Ⅰ‧富烯與N-亞烷基甘胺酸酯的雜環[ 6+3 ]環化加成反應
相對於N-metalated azomethine ylides和各式的烯類會進行的[3+2]或[4+3]環化加成反應；我們利用富烯與N-亞甲苯基甘胺酸酯可以經由一個具有高立體選擇性以及可以one-pot的雜環[6+3]的環化加成反應來製備[2]pyrindine衍生物。
Ⅱ‧富烯與2H-氮代環丙烯進行雜環[ 6+3 ]環化加成反應
我們發現利用富烯與2H-氮代環丙烯在微波振盪器反應下可以得到雜環[4+2]環化加成反應以及路易士酸的催化下可進行雜環[6+3]的環化加成反應，並且利用雜環[6+3]的環化加成反應來應用在製備[2]pyrindine衍生物上。

Ⅰ‧Hetero [6+3]Cycloaddition of Fulvenes with N-Alkylidene
Glycine Ester
In contrast to the [3+2] or [4+3] cycloaddition of N-metalated azomethine ylides and various alkenes, N-benzylidene glycine ester reacts with fulvenes to give the hetero [6+3] cycloaddition adducts with high stereoselectivity, constituting an efficient and novel route to [2]-pyrindines.
Ⅱ‧Hetero [6+3] cycloaddition of Fulvenes with 2H-Azirine
2H-Azirine reacts with fulvenes to give either alkylated fulvene azirines (ultrasound) or the formal [6+3] cycloaddition adducts (Lewis acid). The later constitutes an efficient and novel route to [2]pyrindines.

第一章 緒論…………………………………………………………… 1
第二章 結果與討論………………………………………………… 11
2.1富烯與N-亞烷基甘胺酸酯的雜環[ 6+3 ]環化加成反應.. 11
2.2富烯與2H-氮代環丙烯進行雜環[ 6+3 ]環化加成反應. 20
第三章 實驗部分與光譜數據………………………………………... 32
3.1實驗儀器………………………………………………… . 32
3.2 一般的實驗方法…………………………………………. 33
3.3富烯與N-亞烷基甘胺酸酯進行雜環[ 6+3 ]環化反應實
驗及光譜數據…………………………………………… 34
3.4富烯與2H-氮代環丙烯進行雜環[ 6+3 ]環化加成反應之
實驗及光譜數據…………………………………………. 56
附圖…………………………………………………………… 82

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