Brien, A. O'Leary, T. C. Kelly, and W. Neuberger,〝Application of Diamond-like Carbon Films as Hermetic Coatings on Optical Fibers〞, Diamond and Related Materials, Vol. 5, pp. 492, 1996.29.Daryl Inniss and John Krause, 〝Hermetic Splice over Coating〞, Tech. Dig. Optical Fiber Commun. Conf., paper ThG4, 1991.30.N. Yoshizawa and Y. Katsuyama,〝High-strength Carbon-coated Optical Fiber〞, Electronics Letters, Vol. 25, No. 21, pp. 1429, 1989.31.P. J. Lemaire, K. S. Kranz, K. L. Walker, R. G. Huff, and F. C. Dimarcello,〝Hydrogen Permeation in Optical Fibers with Hermetic Carbon Coatings〞, Electronics Letters, Vol. 24, No. 21, pp. 1323, 1988.32.Christian R. Wüthrich, Claude A. P. Muller, Glen R. Fox, and Hans G. Limberger, 〝High Modulation Efficiency Using Optical Fiber Coated with ZnO Piezoelectric Actuator〞, 1997 International Conference on Solid-State Sensors and Actuators, Chicago, June 16-19, 1997. 33.潘隆源, 〝光纖的密封鍍層之設計及製造〞, 材料科學研究所 碩士論文, 2000.34.D. S. Rickerby and A. Matthews, 〝Advanced Surface Coatings: a Handbook of Surface Engineering〞, Chapman and Hall, New York.35.Hugh O. Pierson, 〝Handbook of Carbon, Graphite, Diamond and Fullerenes〞, Noyes Publications, New Jersey, 1993.36.John Robertson, 〝Amorphous Carbon〞, Current Opinion in Solid State and Materials Science, Vol. 1, pp. 557, 1996.37.Alfred Grill, 〝Diamond-like Carbon: State of the Art〞, Diamond and Related Materials, Vol. 8, pp. 428, 1999.38.Y. Lifshitz, 〝Diamond-like Carbon-Present Status〞, Diamond and Related Materials, Vol. 8, pp. 1659, 1999.39.Aicha Elshabini-Riad and Fred D. Barlow Ⅲ, 〝Thin Film Technology Handbook〞, McGraw-Hill, New York, 1997. 40.E. Suhir and T. M. Sullivan, 〝Analysis of Interfacial Thermal Stress and Adhesive Strength of Biannular Cylinders〞, Int., Dolids Structures, Vol. 26, pp. 581, 1990.41.S. T. Shiue and Y. S. Lin, 〝Thermal Stresses in Metal-Coated Optical Fibers〞, Journal of Applied Physics, Vol. 83, pp. 5719, 1998.42.汪建明 主編, 〝材料分析〞, 中國材料科學學會.43.Kenji k. Hirakuri, Takumi Minorikiawa, Gernot Friedbacher, and Manfred Grasserbauer,〝Thin film Characterization of Diamond-like Carbon Film Prepared by r.f. Plasma Chemical Vapor Deposition〞, Thin Solid Film, 302, pp. 5, 1997.44.Nobuyuki Yoshizawa, Hidenobu Tada, and Yutaka Katsuyama, 〝Strength Improvement and Fusion Splicing for Carbon-Coated Optical Fiber 〞, Journal of Lightwave Technology, Vol. 9, No. 4, pp. 417, 1991.45.Nobuki Mutsukra, Shin-ichi Inoue, and Yoshio Machi, 〝Deposition Mechanism of Hydrogenated Hard-Carbon Films in A CH4 rf Discharge Plasma〞, Journal of Applied Physics. 72(1), 1992.46.A. von Keudell and W. Moller, 〝A Combined Plasma-Surface Model for The Deposition of C:H Films From a Methane Plasma〞, Journal of Applied Physics, 75(12), 1994.47.Y. H. Lee, Y. S. Wu, M. S. Tsai, H. W. Ko, and T. Y. Wung, 〝Properties of Diamond Film by Chemical Deposition〞, Chinese Journal of Materials Science, Vol. 25, No. 3, pp. 163, 1993.48.Matthias Meier and Achim von Keudell,〝Hydrogen Elimination as a Key Step for The Formation of Polymer-like Hydrocarbon Films〞, Journal of Applied Physics, 90(7), 2001.