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研究生:吳佩智
研究生(外文):Pei-Chi Wu
論文名稱:利用共融混合物與離子液體合成配位高分子
論文名稱(外文):Eutectic Mixtures of Choline Chloride/urea, R,R’-Imidazolium Bromide (R: ethyl, butyl; R’: methyl) Ionic Liquids as Reaction Media for The Syntheses of Coordination Polymers
指導教授:廖儒修
指導教授(外文):Liao, Ju-Hsiou
學位類別:碩士
校院名稱:國立中正大學
系所名稱:化學所
學門:自然科學學門
學類:化學學類
論文種類:學術論文
畢業學年度:93
語文別:中文
論文頁數:157
中文關鍵詞:配位高分子離子液體
外文關鍵詞:coordination polymersionic liquids
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本論文研究重點在於以綠色溶劑: (Choline Cloride / Urea, CU)共融混合物、1-ethyl-3-methylimidazolium bromide (EMIMBr)和1-butyl-3- methylimidazolium bromide (BMIMBr)離子液體作為溶劑,同時也作為模板合成新的有機(Organic) / 無機(Inorganic)配位高分子化合物。
利用Phosphoacetic acid和過渡金屬陽離子(Zn2+)在共融混合物(CU)中自我組裝形成固態結晶(NH4)[Zn(O3PCH2CO2)] (1)。1,4-Benzenedicarboxylic acid (H2BDC)、1,3,5-Benzenedicarboxylic
acid (H3BTC)有機配位基和過渡金屬陽離子(Zn2+,Cd2+,Co2+)在EMIMBr和BMIMBr離子液體自我組裝形成固態結晶: (EMI) [Cd(3,5-PDC)Br] (2)、(EMI)2[Zn3(BDC)3Br2] (3A)、(BMI)2[Zn3(BDC)3Br2] (3B)、(EMI)[Cd(BTC)] (4A) 、(BMI)[Cd(BTC)] (4B)、(EMI)[Zn(BTC)] (4C)、(BMI)[Zn(BTC)] (4D) (EMI)2[Zn4(BTC)3(H2O)3(OH)].3H2O (5) 、 (EMI)2[Co3(BTC)2(Br) (OH)].H2O (6)。在這些化合物中包含二維(2、3(A)、3(B))和三維(1、4A、4B、4C、4D、5、6)的結構,我們將探討其合成條件、構造解析、熱穩定性和離子交換的性質。其中化合物(3A),(5)結構中陽離子可與銅離子進行離子交換,在本論文中將對其性質做進一步討論。
My research focusing on synthesizing new organic/inorganic coordination polymers by using green solvents: eutetic-mixtures of choline chloride and urea, 1-ethyl-3-methylimidazolium bromide (EMIMBr), and 1-butyl-3-methylimidazolium bromide (BMIMBr) as both solvents and templates.
The self-assembly of phosphoacetic acid and transition metal cation Zn2+ in eutetic-mixtures of choline chloride and urea, led to the formation of (NH4)[Zn(O3PCH2CO2)] (1). In addition, we used organic ligands, 1,4-benzendicarboxyloc acid (H2BDC) and 1,3,5-Benzenedicarboxylic acid (H3BTC), as bridging linkers to connect transition metal cations, including Zn2+, Cd2+, Co2+, in ionic liquids, such as EMIMBr and BMIMBr. In this work, we have successfully synthesized a serious of coordination polymers, such as (EMI)[Cd(3,5-PDC)Br] (2), (EMI)2[Zn3(BDC)3Br2] (3A), (BMI)2[Zn3(BDC)3Br2] (3B) (EMI)[Cd(BTC)] (4A), (BMI)[Cd(BTC)] (4B), (EMI)[Zn(BTC) (4C), (BMI)[Zn(BTC)] (4D), (EMI)2[Zn4(BTC)3(H2O)3(OH)].3H2O (5), and (EMI)2[Co(BTC)2(Br)(OH)].H2O (6).
Compounds (2), (3A), and (3B) adopt two-dimensional frameworks, which compounds (1), (4A), (4B), (4C), (4D), (5) and (6) adopt three-dimensional frameworks. We further discuss the synthetic parameters, structural characterization, thermal stability, and the property of ionic exchange.
圖目錄-----------------------------------------------------------------------------Ⅱ
表目錄-----------------------------------------------------------------------------Ⅵ
附表目錄--------------------------------------------------------------------------Ⅶ
英文縮寫表-----------------------------------------------------------------------Ⅸ
中文摘要---------------------------------------------------------------------------1
英文摘要---------------------------------------------------------------------------2
第一章 序論-----------------------------------------------------------------------3
第二張 有機無基配位高分子之開發
2.1實驗儀器---------------------------------------------------------------------22
2.2藥品出處---------------------------------------------------------------------23
2.3合成步驟---------------------------------------------------------------------24
2.4 X光單晶繞射實驗及構造解析------------------------------------------37
第三章 結果與討論------------------------------------------------------------57
第四章 結論--------------------------------------------------------------------110
參考文獻------------------------------------------------------------------------111
附表------------------------------------------------------------------------------116
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