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研究生:林柏青
研究生(外文):lin po ching
論文名稱:七種過渡金屬錯合物單晶結構之決定
論文名稱(外文):Crystal structure determination of seven transition metal complexes
指導教授:盧天惠
指導教授(外文):Tian-Huey Lu
學位類別:碩士
校院名稱:國立清華大學
系所名稱:物理學系
學門:自然科學學門
學類:物理學類
論文種類:學術論文
論文出版年:2002
畢業學年度:90
語文別:中文
論文頁數:108
中文關鍵詞:晶體結構配位化合物
外文關鍵詞:crystal structurecoordination compounds
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中文摘要
本論文將報告作者於碩士班研究單晶結構的成果,作者的工作是以X光繞射學的方法,來決定金屬有機化合物的單晶結構。論文中將會詳細說明下列七個單晶結構的金屬離子配位幾何結構和錯合物中之原子間的鍵長與鍵角。
晶體結構一 Dichloro bis-(2-phenylazoquinoline) complex of Ruthenium(II)
晶體結構二 ( Carbonato)「N,N’-bis(pyridyl-2-y)formylidine」-butane- 1,2-diamine) Cobalt(III)
晶體結構三 Bis[(3-aminopropyl methylamine) (dicyanamide) Copper(II) ]perchlorate
晶體結構四 Catena [bis(4-picoline) bis (dicynamide)Manganese(II)]
晶體結構五 Octa(1,1 azido) tetrakis (1-methyl-2-phenyl azo) imidazole tetra Copper(II)
晶體結構六 Dichloro (1-methyl-2-azo paratolyeimidazole) Zinc(II)
晶體結構七 Catena [bis(μ-aquo)(μ-succinato)(nirtrato)(bipyridine) Copper(II)

Abstract
This thesis contains research work of crystal structure determination of seven coordination compounds as a part of my master degree study. I have determined 7 crystal structures of metal organic complexes by using X ray diffraction. Their coordination geometries around the metal ion, and bond lengths and bond angles of the complexes are discussed in this thesis.
Crystal 1 Dichloro bis-(2-phenylazoquinoline) complex of Ruthenium(II)
Crystal 2 (Carbonato)「N,N’-bis(pyridyl-2-y)formylidine」-butane- 1,2-diamine) Cobalt(III)
Crystal 3 Bis[(3-aminopropyl methylamine) (dicyanamide) Copper(II) ]perchlorate
Crystal 4 Catena [bis(4-picoline) bis (dicynamide)Manganese(II)]
Crystal 5 Octa(1,1 azido) tetrakis (1-methyl-2-phenyl azo) imidazole tetra Copper(II)
Crystal 6 Dichloro (1-methyl-2-azo paratolyeimidazole) Zinc(II)
Crystal 7 Catena [bis(μ-aquo)(μ-succinato)(nirtrato)(bipyridine) Copper(II)

I 基本原理
 1.X光的產生與光譜                     1
2.晶體及對稱性                     2
 3.倒晶格空間與反射球                    3
 4.結構因數與相位問題                    5
 5.重原子法求相位 7
 6.直接法求相位 9
 7.傅立業綜合計算與結構建立 11
II單晶結構
1.晶體一Dichloro bis-(2-phenylazoquinoline) complex of henium(II) 16
 2.晶體二 (Carbonato)「N,N’-bis(pyridyl-2-y)formylidine」-butane- 1,2-diamine) Cobalt(III) 25
 3.晶體三 Bis[(3-aminopropyl methylamine) (dicyanamide) Copper(II) ] perchlorate 32
 4.晶體四 Catena [bis(4-picoline) bis (dicynamide)Manganese(II)] 39
 5.晶體五 Octa(1,1 azido) tetrakis (1-methyl-2-phenyl azo) imidazole tetra Copper(II) 48
 6.晶體六 Dichloro (1-methyl-2-azo paratolyeimidazole) Zinc(II) 55
 7.晶體七Catena [bis(μ-aquo)(μ-succinato)(nirtrato)(bipyridine) Copper(II) 61
8.結論 69
9.附錄 70
10.參考文獻 104

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