化學槽內毒性氣體發生外洩時，由於有效的防患措施設備不易裝設，因此屢屢釀成重大的工安與環保事故。如何降低化學槽內毒性化學氣體外洩所造成的災害，逐漸成為今日工業安全與環境保護的重要課題之一。由於噴霧氣流能產生大量液滴，增加與毒性化學氣體接觸之表面積，而噴霧氣流藉由廣大的表面積與毒性氣體產生化學反應，有效地消減毒性氣體，使得毒性氣體在大氣中的濃度下降。因此建立一個噴霧氣流消減毒性氣體的技術，將有助於提昇暨有設置工廠降低災害事故發生的機率，對於新設工廠製程的安全評估，提供一安全指標，供工廠作為規畫時的重要依據。

Accidental releases of chemical gas frequently cause serious individual matter and ruining of environment, therefore to prevent the chemical emergency for releases of toxic gas is very important nowadays. Liquid sprays can produce a lot of drops to increase surface area. Chemical reactions occurred in the large surface area between the drops and chemical gas molecules. The toxic gas are effectively reduced by reaction. For this reason, to found an applicable technique of liquid spray to mitigate accidental releases of toxic and to provide these information and guide for individual building is very important.

中文摘要…………………………………………………………… Ⅱ
英文摘要…………………………………………………………… Ⅲ
致謝………………………………………………………………… Ⅳ
目錄………………………………………………………………… Ⅴ
圖目錄……………………………………………………………… Ⅵ
表目錄……………………………………………………………… Ⅷ
符號說明…………………………………………………………… Ⅸ
第一章 緒論……………………………………………………. 1
第二章 物理模式………………………………………………. 16
第三章 數值方法………………………………………………. 19
3.1 氣體擴散模式………………………………………. 19
3.2 噴霧液滴大小分佈模式……………………………. 27
3.3 吸收性能模擬……………………………………… 31
3.3.1 剩餘容積比………………………………… 31
3.3.2 濃度效應…………………………………… 44
第四章 結果與討論……………………………………………. 53
4.1 剩餘容積比的影響………………………………… 53
4.2 濃度效應的影響……………………………………. 64
4.2.1 Langmuir模式………………………………. 64
4.2.2 Freundlich模式………………………………78
4.3 大氣風速變化之影響………………………………. 94
第五章 結論…………………………………………………… 108
參考資料…………………………………………………………….109

1.David P. Wright, “Chemical Accident Prevention and The Clean Air Amendments of 1990. Fact Sheet”. Washington, DC: U.S. Environment Protection Agency, September 1994.
2.易逸波, 『危險物質意外排放後果模擬國際研討講習會』紀實,工業安全科技, 34期。
3.M. ST-Geroges and J. M. Buchlin, “Detailed Single Spray Experimental Measurements and One Dimentional Modeling.”, Int. J. Multiphase Flow Vol. 20. No. 6. pp. 979-992. 1994.
4.M. ST-Geroges and J. M. Buchlin, M. L. Riethmuller, J. P. Lopez, J, Lieto and F. Griolet, “Fundamental Multidisciplinary Study of Liquid Sprays for Absoption of Pollutant or Toxic Cloud.”, Trans IchemE, Vol 70, Part B, November 1992, pp 205-213.
5.K. W. Schatz and R. P. Koopman, “Water Spray Mitigation of Hydrofluoric Acid Releases.”, J. Loss Prev. Process Ind., 1990, Vol 3, April, pp 222-233.
6.V. M. Fthenakis and V. Zakkay, “A Theoretical Study of Absorption of Toxic Gases by Spraying.”, J. Loss Prev. Process Ind., 1990, Vol 3, pp 197-206.
7.V. M. Fthenakis and D. N. Blewitt, “Recent Developments in Modeling Mitigation of Accidental Releases of Hazardous Gases.”, J. Loss Prev. Process Ind., 1995, Volume 8, Number 2, pp 71-76.
8.V. M. Fthenakis, ”Water-spray Systems for Mitigating Accidental Indoor Releases of Water-soluble Gases.”, J. Loss Prev. Process Ind., 2001, Vol 14, pp 205-211.
9.Jean-Marie Buchlin, “Mitigation of problem cloud.”, J. Loss Prev. Process Ind., 1994, Vol 7, pp 167-174.
10.Wei-Hsin Chen, “Unsteady Absorption of Sulfer Dioxide by an Atmospheric Water droplet with Internal Circulation.”, Atmospheric Environment, 2001, Vol 35, pp 2375-2393.
11.Schwartz, S. E. “Chemistry of Mutiphase Atmospheric Systems”, (Ed. W. jaeschke), NATO ASI Series. Volume G6, Springer-Verlag, Berlin, FRG, 1986.
12.Thomas C. Voltaggio, “Hydrogen Fluoride Study-Final Report, Report to Congress Section 112(n)(6) Clean Air Act As Amended”, United States Environmental Protection Agency, EPA550-R-93-01, September 1993.
13.Eileen B. Segal, “First Aid for a Unique Acid, HF: A Sequel.”, Chemical Health & Safety, January / February 2000, pp18-23.
14.徐振盛，唐大維，『空氣污染防制工程』，淑馨出版社，1995。
15.Pasquill, F., 1976: “Atmospheric Dispersion Parameters in Gaussian Plume Modeling: Part 2. Possible Requirements of Change in the Turner Workbook Values.” EPA-600/4-76-030b.
16.D. Bruce Turner, “Workbook of Atmospheric Dispersion Estimates”, 1994.
17.Aihara, T., Taga, M. and Haraguchi, T., “Heat Transfer from a Uniform Heat Flux Wedge in Air-Water Mist Flow.”, Int. J. Heat Mass Transfer, Vol. 22, 1979, pp.51-60.
18.Hishida, K., Maeda, M. and Ikai, S., “Study on Heat Transfer in a Binary Mist Flow” Trans. Of The Japan Society of Mech. Eng., Vol.47, 1981, pp.1279-1286.
19.鄭淵源，”濾材吸附有害氣體過程之數值計算”，交通大學機械工程所碩士論文，2000。
20.吳國增， “Chemical Thermocynamics”，復漢出版社，1975。
21.Danckwerts, P. V., “Gas-Liquid Reactions”(McGraw-Hill), 1970.