臺灣博碩士論文加值系統

摘要
利用salen和hydroxyquinoline 可以和三價的鋁、鎵、銦形成混配位基的八面體錯合物，而且具有不錯的熱穩定性。根據理論計算的結果得知，這些材料的HOMO位於hydroxyquinoline上，而LUMO則位於和hydroxyquinoline上氧原子對位的salen環上；在當成主發光材料時，Al(Salben-q)的對外量子效率為2.0 %，最大亮度20000 cd/m2，電流效率為6.1 cd/A，而以Al(Saldmpen(OMe)-q)為主發光層摻雜綠色客分子材料coumarin 6或紅色客分子材料DCJTB時都具有比以Alq為主發光層時的效率來得好，摻雜coumarin 6時，最大亮度接近140000 cd/m2，電流效率可達5.6 cd/A；摻雜DCJTB時，對外量子效率可達3.5 %，而且電流效率可達6.9 cd/A， CIE值為(0.59,0.39)，最大放光波長在616 nm。
利用benzoimidazole及acetylacetone為配位基可以和三價的IrCl3形成穩定的銥金屬磷光材料，其HOMO值約在5.1 eV ~ 5.5 eV之間，量子效率以Ir(ppy)3為標準品的測量下為1 ~ 13 %。在以元件結構：ITO/ NPB (50 nm)/ Ir complex:CBP (6.7 %, 30 nm)/ BCP (10 nm)/Alq (40 nm)/ Mg:Ag時，Ir(Bpb)2(acac)及Ir(Dpb)2(acac)的最大對外量子效率分別可達14.0 %及14.6 %，電流效率分別為54.7 cd/A (7.5V)及57.4 cd/A (6.0V)。

目錄
摘要 -----------------------------------------------------------------------------I
表目錄 ----------------------------------------------------------------------------II
圖目錄 ---------------------------------------------------------------------------III
第一章 緒論 ------------------------------------------------------------------1
第二章 有機鋁、鎵、銦金屬螯合物的合成與在電激發光元件的應用
前言---------------------------------------------------------------------18
結果與討論------------------------------------------------------------22
第一節 鋁、鎵、銦螯合物的合成-----------------------------------22
第二節 鋁、鎵、銦金屬螯合物的物理性質----------------------24
第三節 元件製作與性質探討--------------------------------------41
結論---------------------------------------------------------------------59
第三章 有機銥金屬磷光材料的合成與在電激發光元件的應用
前言----------------------------------------------------------------------61
結果與討論-------------------------------------------------------------65
第一節 銥金屬磷光材料及其衍生物的合成--------------------65
第二節 元件製作與性質探討--------------------------------------72
結論----------------------------------------------------------------------90
實驗部分--------------------------------------------------------------------------91
參考文獻--------------------------------------------------------------------------98
光譜資料------------------------------------------------------------------------103

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