臺灣博碩士論文加值系統

IC塑膠構裝的注模膠封製程(Encapsulating Processes of IC Packaging)中，EMC在模具裡僅初凝固成形，其殘留應力相當大也造成EMC初成形後尺寸相當不穩定，更易於影響後續IC功能測試與可靠度測試，所以必須進行注模後烘烤製程，促使交連反應更趨近於穩定完整，發揮EMC被設計賦予的功能目的和適當的機械性質，而能夠保護IC晶片且構建電子構裝體(IC Packaging)達到穩定的結構。本論文主要針對EMC在注模後烘烤作業中，探討其熱機械性質的發展變化，利用DMA/ TMA和DSC儀器實驗所觀測的熱機械性質數據建構成Maxwell Model的數學模式化，亦即構建出EMC在注模後烘烤中熱機械性質的數學模式的構建方法(Methodology)，以方便在IC電子構裝體製程設計之初的工程預估及最後佳烘烤製程的設計。
本實驗結果發現：以較低的烘烤溫度，最終卻能得到較完整較高的彈性模數，顯然欲達成較佳效益的後烘烤結果，必須先了解EMC的聚合反應溫度與材料交連擴散的速率的對應關係。

EMC(Epoxy Molding Compound) is used to encapsulate IC on electronic packaging fields. There are some problems in the thermal process of curing EMC, such as package warpage, poor coplanarity of solder balls or lead, crack damages resulted from residual stress, delamination result from thermal stress… and so on. It is necessary for quality to minimize the warpage and deformation and improve potential damages. By the experiments of curing EMC to get the variants of thermal mechanical properties, we can modeling them by the mathematics equation of viscoelasticity and build up the methodology of modeling EMC. This study is to develop a methodology to calculate the modulus profiles during post-mold cure process and predict the EMC warpage caused by residual stress of incomplete cure and viscous stress during molding.

摘 要3
Abstract4
誌 謝5
目 錄6
圖表目錄9
符號說明11
縮寫說明12
第一章 緒論13
1-1 前言：13
1-2 EMC在IC構裝製程的運用14
1-2-1 IC構裝之PBGA構裝製程簡介14
1-2-2 電子構裝材料EMC之簡介15
1-2-3 商業化的EMC配方之簡介16
1-2-4 EMC的化學交連反應的簡介17
1-3 EMC材料的聚合固化特性及其對機械性質的影響18
1-4 EMC殘留應力的形成之簡介19
1-4-1 製程加工高分子流變過程產生殘留應力19
1-4-2 高分子聚合固化反應過程產生殘留應力21
1-4-3 複合材料結構匹配著不同物性產生殘留應力22
1-5 EMC應力鬆弛問題之簡介23
1-6 研究目的24
1-7 文獻回顧24
1-7-1 聚合體材料機械行為受內外在因素之影響24
1-7-1-1 應變速率之影響25
1-7-1-2 溫度之影響25
1-7-1-3 轉化率之影響25
1-7-1-4 填充物之影響26
1-7-2 聚合體材料的黏彈性回應26
1-7-3 線性網狀無定形聚合體材料之時間─溫度疊合原理27
1-7-4 時間─轉化率疊合原理28
1-7-5 WLF公式29
1-7-6 網狀組織的橡膠彈性的應用30
1-8 本文架構32
第二章 理論分析35
2-1 聚合體黏彈模式35
2-1-1 EMC黏彈模式參數求取過程36
2-2 殘留應力鬆弛實驗概念37
2-3 研究方法及步驟38
第三章 實驗方法與步驟39
3-1 實驗目的39
3-2 實驗流程步驟與規劃39
3-3 實驗設備與裝置44
3-3-1 EMC材料45
3-3-2 EMC試片製作之相關機台設備45
3-3-3 烘烤箱設備45
3-3-4 EMC材料與試片的貯存設備46
3-3-5 DSC熱分析儀46
3-3-6 DMA熱動態機械分析儀46
3-4 實驗步驟與方法47
第四章 實驗結果與討論49
4-1 PMC製程中EMC的熱機械性質之發展49
4-2 EMC之熱機械性質之數學模式建立50
4-2-1溫度與轉化率之相關數學式50
4-2-2 時間與溫度之相關數學式51
4-2-3 EMC的彈性模數之數學模式化53
第五章 綜合討論與未來發展60
5-1 實驗規劃部份60
5-2 實驗系統部份60
5-3 彈性模數之相關數學模式部份61
參考文獻63
自 述68

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