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研究生:李昆達
研究生(外文):Kun-ta Li
論文名稱:雙2-甲基羥口奎啉-2,6-二甲基苯氧基鋁化合物之一維和二維多核固態NMR研究
論文名稱(外文):Multi-nuclear One and Two Dimensional Solid State NMR Studies of Bis(2-Methyl-8-Quinolinolato)-(2,6-Dimethylphenolate)Aluminum
指導教授:丁尚武
學位類別:碩士
校院名稱:國立中山大學
系所名稱:化學系研究所
學門:自然科學學門
學類:化學學類
論文種類:學術論文
論文出版年:2004
畢業學年度:92
語文別:中文
論文頁數:62
中文關鍵詞:固態核磁共振有機發光二極體
外文關鍵詞:Solid-State NMROLED
相關次數:
  • 被引用被引用:0
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  • 下載下載:17
  • 收藏至我的研究室書目清單書目收藏:0
Bis(2-methyl-8-quinolinolato)-(2,6-dimethylphenolate)aluminum is a newly synthesized material suitable for manufacturing organic light-emitting devices (OLED). NMR parameters such as chemical shift, dipolar and quadrupolar tensors are intimately related to the electronic and geometric structures which are important for understanding its physical and chemical properties. In this work, we report the solid state NMR studies of this material. By using two-field (corresponding to proton resonance frequencies of 200 MHz, 500 MHz , respectively) 1D 1H MAS, 27Al MAS, 1H/13C CP/MAS and 2D 13C nutation MAS techniques, the chemical shift tensors of 13C and quadrupolar coupling constant of 27Al have been obtained. The relationship between these values and the light-emitting properties of this material is discussed.
第一章 緒論..............................................1
第二章 有機發光二極體....................................3
發光原理與元件基本結構............................5
電洞注入材料......................................6
電洞傳輸材料......................................7
電子傳輸與主發光體材料............................8
第三章 化學位移各向異性(CSA)、四級偶合常數(Qcc)及不對稱(η).....................................................12
化學位移各向異性(CSA)...........................12
二維跳角實驗(MAH)...............................14
魔角慢旋轉實驗(MAT).............................15
STAG、SSS及SASS實驗.............................15
2D-TOSS實驗.....................................17
二維章動/MAS實驗................................18
四極偶合常數(Qcc)及不對稱參數(η).....................................................18
第四章 實驗部分........................................22
樣品............................................22
實驗儀器........................................22
第五章 結果與討論......................................24
液態實驗結果與討論..............................24
固態實驗結果與討論..............................30
第六章 總結與未來展望..................................48
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