臺灣博碩士論文加值系統

包裝紙之用量在先進國家為包裝材料之首，惟在需抗濕、抗水性之場合卻有其先天缺憾，雖可以PE材料塗佈改善，然其成本高且回收不易，若能針對此等不足加以改善，實為人民之福，國家之幸。本研究以易回收使用之紙張採輕量塗佈方式以增進紙品之抗濕、抗水性並探討其對紙品性質之影響。
採用白土、濕磨碳酸鈣及絹雲母為顏料，苯乙烯丁二烯乳膠及磷酸酯化澱粉、陽性澱粉、疏水澱粉為成分接著劑，以不同組合方式配製塗料、分析塗料性質、進行塗佈並對製成紙品之抗濕、抗水性與光學、印刷性質詳加探討。
實驗結果顯示，完全採用乳膠或澱粉為接著劑時，顏料種類對輕塗紙之抗水性並無大差異；當以白土為顏料時，乳膠為接著劑之紙品有最佳抗水度，以澱粉為接著劑之紙品有最佳抗濕性。
以白土為顏料，接著劑為13﹪乳膠時，輕塗包裝紙之白度不受乳膠玻璃轉移溫度、凝膠含量及粒徑之影響。凝膠含量低（30﹪）時，紙品不透明度最好；凝膠含量越高光澤度越佳；凝膠含量80﹪，粒徑90-100 nm時有最佳平滑度；玻璃轉移溫度10℃、凝膠含量50﹪、粒徑150-160 nm時可展現最佳印後光澤度。就IGT印刷適性之乾強與濕強性質言，皆十分優異，呈現最佳等級；接著劑改採13﹪澱粉時，白度性質差異不大；使用疏水澱粉1者有最佳不透明度，然光澤度、印後光澤度與IGT乾強相當差；使用疏水澱粉2可有最佳平滑度；就IGT濕強性質言，皆呈現最差之濕拉毛；以4﹪疏水澱粉2取代部分乳膠時，對紙品之不透明度、平滑度及光澤度不具特別效用，然其印後光澤度則平均較僅使用SB乳膠為接著劑者高，IGT印刷性質之乾強皆良好，濕強則皆為無濕抵抗及濕拉毛。
與市售產品相較，實驗室塗佈所得紙品之最佳抗濕、抗水性較市售之最佳者高出約79.0﹪及333.3﹪，差異非常明顯；而紙品之白度、光澤度、印後光澤度與IGT乾強性質兩者在伯仲之間，濕強性質則皆較市售產品佳，而不透明度略高市售品，平滑度卻遠低於市售者，應係實驗室塗佈紙壓光不足所致。

The consumption of package paper is the highest among all kinds of packaging materials in the developed country, there is, however, unavoidable drawback when moisture-proof and water-resistant are concerned. These could though be improved with a coated PE layer, the high cost and environmental concern will eventually limit or even inhibit its application. The objectives of this study were to enhance the water-resistance and moisture-proof of the package paper by surfacing the easy-to-recycle coating color onto a packing grade basepaper and to examine the characteristics of the resulted light weight coated package paper.
Clay, CaCO3 and mica were used as pigments, while SB latex and various modified starches were taken as co-binders to produce the designated coating colors. Analysis of the coating colors of different compositions was conducted and the water-resistance, moisture-proof, opacity and printed characteristics of the coated paper, were investigated.
The results showed that pigments hardly have any effect on the water - resistance for LWC while SB latex or starch was used as the binder. Using SB latex as binder gave a coating layer with the best water-resistance, the highest moisture-proof resulted from the use of starch binder, on the contrary.
The glass transition temperature (Tg), gel content (Gc) and particle size (Ps) of an SB latex have nothing to do with the brightness of the coated package paper when clay was used to the pigment and 13 % of SB latex was applied in the color. The lower the gel content (30% in this study) of the SB latex, the higher the opacity of the coated package paper. The higher the gel content (80%in this study), the better the gloss. The best smoothness could be expected when gel content was 80 % and particle size 90-100 nm. The best printed gloss resulted from using an SB latex of 10℃ Tg, 50% Gc and 150-160 nm Ps. The IGT dry and wet picking showed the best results when 13 % SB latex was used.
Almost the same brightness as that with 13 % SB latex, was recorded for a binder of 13% starch, while clay was used as pigment. Water-resistant starch 1, as a binder, provided the best opacity, for the coated paper, though the gloss, printed gloss and IGT dry picking was fairly unsatisfactory. Water-resistant starch 2 observed the best smoothness and the worst wet picking. Binder composed of 4 % water-resistant starch 2 to partially replace the SB latex gave the maximum IGT dry and wet picking resistance besides observing a much better. The opacity, printed gloss than those from only SB latex. Smoothness and gloss of the LWC package paper not upgraded though this replacement.
Comparing with the market coated package paper, the best water-resistant and moisture-proof Lab products showed a significant 79.0 % to 333.3% quality than the former ones. Brightness, gloss, printed gloss and IGT dry picking properties differed not much between the two. The IGT wet picking was better than those in the market, and the opacity was better than that of the two commercial ones, though the smoothness was much less than A and B commercial products probably due to the lack of complete calendaring in the university Lab.

中文摘要 -----------------------------------------------------Ⅰ
英文摘要 -----------------------------------------------------Ⅳ
誌謝 ---------------------------------------------------------Ⅷ
目錄 ---------------------------------------------------------Ⅸ
表目錄 -------------------------------------------------------ⅩⅡ
圖目錄 -------------------------------------------------------ⅩⅤ
第一章 前言
第一節 研究背景 -----------------------------------------------1
第二節 研究目的 -----------------------------------------------2
第二章 文獻回顧
第一節 提升紙品塗層抗濕、抗水之方法 ---------------------------3
第二節 塗料組成份對紙品性質之影響 -----------------------------6
第三節 輕塗包裝紙之塗料設計 -----------------------------------8
第四節 各種紙類中國國家標準之抗水度規範-----------------------18
第三章 原料性質
第一節 材料 --------------------------------------------------19
第二節 方法 --------------------------------------------------22
第三節 結果與討論 --------------------------------------------29
（一）SB乳膠性質測試 -----------------------------------------29
（二）澱粉性質 -----------------------------------------------32
（三）顏料之性質 ---------------------------------------------40
（四）原紙性質測定 -------------------------------------------41
第四章 塗料性質
第一節 材料 --------------------------------------------------45
第二節 方法 --------------------------------------------------47
第三節 結果與討論 --------------------------------------------49
（一）酸鹼值 -------------------------------------------------49
（二）高剪力粘度 ---------------------------------------------52
（三）保水度 -------------------------------------------------56
第五章 塗料組成份對輕塗包裝紙抗濕、抗水性之影響
第一節 材料 --------------------------------------------------63
第二節 方法 --------------------------------------------------64
第三節 結果與討論 --------------------------------------------70
（一）顏料對輕塗包裝紙抗水度之影響 ---------------------------70
（二）SB乳膠特質對輕塗包裝紙抗水度及透濕度之影響 -------------72
（三）澱粉添加對輕塗包裝紙抗水度及透濕度之影響 ---------------75
（四）實驗室輕塗包裝紙與市售產品之比較 -----------------------77
第六章 輕塗包裝紙之印刷適性
第一節 材料 --------------------------------------------------78
第二節 方法 --------------------------------------------------78
第三節 結果與討論 --------------------------------------------81
（一）乳膠特質對輕塗包裝紙印刷適性之影響 ---------------------81
（二）澱粉添加對輕塗包裝紙印刷適性之影響 ---------------------89
（三）實驗室輕塗包裝紙與市售產品之性質比較 ------------------102
第七章 結論 -------------------------------------------------104
參考文獻 ----------------------------------------------------107

王永煌 2000 丁苯乳膠在紙張塗佈之應用 私人通訊
林敏奇、陳建偉譯 1987 陽性澱粉改善上膠及留存
漿與紙 82：9∼14
邱俊雄 1984 合成橡膠乳液在造紙上之應用
漿與紙53：19∼20
周樹高 1997 “九五”期間大陸紙包裝製品市場前景預測分析 漿與紙200：4∼7
范立俊 1992 陽性馬鈴薯澱粉用於濕端添加之效應
漿與紙 139：21∼23
徐智龍 2001 塗料-組成、物性、配製 塗佈技術高級班
p.51∼55
許正治 1999 塗佈用顏料 表面處理與塗佈基本技術培訓班p.158∼188
姚獻平、鄭麗萍 1999 澱粉衍生物及其在造紙中的應用技術
中國輕工業出版社 p.49∼52
陸珩、何子萬 1989 紅外線光譜 有機分子光譜分析 p.13∼50
郭蘭生 1982 影響紙張不透明度之因子
漿與紙 27：27∼29
郭蘭生 1992a 塗佈紙之製造~談紙業界如何製造銅板紙（五）印刷與設計雜誌68（2）：96∼98
郭蘭生 1992b 塗佈紙之製造~談紙業界如何製造銅板紙（七）印刷與設計雜誌70（4）：136∼139
陳興國 1996 推廣紙製品-綠化世界 漿與紙194：52∼57
陳鴻銘 2001 紙塗佈技術-高分子合成乳膠的應用
高立圖書有限公司 p.4，52
陳忠輝 1997 印墨、紙張、印版在印刷機上諸問題之探討
漿與紙 206：4∼21
陳君忠 1987 陽性澱粉在造紙工程之應用
造紙用化學及機器研討會。p.3.1∼3.42
張燕萍 2001 變性澱粉製造與應用 化學工業出版社 p.1∼59
張友松 1999 變性澱粉生產與應用手冊 中國輕工業出版社p.74∼82,226∼228
黃貞甄 2002 SB乳膠對輕量塗佈紙性質之影響 國立屏東科技大學森林系碩士班碩士學位論文 p.27∼30
楊福馨 1996 可食性包裝研究進展 漿與紙187：30∼33
楊宏遠 1997 紙板塗佈加工與SBR乳膠的影響
漿紙技術 1（3）：45∼47
楊宏遠 1998a 紙板塗佈加工與SBR乳膠的影響
漿紙技術1（4）：29∼38
楊宏遠 1998b 紙板塗佈加工與SBR乳膠的影響
漿紙技術 2（3）：42∼52
鄭勝雄 1980 紙張塗佈工程 新文化彩色印書館 p.58∼67，
15∼25，261∼263
戴德發 1999 絹雲母性質。向陽礦業有限公司。
蘇裕昌 1996 造紙用藥品的基礎及應用（一）上膠劑─
內部上膠劑（上）漿紙技術 1（2）：1∼18
蘇裕昌 1997 造紙用藥品的基礎及應用（二）上膠劑─
內部上膠劑（下）漿紙技術 1（2）：1∼20
蘇裕昌 1999 紙張表面處理 表面處理與塗佈基本技術培訓班 p.136∼157
蘇裕昌 2000a 澱粉在造紙上的應用 漿紙技術 4(1)：1∼12
蘇裕昌 2000b 紙面剝起的發生及對策 漿紙技術 4(1)：39∼44
蘇裕昌 2000c 防水紙及防水紙板 漿紙技術 4（3）：1∼12
蘇裕昌 2001a 塗佈紙概論 塗佈技術高級班上課講義 p.4∼6
蘇裕昌 2001b 紙張表面處理 表面處理與塗佈基本技術培訓班上課講義 p.154∼155
內田明 1984 塗工紙品質に及ぼすバイダーの影響
紙パ技協誌38（12）：18∼23
濱口千里、蓼沼博 1976 合成ゴム18（1）：18
Alince, B. and P. Lepoutre, 1983 Viscosity, packing density and optical properties of pigment blends. Colloids and Surfaces 6(6)：155∼165
Casey, J.P. 1980 Pulp and Paper Chemistry and Chemical Technology.4(11)：2077∼2094
EngstrÖm, G. and V. Morin 1997 Analysis of porosity distribution in coating layers. Tappi J. 80(5)：203∼209
Greif, D.S. and J. C. Koval. 1990 Modified Starches:
Manufacture and Properties of Starch and Starch Products in Paper Coating. TAPPI PRESS p.29∼41
Hagemeyer, R. W. 1960 The effect of pigment combination and solids concentration on particle packing and coating paper characteristics. Tappi J. 43(3)：277∼288
Hayes, P. C. 1998 Styrene-Butadiene and Styrene-Acrylic G.M.Latices in Paper Coating Applications. Coating Materials: Pigment, Binders and Additives Short Courses. TAPPI Course Notes p.329∼356
Heiser, J.E. 1981 Review of latex binder formulations, effects on coated paper properties. PULP ＆ PAPER p.65∼72
Hoover,J.F. 1992 Styrene-Butadiene Latex in Paper and Paperboard Coating Applications, Coating Binders Short Course. TAPPI Course Notes p.85∼90
Jain, N. K. and S. K. Kataria 1984 Role of synthetic binder in pigment coating. Tappi J. 21(4)：18∼24
Kane, R. J. 1995 Paper coating additives-general description. Paper Coating Additives. p.1∼10
Macnair, K.A.1998 Styrene-Butadiene Latices.Synthetic Coating Adhesives.TAPPI PRESS p.1∼15
Chonde, Y. 1995 A review of wet coating structure: pigment/latex/cobinder interaction and its impact on rheology and runnability. Coating Fundamentals Symposium. TAPPI Proceedings p.57∼62
Reinbold, R and H. Ullrich, 1980 Possibility and limitations of high solid colors. Tappi J. 63（1）：47∼51
TAPPI 1986 TIS 0102-01 Literature references on the measurement of water retention of paper coatings. p.1∼6
Vincent, E.M. 1998 Binders Overview. Coating Materials: Pigment, Binders and Additives Short Courses. TAPPI Course Notes p.241∼255
Zijderveld, A. H. 1970 Converted Starches for Adhesives. Paper 12(11)：831∼837