摘要
中文
1.甲苯二異氰酸酯與矽氧化合物S510或是氟化合物(2,2,3,3- tetrafluoro-1-propanol)及其他添加劑經反應所合成水性PU樹脂分子的結構已由FT-IR光譜證實。實驗結果顯示，水性PU樹脂薄膜的拉應力會分別隨矽氧化合物和氟化合物濃度增高而變小，卻會隨環氧化合物和Bisphenol A濃度增加而變大，前者是是因為水性PU樹脂分子本身作用力增強之故而後者是因為PU分子與分子間的作用力增大。實驗結果顯示，水性PU樹脂薄膜的伸長率會分別隨矽氧化合物、氟化合物、環氧化合物和Bisphenol A濃度增高而變小，因為水性PU樹脂分子本身作用力增強之故。實驗數據亦指出水性PU樹脂薄膜的光澤度會隨矽氧化合物、環氧化合物和Bisphenol A濃度增高而變大，卻會隨氟化合物濃度增高而變小，前者是因為水性PU樹脂薄膜的分子排列較整齊之故而後者是因為薄膜的分子排列較不整齊之故，實驗結果顯示，水性PU樹脂溶液的表面張力會隨矽氧化合物和環氧化合物濃度之增高而變大，卻會隨氟化合物和Bisphenol A濃度之增高而變小；前者是因為吸附在水溶液表面上的非極性排列較整齊之故而後者是因為水溶液表面吸附較多非極性基之故。水性PU溶液的粒徑均會隨矽氧化合物、環氧化合物、氟化合物或是Bisphenol A濃度之增高而變大，原因是因為水性PU樹脂分子上的極性基間的相互作用，使得水性PU樹脂分子的自由體積變大，結果導致水性PU樹脂溶液的黏度和平均粒徑變大。實驗數據顯示，水性PU樹脂溶液的吸水率會隨矽氧化合物、環氧化合物、氟化合物或是Bisphenol A濃度之增高而變大，原因是因為水性PU樹脂主鏈上的極性基增多之故。

英文
Toluene diisocyanate reacted with siloxane compound or fluoro compound and other additives to form the polyurethane ionomers was successfully synthesized and their structures have been demonstrated by FT-IR spectra. In aqueous solution, Ｔhe average particle sizes appear to increase with increasing concentration of the siloxane compound or fluoro compound. This is because the intermolecular interaction between polyurethane ionomer molecules themselves becomes strong. Furthermore, this interaction increasing the free volume of the ionomer molecule makes both the viscosities and the average particle sizes of the polyurethane ionomer molecules become large. Experimental results show that both the tensile strength and the elongation of self-cured film made by the polyurethane ionomer are seen to decrease with increasing concentration of the siloxane compound and fluoro compound, respectively, as a result of strong intramolecular interaction.

目錄
中文摘要……………………………………………………………….1
英文摘要……………………………………………………………….2
1.前言…………………………………………………………………3
2.理論部分…………………………… ……………………………..5
2-1 PU離子體…………………………………………………………..6
2-1-1 PU離子體的合成反應……………………………………………8
2-2 合成水性PU樹脂原料 ………………………………………………11
2-2-1 異氰酸酯（Isocyanate）……………………………………..11
2-2-2 多元醇（Polyol）……………………………………………..16
2-2-3 離子基單體…………………………………………………….17
2-2-4 鏈延長劑(linkage extender) ……………………………….18
2-2-5 催化劑(catalyst)…………………………………………….20
2-2-6 內部乳化劑(Internal emulsifiers)……………………….21
2-2-7 架 橋 劑（Cross-linking Agent）………………………..22
2-2-8 溶劑的選擇…………………………………………………….23
2-2-9 離子基含量對水性PU樹脂之影響……………………………24
2-3 PU離子體的製造………………………………………………..25
2-3-1丙酮製程…………………..………………………………….26
2-3-2 預聚物混合法(prepolymer mixing process)………………27
3實驗部份……………………………………………………………..28
3-1實驗之分析儀器設備……………………………………………. 28
3-1-1 實驗裝置……………………………………………………...28
3-2-1 分析儀器……………………………………………………….29
3-2-2 實驗藥品……………………………………………………… 30
3-2-3 實驗步驟……………………………………………………… 32
3-3-1 實 驗 合 成 步 驟…………………………………………..32
3-3-2 水性PU樹脂之皮膜的製備…………………………………….33
3-4 物性之測試……………………………………………………… 33
3-4-1 紅外光譜儀之測試…………………………………………… 33
3-4-2 表面張力之測試（Wilhelmy法）…………………………….34
3-4-3 黏度之測試 ……………………………………………………35
4 結果與討論……………………………………………………… ..37
4-1 IR光譜的探討…………………………………………………….37
4-2表面張力的探討…………………………………………………..40
4-3 拉應力（Tensile strength）之探討………………………….41
4-4 伸長率（ Elongation）之探討…………………………………42
4-5 光澤度之探討…………………………………………………….43
4-6平均粒徑大小(Average partical size)之探討………………..44
4-7 吸水率(Water-uptake)之探討…………………………………46
5 結論…………………………………………………………………47
6 參考文獻……………………………………………………………86

六.參考文獻
1*. A study of Fluorescence from Fluorescent Dye-based Polyurethane Ionomer, Journal of Applied Polymer Science, 89, 2723-2737 (2003).
2*. Fluorescence for Fluorescent Dye-BSED Polyurethane Ionomer(II), Polymers for Advanced Technologies, 15,93-99 (2004).
3*. Synthesis and Characterization of high Dielectric Constant Polyamine/ Polyurethane Blends, Symthetic Metals, 2004, in press.
4*. Photosensitive Fluorescein Polyurethane Ionomer, Journal of Applied Polymer Science, 2003, in press.
5*. A Study of Water Vapor-Permeable Polyurethane Resin, Journal of Applied Polymer Science, Vol. 86, 2002-2010 (2002).
6*. On the Study of Polyurethane Ionomer Part (I), Polymers for Advanced Technologies, 13, 285-292 (2002).
7*. On the Study of Polyurethane Ionomer Part (II), Polymers for Advanced Technologies, 13, 293-300 (2002).
8*. Flame Retardant and Dielectric Properties Glass Fibre Reinforced Nylon-66 Filled with Red Phosphorous, Polymer Degradation and Stability. 74, 239-245 (2002).
9. Mannich 胺類新型解乳化劑應用性之探討. 全球華人石油與石化科技研討會論文集2001中華民國。
10*. Study of Oxygen-permeable Polyurenthane Ionomer (II), Journal o Applied Polymer Science, Vol. 78, 1932-1938 (2000).