臺灣博碩士論文加值系統

摘要
本研究應用真空電弧熔煉爐配製TiNi 形狀記憶合金，施以固溶處理
後再分別進行時效處理和加工硬化，而後進行基本性質、坑穴沖蝕、水
砂沖蝕及氣砂沖蝕試驗。
實驗結果顯示Ti49Ni51 合金經過時效後由於析出硬化及應力誘發麻
田散體相(stress-induced martensitic，SIM)的效應，使抗沖蝕性增加；冷
加工雖可提高TiNi 合金之強度及硬度，但由於合金內部堆積大量差排使
延性及韌性大幅降低，而降低其抗沖蝕特性。
水砂沖蝕及氣砂沖蝕的行為相似，沖蝕後之顯微組織隨沖擊角度之
遞增，沖蝕形態均由狹長犁溝流線痕跡逐漸轉變為突起屑片重疊覆蓋的
趨勢。於水砂沖蝕試驗中TiNi 合金沖蝕速率隨沖擊角度之遞增而增加，
直到30〜45 度後開始降低。而氣砂沖蝕之沖蝕速率較水砂沖蝕為高，
氣砂沖蝕的最大重量損失出現在45〜60 度。
TiNi 合金於沖蝕後，晶格嚴重變形扭曲，致使XRD 之繞射峰變寬、
強度降低，並產生應力誘發麻田散相及應力誘發R 相之結構。

Abstract
The Ti49Ni51 and Ti50Ni50 alloys were used and prepared by vacuum arc
remelting technique. We studied the basic properties and erosion
characteristics of these alloys subjected to solution treatment, aging and cold
working. The erosion characteristics of these alloys have been systematically
studied by using cavitation erosion, gas-solid and liquid-solid impingement
tests.
Experimental results show that the aged Ti49Ni51 alloy can exhibit a
better erosion resistance because of the effects of precipitate hardening and
stress-induced martensitic (SIM) transformation. The work-hardening
increases the alloy’s strength and hardness, but the alloy’s erosion resistance
decreases because of the decreased ductility and toughness.
The gas-solid and liquid-solid impingement tests have similar erosion
behavior. The impinged morphologies exhibit a lot of long and narrow
furrows at low impingement angles, but the overlapped chips at high
impingement angles. In the liquid-solid impingement tests, there appears the
maximum erosion rate at the impinged angle of 30~45° . The erosion rate of
gas-solid impingement is larger than that in liquid-solid impingement. The
gas-solid impingement has the maximum erosion rate at impinged angle of
45~60° .
After impingement tests, the lattice structures of all TiNi alloys have
been distorted. This effect results in the broadened XRD peak with lower
peak intensity. Mean while, the stress-induced martensitic (SIM) and
stress-induced R-phase (SIR) transformation also occur during the
impingement.

中文摘要
英文摘要
總目錄
圖目錄
表目錄
第一章 前言
第二章 理論基礎與文獻回顧
第三章 實驗方法與流程
第四章 TiNi 合金強化後之基本性質
第五章 坑穴沖蝕
第六章 水砂沖蝕試驗
第七章 氣砂沖蝕試驗
第八章 結論
參考文獻
誌謝
作者簡介

參考文獻【1】L. Delaet, R.V. krishnan, H. Tas and H. Warlimont, J. Mater. Sci, 9(1974)1521.【2】R. V. krishnan,L. Delaey, H. Tas and H. Warlimont, J. Mater. Sci, 9(1974)1536.【3】H. Warlimont, L. Delaey, R. V. krishnan and H. Tas, J. Mater. Sci, 9(1974)1545.【4】K. Otsuka and K. Shimizu, Int. met. Rev., 31(1986)93.【5】A. P. Jardine, K.H.G.Ashbee and M. J. Bassett, J.Mater. Sci., 23(1988)4273.【6】W. J. Moberly, J. L. Pfoft, T. W. Duering and R. Sinclair, Acta Met.Mater., vol. 38(1990)2601.【7】H. C. Lin. and S. K. Wu, Acta Met., Vol. 42 (1994)1623.【8】H. C. Lin. and S. K. Wu, Scripta Met. Mater., 26(1992)59.【9】H. C. Lin. and S. K. Wu, Scripta Met. Mater., 25(1991)529.【10】H. C. Lin. and S. K. Wu, and M. T. Yeh, Metallurgical Transactions A.,vol. 24A(1993)2189.【11】L. Delaey, J. Janssen, D. Van de Mosselaer, G. Dullenkopf andA.Deruyttere, Script Met., 13(1979)73.【12】K. N. Meltn and O. Mercier, Acta Met., 27(1979)137.【13】W. J. Bueler and F. E. Wang, Ocean Eng., (1968)105.【14】H. Tobushi, Y. Ohashi and H. Tamamoto, experimental Mechanics.,32(4)(1992)340.【15】Y. shida and Y. Sugimoto, wear, 146(1991)219.【16】Y. Suzuki and T. Kuroyanagi, titanium Zirconium., 27(1979)67.【17】R. H. Richman, A. S. Ruo and D. Yang, Wear, 181-183(1995)80.【18】A. P. Jardine, Y. Field and H. Herman, J. Matre. ci.Lett.,10 (1991)943.【19】A. P. Jardine, Y. Field, H. Herman, D. R. Marantz and K. A. Kowalsky,Scripta Met. Mater., 24(1990)2391.【20】R. H. Richman, A.S. Rao and D. Yang, Wear, 157(1992)401.【21】K. S. Zhou, D.Z. Wang and M. Liu, Surface and Coating Techno.,34(1987)79.【22】H.C. Lin, S.K. Wu and C.H. Yeh, Wear, 249(2002)557.【23】K. G. Budinski, Surface Engineering for Wear Resistance, Prentice-Hall,Inc., New York, (1988)24-28.【24】L. C. Chang and T. A. Read, Trans. AIME., 189(1951)47.【25】C. M. Wayman, J. Metal. 32(1980)129.【26】L. Mc. D. Scketky, Scientific American, 241(1979)74.【27】A.Sato, E. Chishima, K. Soma and T. Mori, Acta Met., 30(1982) 1177.【28】M. Murakami and H. Suzuki, Proc. of Annual Meeting of theJapanInstitute of Metal, (1985)424.【29】T. Tadaki, K. Otsuka and K. Shimizu, Ann. Rev. Mater. Sci., 18(1988)25.【30】H. Warlimont and L. Delaey, Prog. Mater. Sci., 18(1974)1.【31】C. M. Wayman, Invited Paper Presented at AIME Annual Metting,(1985)Feb.【32】D. P. Dunne and C. M. Wayman, Met. Trans., 4(1973)147.【33】G. B. Olson and Cohen, Script Met., 9(1975)1247.【34】T. Saburi and S. Nenno, in: Proc. Int. Conf. On Solid to SolidPhaseTransformation, Asm, Metals Park, Ohio, (1982)1455.【35】T. Saburi, S. Nenno and C. M. Wayman, ICOMAT-79(1979)619.【36】M. Nishida and T. Honma, ICOMAT-82, 43(1982)C4-225.【37】M. NiShida and T. Homa, Scripta Met., 18(1984)138, 1293, 1299.【38】K. Otsuka and K. Shimizu, Metals Forum, 4(1981)142.【39 】K. Otsuka and C. M. Wayman, in: Review on theDeformationBehavior of Materials, (P. Feltham ed), Israel(1977)1267.【40】K. Otsuka , Proc. Int. Conf. On Solid in Solid Phase Transformation,TMs-AIME, Pittsburgh, Pa(USA)(1981)1267.【41】K. Otsuka, C. M. Wayman, K. Nakai, H. Sakamoto and K. Shimizu,Acta Met., 24(1976)207.【42】J. W. Christian, Met. Trans., 13(1982)509.【43】S. K.Wu and C. M. Wayman, Acta Met ., 37（1989）2805.【44】W. J. Buehler, J. V. Gilfrich and R. C. Wiley, J. Appl. Phys., 34 (1963)1475.【45】W. J. Buehler and F. E. Wang, Ocean Eng., 1(1968)105.【46】H. Kambic, S. Murabayashi, E. Shirey, C. Sutton, Y. Sugita, J. Kasick,H. Harasaki, Y. Nose and T. Oku, International J. ArtificalOrgans,11(6)(1988)487.【47】K. Otsuka, S. Sawamira and K. Shimizu, Phys. Stat. Sol. (a)., 5(1971)457.【48】O. Matsumoto, S. Miyazaki, K. Otsuka and H. Tamura, Acta Met.,35(1987)2137.【49】K. M. Nowles and D. A. Smith, Acta Met.,29(1981)101.【50】T. Saburi and C. M. Wayman, Acta Met., 27(1979)979.【51】T. Saburi and C. M. Wayman, Acta Met., 28(1980)15.【52】G. D. Sandrock, A.J. Perkins and R. F. Hehemann. Met. Trans., 2(1971) 2769.【53】C. M. Hwang, M. Meichle, M. B. Salamon and C. M. Wayman,Philosophical Magazine A, 47(1983)9.【54】E. Goo and R. Sinclair, Acta Met., 33(1985)1717.【55】X. Zhao, X. Wu and T. Ko, Acta Met., 37(1989)1783.【56】H. C. Ling and R. Kaplow, Met. Trans., 12A(1981)2101.【57】H. C. Ling and R. Kaplow, Met. Trans., 11A(1980)77.【58】C. M. Hwang, M. Meichle, M. B. Salamon and C. M. Wayman, Phil.Maf. A, 47(1983)34.【59】M. Nishida, C. M. Wayman and T. Hnma; Met. Trans.17A（1986）1505.【60】M. Nishida, C. M. Wayman ; Met. Sci. Eng. 93（1987）191.【61】S. K .Wu , H.C.Lin and T. S. Chou ; Scripta Met. Mater 23（1989）2043.【62】S. K. Wu and H. C. Lin ; Scripta Met. Mater 25（1991）1295.【63】T. Honma ; ICOMAT-86（1986）,709.【64】A. I.Lotokov , V. N. Grishkov , V. A. Udovenk and A. V. Kuzentsov ;Phys. Met.,54（1982）152.【65】Y. C. Hu ; Master’s thesis, NTU ,1990.【66】T. Saburi, T. Tatsumi and S. Nenno ; J. De Phys.43（1982）,C4-261.【67】C. M. Hwang, M. Meichle, M. B. Salamon and C. M. Wayman; Phil,Meg.A47（1983）9.【68】T. Tadaki , Y. Nakata, K. Shimizu and K. Otsuka; Trans. Jim.27（1986）731.【69】T. Saburi. S. Nenno and T. Fukada ; J. Less-Common Metals 125（1986）,157.【70】S. Miyazaki, Y. Ohmi, K. Otsuka and Y. Suzuki, J de Phys. （suppl.）,C4（1982）p.255.【71】S. Miyazaki and K. Otsuka, Met. Trans., Vol.17a（1986）p.53.【72】D. N. Abujudom, P. E. Thoma and S. Farabi,ICOMAT-89（1989）p.565.【73】T. Todoroki and H. Tamura, Trans. JIM,Vol.28（1987）p.83.【74】Y. Liu and P.G. Mccormick ISIJ Inteeernatioal ,Vol.29（1989）p.417.【75】H.C. Lin, S.K.Wu, T.S. Chou and H.P. Kao, Acta Met., Vol.39（1991）p.2609.【76】H.C. Lin S.K. Wu and J.C. Lin, Material Chem. Phys. Vol..37（1994）p.184.【77】H.C. Lin and S.K. Wu, Met Trans., Vol.24A（1993）p.294.【78】H.C. Lin and S.K. Wu, Scripta Met., Vol.26(1992)p.59.【79 】M. G. Fontana, N. D. Greene, Corrosion Eng., McGraw-HillBookCompany, New York, (1978)84-87.【80】J. A. Roberson and Clayton T. Crowe, Eng. Fluid Mechanics,5thed.,McGraw-Hill Book Company, New York, (1993)182.【81】J. K. Vennard and Robert L. Street, Elementary Fluid Mechanics, 6thed. McGraw-Hill Book Company, New York, (1982)327, 672.【82】劉君祖，牛頓現代科技大百科，第13 冊-物理科學(I)-物理篇，牛頓出版股份有限公司，(1989)35。【83】W.H. Huang, K.C. Chen and J.L. He, Wear (2002) 459【84】J. G. Auret, O. F. R. A. Damm, G. J. Wright, and F. P. A. Robinson.“Cavitation Erosion of Copper and Aluminum in Water at ElevatedTemperature,” Tribology International, 26（1993）421-429【85】D. A. Woodford, Metall. Trans., 3(1972)1137.【86】B. C. S. Rao and D. H. Buckley, Mater. Sci. Eng., 67(1984)55.【87】A. Karimi and J. L. Martin, Int. Metall, Rev., 30,1(1986)1.【88】Y. K. Zhou and F. G. Hammitt, Wear, 86(1983)299.【89 】F. G. Hammitt, Cavitation and Multiphase Flow Phenomena,McGraw-Hill, New York,1980.【90】A. Thiruvendagam, Cavitation erosion, Appl. Mech. Rev.,24,3, (1971).【91】McGuinness, Terence and Thiruvengadam, A., “Cavitation Erosion-Corrosion Modeling”, Erosion, Wear, and Interfaces with Corrosion,ASTM STP 567( 1974)30-55.【92】W. C. Leith, Cavitation damage of materials, Eng. J.(Can.), 2(1)(1959)43.【93 】A. Thirurendagam, A unified theory of cavitation damage, J.BasicEng., 85(3)(1963)365.【94】J. M. Hobbs, in Erosion by Cavitation or Impingement, ASTM STP408, 1967, 159-179.【95】M. S. Plesset, and R. E. Devine, J. of Basic Eng., Transactions,American Society of Mechanical Engineers, Dec. 1966.【96】I. Finnie, “ Erosion of Surface by Solid Particle”, (1960)87-103.【97】Robert Bellman and Alan Lery, Wear, 70(1981)1-27.【98】K. Z. Gahr, Microstructure and Wear of Material, Tribology Series 10,Elserier Science Publishing Company, INC., 1987.【99】S. Timosheko,”Theory of Elasticity”, 1st ed., Mcgraw-Hill BookCompany Inc., New York,(1934).【100】K. Wellilnger and H. Uetz, Meterial Purf., 9(1967)153-160.【101】A. W. Ruff., Mater. Sci. and Technology, 16(1979).【102】S. S. Aptehar, “Erosion of white cast iron and stellite”, Wear ofMaterials. ASME, New York, (1985)677-686.【103】R. Richardson, Wear, 10(1967)291.【104】Standard Test Method for Cavitation Erosion Using VibratoryApparatus. ASTM Standard G32-92, 1992.【105】A. W. RUFF and L. K. IVES Wear , 35（1975）195-1993【106】P. Chevallier, A. B. Vannes, and A. Forner, Wear, 186-187(1995)210-214【107】Standard Test for Conducting Erosion Tests by Solid ParticleImpingement Using Gas Jets, ASTM G76-95.【108】J. G. He and F. G. Hamnitt, Wear, 76(1982)269-292.【109】W. J. Tomlinson and A.S. Bransden, Wear, 185(1995)59-65.【110】Ke Song Zhou and H. Herman, Wear, 80(1982)101-113.【111 】W. J. Tomlinson and S. J. Matthews, J. of Mater. Sci., 29(1994)1101-1108【112】Y. J. Zhou and F.G. Hammitt, Wear, 87(1983)163-171.【113】H. G. Feller and Y. Kharrazi, Wear, 93(1984)249-260.【114】R. H. Richman and W. P. McNaughton, Wear, 140(1990)63-82.【115】S. M. Ahmed, K. Hokkirigawa, and R. Oba, Wear, 177(1994)129- 137.【116】V. Riddei, P. Pacor and J. K. Appeldoorn, Wear, 27(1974)99-108.【117】C.T. Kwok, H. C. Man and F. T. Cheng, Mater. Sci. and Eng., A242(1998)108-120.【118】J. M. Robinson, S. Anderson, R. D. Knutsen and R. C. Reed, Mater.Sci. and Techno., 11(1995)611.【119 】P. Chevallier, A. B. Vannes and A. Forner, Wear, 186- 187(1995)210-214.【120】O. Mercier, K.N. Melton, G. Gremaud and J. Hagi, J. Appl. Phys.,51(1980)1833.【121】A. I. Lotkov, A. V. Kuznetsov, V. N. Griskov and A. A. Botaki, Proc.of Intl SMA Symp. Guilin, China, 1986, p153.【122】N. Nakanishi, “Shape Memory Effects in Alloys” ed. J. Perkins,Plenum Press, 1975, p147.【123】G. P. Tilloy and W. Sage, Wear, 16(1970)447-465.【124】G. P. Tilloy, Wear, 14(1969)63-79.【125】J. H. Neilson and A. Gilchrist, Wear, 11(1968)111-122.【126】E. Raask, Wear, 13(1969)301-305.【127】C.T. Morrison and R. O. Scattergood, Wear, 111(1986)1-13.【128】R. Bellman, JR. and Alan Levy, Wear, 70(1981)1-27.【129】I. M. Hutchings, R. E. Winter and J. E. Field, Proc. R. Soc. Lond.,A348(1976) 379-392.【130】R. E. Winter and I. M. Hutchings, Wear, 29(1974)181-194.【131】M. Naim and S. Bahadur, Wear, 94(1984)219-232.【132】Yoshiro Iwai and Kazuyuki Nambu, Wear, 210 (1997) 211-219.【133】J. W. Tichler, A. W. J. de Gee, H. C. van Elst, Erosion, Wear, andInterfaces with Corrosion, STP 567, ASTM, Philadelphia, PA, 1974,pp.56.【134】K. K. Womg and H. Mcl. Clark, Wear, 160 (1993) 95-104.