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研究生:葉綮翊
論文名稱:聚乙烯/改質聚醯胺及聚乙烯/改質聚醯胺奈米尼龍容器油漆混合劑阻隔性能研究
論文名稱(外文):Paint mixed solvent permeation resistance of polyethylene/modififed polyamide, and polyethylene/blends of modified polyamide and nylon clay bottles
指導教授:葉正濤
學位類別:碩士
校院名稱:國立臺灣科技大學
系所名稱:高分子工程系
學門:工程學門
學類:化學工程學類
論文種類:學術論文
論文出版年:2003
畢業學年度:92
語文別:中文
論文頁數:85
中文關鍵詞:ClayNylon6PEPermeation
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論文摘要
本研究主要係探討聚乙烯(polyethylene, PE)、聚乙烯/改質聚醯胺(polyethylene/modified polyamide, PE/MPA)、聚乙烯/改質聚醯胺/奈米尼龍(polyethylene/modified polyamide/nylon clay, PE/MPA/NYC)吹瓶樣品之油漆混合溶劑滲透阻隔性質。為了瞭解這些油漆混合溶劑之滲透機理,除了油漆混合溶劑外,存在於這些混合溶劑內之純溶劑亦分別被盛裝於這些容器內,並探討其滲透性質。添加NYC阻隔塑膠改質MPA製備不同配方之MPANYC(blends of modified polyamide and nylon clay),再將所製備各種MPANYC樣品與PE吹瓶製備成PE/MPANYC 樣品並探討其油漆混合溶劑滲透阻隔性質。 結果發現經適當配方製備之PE/MPA及PE/MPANYC吹瓶樣品,其在40℃下之松香水滲透阻隔改善倍率分別較PE吹瓶樣品改善46.8及63.6倍。 相較於松香水,PE吹瓶樣品極性溶劑的滲透速率明顯大幅減小;但與PE/MPA及PE/MPANYC系列吹瓶樣品相比較仍然快的多。 另一方面,PE吹瓶樣品之油漆混合溶劑滲漏速率大約與經簡易混合定律(simple mixing rule)所估算之滲透速率相似。 相較於PE吹瓶樣品,當混合溶劑內極性溶劑含量達到某特殊範圍時,PE/MPA吹瓶樣品之油漆混合溶劑滲漏速率卻遠較經簡易混合定律所估算之滲透速率高出許多。 而經添加NYC配方與含量之PE/MPANYC吹瓶樣品, 即使當混合溶劑內極性溶劑含量達到此特殊範圍時,其混合溶劑滲透速率境明顯下降至與經簡易混合定律所估算之滲透速率差不多。為瞭解上述這些有趣之油漆混合溶劑阻隔滲透性質,這些吹瓶樣品內高分子的基礎流變、寬角X光繞射、熱學性質及吹瓶樣品內阻隔塑膠斷面型態亦在本文中被進一步探討。
目 錄
論文摘要 I
ABSTRACT III
誌謝 ………….. ... V
目錄 ……….. VI
圖表索引 VIII
一、前言 1
二、文獻回顧 4
2.1 高分子聚摻合物 4
2.2 氣體或溶劑蒸氣對高分子材料的滲透…………………………...7
2.2.1 氣體或溶劑蒸氣滲透分子特性對滲透性之影響……………………………………………………….……..8
2.2.2 高分子材料特性對滲透性的影響 11
2.2.3 添加劑對滲透性的影響 23
2.3 聚乙烯阻隔性容器之製備 26
2.4 聚摻合物中的相容劑先質 31
2.5 聚烯烴/聚醯胺摻合物之研究 34
2.6 乙烯乙烯醇共聚物阻隔性材料之研究 36
2.7改質聚醯胺/奈米尼龍共聚物摻合物(Modified blend of polyamide and nylon clay copolymer,MPANYC)之製備原理 40
2.8 噴漆塗料…………………………………………………………43
2.8.1 塗料溶劑……………………………………………………45
三、實 驗…………………………………………………………………….49
3.1 原料 49
3.2 樣品製備 50
3.2.1 製備改質聚醯胺奈米尼龍共聚物摻合物( MPANYC ) 50
3.2.2 PE、PE/MPA及PE/ MPANYC 吹瓶樣品製備 52
3.3 流變性測試 53
3.4 PE、MPA及 MPANYC 之熱學性質分析及廣角X光繞射分析(WAXD)…………. 54
3.5 形態分析………………………………………………………….55
3.6 混合溶劑滲透速率測試 56
四、結果與討論 58
4.1 Clay形態分析 58
4.2 流變性質分析 60
4.3 熱學與寬角X光繞射性質分析 62
4.4 斷面形態分析…………….………………………………………67
4.5 滲透性質測試………………………………………….…………69
五、結 論 .79
參考文獻 .81
作者簡介……………………………………………………….………….....85
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