臺灣博碩士論文加值系統

本篇論文是以中溫溶劑熱法合成出五個新穎的有機-無機混合結構的六價鉬砷(磷)酸鹽化合物：(H2DABCO)[(MoO2)(C2O4)(HAsO4)] (1)、(H2DABCO)2[(MoO2)2(C2O4)(AsO4)2] (2)、(H2DABCO)[(MoO2)(HPO4)2] × H2O (3)、(H2DABCO)[(MoO2)(OH)2(HPO4)] (4)以及(C5N2H8)2[(Mo3O8) (AsO4)2]·H2O (5)，利用單晶X光繞射儀鑑定其結構，熱分析儀來分析其熱性質。這五個化合物的結構型態有四個為一維鏈狀結構(化合物1~4)，一個為二維層狀結構(化合物5)。其化合物1~4的有機模板皆為 DABCO；化合物5的有機模板為C5H6N2。化合物1與化合物4具相同的structure topology，含有相同連結形式的無限鏈( [MoXO8] ¥, X= As or P )；化合物1與化合物2在結構上主要的差異為草酸根的鍵結形式不同，化合物1的草酸根位於末端的位置，有一端懸掛在無限鏈的兩旁，為mono-bidentate；化合物2的草酸根則是扮演橋基的角色，連接兩條無限鏈，為bis-bidentate。化合物3是MoO6八面體上的四個氧原子與兩個不同位置PO4四面體上的氧原子以共角的方式連結在一起，因此，在化合物3的無限鏈上，有四環的孔洞存在；化合物5則是一個新穎的結構型態，其MoO6八面體與AsO4四面體以共角形式相連結形成二維層狀結構，每一層皆具有四與八環孔洞。

目錄
摘要
第一章 緒論
Ⅰ. 簡介 1
Ⅱ. 研究動機 3
表 1-1 化合物的化學式及晶格常數簡介 6
第二章 研究方法
Ⅰ. 合成方法 7
Ⅱ. 使用藥品 9
Ⅲ. 鑑定方法 9
表 2-1 實驗合成步驟流程圖 18
第三章 合成、結構與性質探討
Ⅰ. (H2DABCO)[(MoO2)(C2O4)(HAsO4)] (1) 19
Ⅱ. (H2DABCO)2[(MoO2)2(C2O4)(AsO4)2] (2) 24
Ⅲ. (H2DABCO)[(MoO2)(HPO4)2] × H2O (3) 30
Ⅳ. (H2DABCO)[(MoO2)(OH)2(HPO4)] (4) 35
V. (C5N2H8)2[(Mo3O8)(AsO4)2]·H2O (5) 40
化合物1的結構相關圖 44
化合物2的結構相關圖 49
化合物3的結構相關圖 53
化合物4的結構相關圖 58
化合物5的結構相關圖 62
第四章 總結 64
參考文獻 70
附錄A 晶體結構解析的詳細資料表 74
附錄B 化合物的粉末 X-ray繞射圖比對 96

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