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研究生:賴慧玲
研究生(外文):Hui-Ling Lai
論文名稱:以機械合金法製備錫銀及錫銀鉍之無鉛銲錫粉末
論文名稱(外文):Lead-Free Sn-Ag and Sn-Ag-Bi Solder Powders Fabricated by Mechanical Alloying
指導教授:杜正恭杜正恭引用關係
指導教授(外文):Jenq-Gong Duh
學位類別:碩士
校院名稱:國立清華大學
系所名稱:材料科學工程學系
學門:工程學門
學類:材料工程學類
論文種類:學術論文
論文出版年:2002
畢業學年度:90
語文別:英文
論文頁數:99
中文關鍵詞:機械合金無鉛銲錫研磨機制界面反應
外文關鍵詞:mechanical alloyinglead-free solder alloymilling mechanisminterfacial reaction
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在電子構裝技術中,銲錫(solder)在矽晶片的組裝及連接上扮演了相當重要的角色。本研究即以機械合金方法(Mechanical Alloying Technique)製備Sn-3.5Ag及Sn-3.5Ag-4Bi系統之無鉛銲錫粉末。
為了深入了解Sn-Ag及Sn-Ag-Bi粉末之研磨機制,本文首先分別探討在不同研磨時間下粉末顆粒之形態變化。在Sn-Ag系統中,由於粉末較具延展性,因此會先被壓平成薄片狀。待繼續研磨至粉末被加工硬化後,原先形成之薄片開始被破碎成較小顆粒。隨著研磨時間增長,冷銲的效應也慢慢增大,因此被破碎之小顆粒開始形成較大的合金粒或錠狀。然而,在Sn-Ag-Bi系統中,所添加之4wt%鉍使得粉末間之銲接及合金作用受到限制。粉末在研磨之後開始聚集成球,但其顆粒與顆粒之間仍是呈現相互分離的狀態。因此,在此系統中,另外使用二階段研磨方式,先將錫、銀粉末進行研磨後再加入鉍,以進一步了解添加鉍對研磨機制所造成的影響。藉由二段式研磨,可得到顆粒更小之Sn-Ag-Bi粉末。實驗結果也發現,在研磨過程中不同粉末外貌與其結晶方向性(crystal orientation)有相當大的影響。其關聯可由XRD分析之(101)/(200)面強度比加以量化及討論。
由於在研磨過程中持續的破碎與變形將引入高能量,因此研磨媒
介扮演著相當重要的角色。利用陶瓷容器將會比鐵弗龍容器造成更大的撞擊能力,並促進相變化的發生。除此之外,較大的磨球可達到將鉍破碎的效果而使其溶入錫粉之中。相反的,小顆磨球則以混合效果較佳。因此當使用3mm磨球時,粉末可藉由研磨達到局部均勻的混合,而在138℃左右,亦即Sn-Bi共晶溫度,有一個小吸熱峰產生。以MA製成之Sn-Ag及Sn-Ag-Bi合金粉末,其熔點分別為221及203℃,因此將適用於240℃之迴溫過程。而在XRD分析中也發現Ag3Sn生成相,代表其成功之合金過程。在製備出合金粉末後,即可直接加入助銲劑(flux),調配成方便使用之銲錫膏。經過迴銲後,自製之錫膏與Ni-P/Cu/Si基板間形成接觸角小於20°之良好接合。

In the practice of package system, solder plays a crucial role in the assembly and interconnection of silicon die. In this study, mechanical alloying (MA) process was used to produce the lead free solder pastes of Sn-3.5Ag and Sn-3.5Ag-4Bi.
To understand the milling mechanism of Sn-3.5Ag and Sn-3.5Ag-4Bi powders during mechanical alloying, the particle morphology of MA powders milled for various time was observed and discussed. In the Sn-Ag system, the ductile powders were first flattened to thin slices, and then fractured to small particles caused by the work-hardening. With further milling, the fractured particles would cold weld to larger alloy ingots. However, in the Sn-Ag-Bi system, even 4wt% addition of Bi powder made the alloying and welding limited. Instead, “agglomeration” phenomenon was found. Another method of two-stage milling was also used to further understand the effect of addition of brittle components, in which the Sn-Ag-Bi powders were fractured to even smaller particles by the trapped Bi. It was found that the crystal orientation was affected by the particle morphology after various milling time. The intensity ratio of (101)/(200) Sn was calculated and plotted to correlate with the observed powder morphology discussed earlier.
Due to the induced high energy by repeated fracturing and welding, the grinding media play an important role during MA process. Ceramic container was used to provide stronger impact force, which could induce the phase transformation, than the Teflon container. In addition, it’s found that 1cm balls could fracture Bi particles and promote it dissolved into Sn matrix. On the contrary, the mixing effect was much predominant when using 3mm balls. MA powders after milling with 3mm balls showed a small endothermic peak from the DSC profile at 138C, which was the eutectic temperature of Sn-Bi. The melting points of MA powders in ceramic container were measured to be 221˚C and 203˚C, respectively, for Sn-3.5Ag and Sn-3.5Ag-4Bi from the DSC curves. The reduced melting point ensured the complete melting during reflow with a peak temperature of 240C. The formation of Ag3Sn was also observed from the X-ray diffraction peaks, indicating successful alloying by mechanical alloying. The solder pastes could thus be produced by adding flux into the MA powders. The wetting property of the solder joint was also evaluated. The as-prepared solder pastes on electroless Ni-P/Cu/Si exhibited sufficient metallurgical bonding with contact angles less than 20.

Contents
List of Tables IV
Figure Captions V
Abstract IX
Chapter I Introduction 1
Chapter II Literature Review 5
2.1 Electronic Package 5
2.1.1 Industry Trend 5
2.1.2 Solder Joint 9
2.2 Joint Materials 12
2.2.1 Solder Materials 12
2.2.2 Sn-Pb Solder 14
2.2.3 Lead-Free Solder 16
2.2.4 Metallization Layer 20
2.3 Mechanical Alloying 22
2.3.1 Introduction 22
2.3.2 Milling Mechanism 23
2.3.3 Solid Solubility 27
2.3.4 Diffusion in Mechanical Alloying 27
2.4 Joint Properties 31
2.4.1 Melting Temperature 31
2.4.2 Interfacial Reaction 31
2.4.3 Wettability 36
Chapter III Experimental Procedures 42
3.1 Fabrication of Lead Free Solder Pastes 42
3.1.1 Mechanical Alloying 42
3.1.2 Solder Pastes 42
3.2 Characterization of Powders 44
3.2.1 X-ray Diffraction 44
3.2.2 SEM and EPMA 44
3.2.3 Differential Scanning Calorimetry (DSC) 44
3.2.4 Wettability Test 45
3.3 Metallization Layer 45
3.4 Reflow Process 49
3.5 Microstructural Characterization 49
Chapter IV Results and Discussion 53
4.1 Milling Mechanism of Sn-Ag and Sn-Ag-Bi Solder Powders 53
4.1.1 Sn-Ag System 53
4.1.2 Sn-Ag-Bi System 55
4.1.3 Two-Stage Milling (Sn-Ag-Bi System) 56
4.1.4 Evolution of Morphology During MA Process 58
4.1.5 Milling-Induced Crystal Orientation 61
4.2 Sn-Ag and Sn-Ag-Bi Solder Powders Prepared by Mechanical Alloying 65
4.2.1 Process Parameters (Sn-Ag-Bi system) 65
4.2.2 Milling-Induced Phase Transformation and Dissolution 69
4.2.3 Wettability Test 76
4.3 Interfacial Reaction 79
4.3.1 As-Reflowed Sn-3.5Ag Solder Joints (Commercial Pastes) 79
4.3.2 As-Reflowed Sn-3.5Ag-4Bi Solder Joints 83
4.3.3 Phosphorus-Rich Layer 83
Chapter V Conclusions 90
References 92

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