本文分析大屯火山群溪水中溶解性與顆粒性重金屬元素(Al、Co、Cu 、Fe、Mn、Pb、V、Zn、)的分佈特性，再藉由分佈係數的對數（log Kd）與pH值、電導度、離子強度、D.O.的比較，來探討重金屬元素的交互作用與移動性。在大屯火山群溪水採樣站中，只有南磺溪與北磺溪位於後火山作用區，化學成分供應源主要由火山硫磺氣體及溫泉水輸入，導致pH偏低、電導度與離子強度增加、D.O.降低，而懸浮顆粒的吸附作用減少重金屬元素釋放至水中，所以濃度範圍比沒有溫泉水輸入的採樣站對較高，也影響水中重金屬元素在溶解性與顆粒性的移動性。

In this study,we analyze the mobility of dissolved and particulate trace metals (Al,Co,Cu,Fe,Pb,V,Zn) in the stream water of Tatun Volcano group.Then we compare the logarithm partition coefficient(log Kd) with pH、conductivity、ionic strength、D.O. to discuss the interaction and mobility between trace metals.All of the stream water station,only The Nanhuang-Hsi stream and The Beihuang-Hsi stream are located in the volcano function area,the chemistry composition supple source mainly by the volcano sulphur gas and the hot spring water importation,case pH low,conductivity degree and the ionic strength increment, D.O.reduce,and suspend the adsorption of the gain to reduce , therefore the trace metals to release to the stream water and the concentration range is higher than that have no hot spring water''s importation，also influence the mobility of dissolved and particulate trace metals.

誌謝 ……………………………………………………………………1
摘要 ……………………………………………………………………2
Abstract ……………………………………………………………………3
目錄 ……………………………………………………………………4
圖目錄 ……………………………………………………………………5
表目錄 ……………………………………………………………………6
第一章 序論 ………………………………………………………………7
1.1 前言 …………………………………………………………7
1.2 重金屬元素在水中的移動方式 ……………………………8
1.3 控制大屯火山群溪水重金屬含量之主要因素……………11
1.4 前人研究……………………………………………………12
1.5 研究目的……………………………………………………13
第二章 研究區域…………………………………………………………14
2.1 大屯火山群河流水文特徵…………………………………14
2.2 大屯火山群的溫泉…………………………………………14
第三章 採樣與樣品分析…………………………………………………22
3.1 採樣地點……………………………………………………22
3.2 採樣方法與前處理…………………………………………25
3.3 實驗儀器與藥品……………………………………………26
第四章 結果………………………………………………………………36
4.1 大屯火山群溪水水文資料…………………………………36
4.2 溶解態重金屬含量…………………………………………45
4.3 懸浮態重金屬含量…………………………………………50
第五章 討論………………………………………………………………70
5.1 大屯火山群自然作用對溶解態及顆粒態重金屬的影響…70
5.2 影響大屯火山群溪水重金屬移動性的因素………………70
5.3 吸附作用對重金屬移動性的探討…………………………71
5.4 以分佈係數探討重金屬元素的移動性……………………72
第六章 結論………………………………………………………………91
參考文獻 ……………………………………………………………………92

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