臺灣博碩士論文加值系統

此研究為探討以機械合金法合成Cu-Zr-Ti-Y系與Ni-Zr-Ti-Y系非晶質合金粉末的非晶質化行為，所得到的結果如下：
（1）銅基合金(Cu0.6Zr0.3Ti0.1)100-XYX﹝X=0、1、2、3、4、5、6、8、10﹞，Cu60-XZr30Ti10YX﹝X=2、6、8﹞，Cu60Zr30-XTi10YX﹝X=2、6、10﹞，Cu60Zr30Ti10-XYX﹝X=2、6﹞與鎳基合金(Ni0.67Zr0.1Ti0.23)100-XYX﹝X=0、2、6、8、10﹞、Ni67-XZr10Ti23YX﹝X=6、8、12﹞、Ni67Zr10-XTi23YX﹝X=6、8﹞、Ni67Zr10Ti23-XYX﹝X=6、8、10、14﹞經過五小時機械合金法處理後可形成完全非晶質合金粉末。
（2）以取代鋯元素或鈦元素的形式，添加6 at%釔元素於銅基合金Cu60Zr30Ti10中，可擴大其過冷液態區﹝ΔTX﹞，而得到具寬廣過冷液態區組成Cu60Zr24Ti10Y6﹝81K﹞與Cu60Zr30Ti4Y6 ﹝88K﹞。
（3）用適量釔元素取代鎳基合金Ni67Zr10Ti23的鎳元素，可使原本不具過冷液態區﹝ΔTX﹞的Ni67Zr10Ti23，出現寬廣過冷液態區﹝ΔTX﹞，其組成分別為Ni59Zr10Ti23Y8﹝70K﹞、Ni58Zr10Ti23Y9﹝60K﹞與Ni57Zr10Ti23Y10﹝55K﹞之非晶質合金粉末。
（4）本實驗非晶質合金粉末的Trg 值與過冷液態區﹝ΔTX﹞之間，並無存在一線性關係，而非晶質合金粉末形成塊狀非晶質之能力，取決於其過冷液態區﹝ΔTX﹞的大小。

中文摘要…………………………………………………………………..i
英文摘要…………………………………………………………………...iii
目錄……………………………………………………………………...iv
圖目錄…………………………………………………………………vii
表目錄……………………………………………………………….xiv
一、前言…………………………………………………………………...1
二、文獻回顧…………………………………………………………...…3
2-1 非晶質合金特性………………………………………...3
2-2 塊狀非晶質合金…………………………………………...5
2-3 塊狀非晶質合金之玻璃形成能力……………………………...8
2-4 鎳基塊狀非晶質合金…………………………………….…9
2-4.1 Ni-M-P系(M = Ti, Zr, Hf, Nb)…………..9
2-4.2 Ni-Nb-Cr-Mo-P-B系……………………….10
2-4.3 Ni-Ti-Zr-(Si,Sn)系……………………….10
2-4.4 Ni-Zr-Al-Y系………………………………11
2-5 銅基塊狀非晶質合金………………………………….11
2-5.1 Cu-Ti-Zr-Ni系……………………….…...12
2-5.2Cu-Ti-Ni-Si-B系………………………….…12
2-5.3 Cu-Zr-Ti系…………………………….……13
2-5.4 Cu-Hf-Ti系…………………………………14
2-5.5 Cu-Zr-Ti-Y系…………………………….14
2-5.6 Cu-Zr-Ti-Be系…………………………...15
2-5.7 Cu-Zr-Hf-Ti系…………………………...15
2-5.8 Cu-Ti-Zr-Ni-Si-Sn系…………………….16
三、實驗步驟……………………………………………………………30
3-1 機械合金處理………………………………………………….30
3-2 粉末結構分析………………………………………………….31
3-3 熱分析………………………………………………………….32
3-4 粉末型態觀察………………………………………………….32
3-5 實驗流程圖…………………………………………………….34
四、結果…………………………………………………………………36
4-1 粉末型態觀察………………………………………….36
4-1.1 Cu-Zr-Ti-Y………………………………….36
4-1.2 Ni-Zr-Ti-Y………………………………..37
4-2 X-ray繞射分析……………………………………………38
4-2.1 Cu-Zr-Ti-Y………………………………….38
4-2.2 Ni-Zr-Ti-Y………………………………..39
4-3熱分析……………………………………………………..40
4-3.1 Cu-Zr-Ti-Y………………………………….40
4-3.2 Ni-Zr-Ti-Y………………………………..41
五、討論………………………………………………………………...110
5-1 過冷液態區﹝ΔT﹞………………………………………110
5-2 簡化玻璃轉換溫度（Trg）………………………………115
六、結論………………………………………………………………..118
參考文獻…………………………………………...…………………..120

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