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研究生:洪佳博
研究生(外文):Chia-Po Hung
論文名稱:AISI403不�袗�之抗氫脆性研究
論文名稱(外文):Hydrogen Embrittlement of AISI 403 Stainless Steel
指導教授:吳建國吳建國引用關係
指導教授(外文):J. K. Wu
學位類別:碩士
校院名稱:國立臺灣海洋大學
系所名稱:材料工程研究所
學門:工程學門
學類:材料工程學類
論文種類:學術論文
論文出版年:2005
畢業學年度:93
語文別:中文
論文頁數:75
中文關鍵詞:冷加工氫脆403不�袗�氫滲透
外文關鍵詞:cold workhydrogen embrittlement403 stainless steelhydrogen permeation
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本研究主要在探討冷加工處理後對AISI 403不�袗�氫脆及機械性質的影響。而實驗主要是利用電化學氫滲透實驗來量測氫在材料中的行為,並配合使用慢速率拉伸試驗,討論氫對不同加工量的AISI 403不�袗�機械性質影響。
電化學氫滲透實驗發現,AISI 403不�袗�在冷加工過後,會增加氫在材料中的有效擴散係數、氫滲透速率和視固溶量均會隨加工量的增加而增加。
在慢速率拉伸試驗中,最大抗拉強度隨著加工量而增加;相對地,伸長量隨著加工量增加而減少。加工量越大的AISI 403不�袗�,在充氫後其延性減少的越明顯。由延性破壞轉變成脆性破壞。
對於AISI 403不�袗�而言,冷加工會使氫在材料中擴散加快,並增加材料中氫的濃度,使材料變脆,延性下降,產生氫脆。所以冷加工對材料抗氫脆的性能有是有害的。
The aim of this work is to study the effect of cold work on hydrogen embrittlement and mechanical in AISI 403 stainless steel. Hydrogen embrittlement of as received, 10% and 20% cold worked AISI 403 stainless steel has been evaluated by using electrochemical permeation measurement and tensile test in this study.
For electrochemical permeation measurement, it is known that hydrogen effective diffusivity and permeation rate increase with increase cold work. Cold may cause some micro-crack in microstructure, thus resulting in the high rate of hydrogen permeation.
For slow train rate tests, the ultimate tensile strength increase with the amount of cold work, while elongation decrease with cold work. After hydrogen charging, hydrogen diffused into the the microstructure, resulting the elongation decayed significantly. The fractography of precharged specimens shows that the ductile fracture has changed to the brittle fracture, and some hydrogen-assisted secondary cracks were also observed in the specimens.
目錄

頁次
目錄 ……………………………………………………………… Ⅰ
圖目錄 …………………………………………………………… Ⅱ
表目錄 …………………………………………………………… Ⅲ
中文摘要 ………………………………………………………… Ⅳ
英文摘要 ………………………………………………………… Ⅴ

第一章 前言 ……………………………………………………… 1

第二章 文獻回顧 ………………………………………………… 3
2.1 不�袗�及麻田散鐵不�袗� ………………………………… 3
2.2 AISI 403不�袗� …………………………………………… 3
2.3 氫脆 ………………………………………………………… 5
2.4 冷加工對氫脆及機械性質影響 …………………………… 6

第三章 理論背景 ……………………………………………… 10
3.1 氫脆理論 ………………………………………………… 10
3.2 氫脆機構 ………………………………………………… 11
3.4 氫對材料機械性質影響 ………………………………… 15
3.5 氫破壞種類及原因 ……………………………………… 18
3.6 氫破壞之防治方法 ……………………………………… 21
3.7 電化學氫滲透理論 ……………………………………… 23

第四章 實驗步驟 ……………………………………………… 37
4-1 材料試片準備 …………………………………………… 37
4-2 金相組織觀察及微硬度試驗 …………………………… 37
4.3 電化學氫滲透實驗 ……………………………………… 38
4.4 慢速率拉伸試驗 ………………………………………… 39

第五章 結果與討論 …………………………………………… 45
5.1 金相組織及微硬度測試 ………………………………… 45
5.2 電化學氫滲透實驗 ……………………………………… 45
5.3 慢速率拉伸試驗 ………………………………………… 47
5.3.1 慢速率拉伸試驗結果 ………………………………… 47
5.3.2 慢速率拉伸試驗破斷面觀察 ………………………… 48

第六章 結論 …………………………………………………… 61

參考文獻 ……………………………………………………… 62
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