臺灣博碩士論文加值系統

　　本實驗利用OODR光譜技術中的疊加方式，探索NaH分子D1Σ＋電子激發態，並針對此一能階可能會因為雙位能谷存在，導致所觀察到的光譜訊號形狀會有不規則的現象發生，做了深入的研究與探討。
　　實驗結果得到18（v* ~ v*+17）個振動能階數，其中轉動能階數分佈在J=0-11，共計有156個振轉能階數。

　　We made use of the technique of stepwise Optical-Optical Double Resonance Fluorescence Depletion Spectroscopy on NaH D1Σ＋.This study aims at abnormal lineshapes which are caused by the existense of potential barriers.
　　We have observed 156 rovibrational levels,18 vibrational levels and the range of J from 0 up to 11, of the D1Σ＋ state.

1.論文封面
2.口試合格證明
3.致謝
4.中文摘要..............................I
5.英文摘要.............................II
6.目錄................................III
7.表目錄................................V
8.圖目錄...............................VI
9.第一章 緒論...........................1
10.1-1 前言.............................1
11.1-2 文獻回顧.........................2
12.1-3 NaH的D1Σ＋電子激發態之光譜研究動機與準備................................5
13.第二章 基本原理.....................12
14.2-1分子結構.........................12
15.2-2分子光譜.........................13
16.2-3分子光譜OODR訊號形狀探討.........20
17.第三章 實驗.........................27
18.3-1實驗前準備事項...................27
19.3-2實驗藥品的製備...................27
20.3-3實驗儀器介紹.....................29
21.3-4實驗方法簡介.....................35
22.3-5實驗步驟.........................36
23.3-6實驗裝置.........................37
24.3-7實驗注意事項.....................38
25.第四章 結果與討論...................54
26.4-1 NaH分子存在之確認...............54
27.4-2 NaH分子D1Σ＋電子激發態訊號之確認.......................................55
28.4-3 NaH分子D1Σ＋電子激發態訊號之實驗結果...................................58
29.4-4 NaH分子D1Σ＋電子激發態訊號之實驗探討...................................58
30.第五章 結論.........................89
31.參考文獻............................90
32. 附錄...............................95

1. T. Hori, Z. Phys. 62, 352 (1930).
2. E. S. Sachs, J. Hinze, and N. H. Sabelli, J. Chem. Phys. 62, 3377 (1975).
3. E. S. Sachs, J. Hinze, and N. H. Sabelli, J. Chem. Phys. 62, 3367 (1975).
4. E. S. Sachs, J. Hinze, and N. H. Sabelli, J. Chem. Phys. 62, 3384 (1975).
5. F. B. Orth, W. C. Stwalley, S. C. Yang, and Y. K. Hsieh, J. Mol. Spectrosc. 79, 314 (1980).
6. W. T. Zemke and W. C.Stwalley, J. Chem. Phys. 69, 409 (1978).
7. A. M. Karo, M. A. Gardner, and J. R. Hiskes, J. Chem. Phys. 68, 1942 (1978).
8. W. T. Zemke, K. R. Way, and W. C. Stwalley, J. Chem. Phys. 69, 402 (1978).
9. R. E. Olson and B. Liu, J. Chem. Phys. 73, 2817 (1980).
10. C. R. Vidal and W. C. Stwalley, J. Chem. Phys. 80, 2697 (1984).
11. O. Nedelec and M. Giroud, J. Chem. Phys. 79, 2121 (1983).
12. S. J. Singer, K. F. Freed, and Y. B. Band, J. Chem. Phys. 81, 3091 (1984).
13. R. E. Olson and M. Kimura, Phys. Review A. 32, 3092 (1985).
14. U. Magg and H. Jones, Chem. Phys. Lett. 146, 415 (1988).
15. A. Pardo, J. J. Camacho, J. M. L. Poyato, and E. Martin, Chem. Phys. 121, 41 (1988).
16. A. G. Maki and W. B. Olson, J. Chem. Phys. 90, 6887 (1989).
17. W. C. Stwalley, W. T. Zemke, and S. C. Yang, J. Phys. Chem. Ref. Data. 20, 153 (1991).
18. W. C. Stwalley and W. T. Zemke, J. Phys. Chem. Ref. Data. 22, 87 (1993).
19. W. M. Ruyten and D. Keefer, Appl. Phys. Lett. 61, 880 (1992).
20. M. Rafi, N. Ali, K. Ahmad, I. A. Khan, M. A. Baig, and Z. Iqbal, J. Phys. B: At. Mol. Opt. Phys. 26, L129 (1993).
21. S. Lochbrunner, M. Motzkus, G. Pichler, K. L. Kompa, and P. Hering, Z. Phys. D. 38, 35 (1996).
22. J. T. Bahns, C. C. Tsai, B. Ji, J. T. Kim, G. Zhao, W.C. Stwalley, J.C. Bloch, and R. W. Field, J. Mol. Spectrosc. 186, 222 (1997).
23. W. C. Lin, J. J. Chen, and W. T. Luh, J. Phys. Chem. A. 101, 6709 (1997).
24. R. A. Tuwirqi, A. Bakry, M. Rafi, and Fayyazuddin, J. Phys. B: At. Mol. Opt. Phys. 30, 2033 (1997).
25. A. Yiannopoulou, G. H.Jeung, S. J. Park, H. S. Lee, and Y. S. Lee, Phys. Review A. 59, 1178 (1999).
26. J. J. Chen, W. T. Luh, and G. H. Jeung, J. Chem. Phys. 110, 4402 (1999).
27. A. S. Dickinson, R. Poteau, and F. X. Gadea, J. Phys. B: At. Mol. Opt. Phys. 32, 5451 (1999).
28. T. Leininger, F. X. Gadea, and A. S. Dickinson, J. Phys. B: At. Mol. Opt. Phys. 33, 1805 (2000).
29. Y. L. Huang, W. T. Luh, G. H. Jeung, and F. X. Gadea, J. Chem. Phys. 113,683 (2000).
30. F. P. Pesl, S. lutz, and K. Bergmann, Eur. Phys. J. D. 10, 247 (2000)
31. H. S. Lee, Y. S. Lee, and G. H. Jeung, Chem. Phys. Lett. 325, 46 (2000).
32. N. Geum, G. H. Jeung, A. Derevianko, R. Cote, and A. Dalgarno, J. Chem. Phys. 115, 5984 (2001).
33. A. Bhattacharjee and K. R. Dastidar, Phys. Review A. 65, 022701 (2002).
34. S. Demianiuk and K. Kolwas, J. Phys. B: At. Mol. Opt. Phys. 34, 1651 (2001).
35. B. K. Taylor and P. R. Newman, J. Chem. Phys. 118, 8770 (2003)
36. S. Ghosh, S. S. Bhattacharyya, and S. Saha, Phys. Review A. 67, 054701 (2003).
37. M. Merawa, D. Begue, and A. Dardelos, J. Phys. Chem. A. 107, 9628 (2003).
38. S. K. Hsu, J. J. Wang, P. Yu, C. Y. Wu, and W. T. Luh J. Phys. Chem. A. 106, 6279 (2002).
39. C. E. Moore,'Atomic Energy Levels', Vol. I, p. 89, NSRDS-NBS 35, Washington D.C. (1971).
40. H. M. Crosswhite, J. Res. of National Bureau of Standard-A. Phys. and Chem. 79, 17 (1975).
41. X. Zhu, A. H. Nur, and P. Misra, J Quant. Spectrosc. Radiative Transfer 52, 167 (1994).
42. D. R. Lide, 'Hanbook of Chemistry and Physics ', CRC Press, London (1995).
43. S. Gerstenkorn and P. Luc, 'Atlas du Spectre D’Absorption de la Molecule d’Iode', CNRS, Paris (1978).
44. S. Gerstenkorn and P. Luc, Rev. Phys. Appl. 14, 791 (1979).
45. I. N. Levine, 'Quantum Chemistry', Prentice Hall, Englewood Cliffs, (1991).
46. B. Douglas, D. Mcdaniel, and J. Alexander, 'Concepts and Models of Inorganic Chemistry', Wiley, New York (1994).
47. G. Herzberg, 'Molecular Spectra and Molecular Structure: Vol. 1, Spectra of Diatomic Molecules', Robert E. Krieger Publishing Co., Malabar, Florida (1989).
48. A. G. Gaydon, 'Dissociation Energies and Spectra of Diatomics Molecules', Chapman and Hall, London (1968).
49. C. J. Hendrik, 'The Theory of Molecular Spectroscopy', American Elsevier Pub. Co., New York (1976).
50. U. Fano, Phys. Rev. 124, 1866 (1961).
51. U. Fano, J. Optic. Soc. Am. 65, 979 (1975).
52. H. B. Lefebvre, and R. W. Field, 'Perturbations in the Spectra of Diatomic Molecules', Academic Press, Orlando (1986).
53. W. Demtröder,'Laser Spectroscopy ', Springer-Verlag, New York (1973).
54. J. I. Steinfeld, 'Molecules and Radiation：An Introduction to Modern Molecular Spectroscopy ', MIT Press, Cambridge (1985).
55. D. A. McQuarrie, 'Quantum chemistry', Wiley, New York (1992).
56. Z. G. Wang and H. R. Xia, 'Molecular and Laser Spectroscopy', Springer-Verlag, New York (1991).
57. K. H. Drexhage and F. P. Schafer, 'Dye Lasers', Springer-Verlag, New York (1990).
58. 李匡邦, 何東英, 許東明, '光譜化學分析', 揚智出版社, 臺北市 (1997).
59. 丁勝懋, '雷射工程導論', 中央出版社, 臺北市 (1995).
60. 謝從卿, 潘可傳, '物理化學', 安和出版社, 台北縣 (1987).
61. 石宇華, '量子化學', 安和出版社, 台北縣 (1987).
62. 柯以侃, 吳明珠, '儀器分析', 新聞京開發出版有限公司, 台北縣(2001).
63. 張耀元, '氣態氫化鈉分子高能位C1Σ+電子態之雙光子共振光譜研究', 國立成功大學化學所碩士論文(2000年六月).
64. 廖美惠, '確認氣態氫化鈉C1Σ+電子態振動量子數及其光譜研究',國立成功大學化學所碩士論文(2001年六月).
65. 吳國龍, '氣態氫化鈉C1Σ+能態高能位與低能位的光譜探討', 國立成功大學化學所碩士論文(2002年六月).
66. 呂采蓮, '氣態氫化鈉分子X1Σ＋能態誘發放射光譜及C1Σ＋能態雙位能阱的雙光子共振光譜', 國立成功大學化學所碩士論文(2003年六月).
67. 黃益龍, '雙原子鈉分子41Σ+u 電子態及附近區域位能之雷射光譜研究', 國立成功大學化學所碩士論文(2003年六月).
68. 吳佳穎, '單氫化鋰(7LiH)分子D1Σ+電子激發態之雙光共振(OODR)光譜學研究', 國立中興大學化學研究所碩士論文(2001年七月).
69. M. G. Maujean, J. Breton, and P. M. Guyon, Chem. Phys. Lett. 63, 591 (1979).
70. U. Fano, Phys. Review A. 2, 353 (1970).
71. E. J. Heller, J. Chem. Phys. 68, 683 (1977).