臺灣博碩士論文加值系統

我們以萘胺類當親核性試劑，利用鈀錯合物催化使烯丙醇類上的碳-氧鍵斷裂。此外，以鉑催化烯丙基化反應很少被注意到，故我們報告利用鉑錯合物催化苯胺類與烯丙醇類進行氮-烯丙基化反應的研究。就我們所知，這是第一個在鈦試劑的存在下，直接利用烯丙醇類使苯胺類進行鉑催化烯丙基化反應的例子。

We have recently reported our attempts of some successful applications of a process involving the C-O bond cleavage with allylic alcohols using aminonaphthalenes as nucleophiles catal-
yzed by palladium complexes. However, platinum-catalyzed allylation has attracted a little attraction. We report here a novel catalysis of platinum complex, which mediates N—allylation of anilines with allylic alcohols. This is, to our knowledge, the first example of platinum-catalyzed allylation of anilines by the dire- ct use of allylic alcohols in the presence of titanium reagents.

目 錄
中文摘要. . . . . . . . . . . . . . . . . . . . . . . . . 1
英文摘要. . . . . . . . . . . . . . . . . . . . . . . . . 2
第一章 總論. . . . . . . . . . . . . . . . . . . . . . 3
第二章 結果與討論
I. . . . . . . . . . . . . . . . . . . . . . . . . . .12
II. . . . . . . . . . . . . . . . . . . . . . . . . . 26
第三章 結論. . . . . . . . . . . . . . . . . . . . . .38
第四章 實驗部分
I. 實驗儀器與化學試藥. . . . . . . . . . . . . . . . . . 40
II. 合成方法
II-1. . . . . . . . . . . . . . . . . . . . . . . . . . .43
II-2. . . . . . . . . . . . . . . . . . . . . . . . . . .63
第五章 參考文獻. . . . . . . . . . . . . . . . . . . . 66

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