本論文的研究目的是合成PBI與PBI-BS，並且將PBI加以製成薄膜應用於燃料電池上。我們利用元素分析、1H-NMR、13C-NMR及FTIR來鑑定PBI與PBI-BS。我們將不同LiCl/PBI比例的溶液注型成膜：將2 wt％的PBI溶液裝在不鏽鋼容器中成膜（方法I）或是使用刮刀將8 wt％的PBI溶液塗佈到玻璃板上成膜（方法II）並且控制膜厚。
從SEM的觀察發現，方法II製備之薄膜的表面會比方法I製備的薄膜平整。在含酸率與導電度的測量方面，方法II製備之薄膜都會比方法I製備之薄膜高。而且PPII-7.2及 PPII-10.8的導電度可以比Nafion 117還高。將PPII-7.2膜製作成MEA於質子交換膜燃料電池測試，陽極及陰極的Pt loading量分別為1 mg/cm2、0.5 mg/cm2，而氧氣進料為200 ml/min，氫氣進料為200 ml/min，在70℃下得到電池的最大功率為100 mW/cm2，開路電位（OCV）為0.83 V。
我們總結出製備PBI膜的適合條件：
（1）LiCl/PBI的莫爾比須小於10.8。
（2）方法II為較佳的製膜方法。

In this study, polybenzimidazole (PBI) and polybenzimidazole sulfonic acid (PBI-BS) were synthesized. The PBI membranes prepared for evaluation. PBI and PBI-BS were identified by element analysis, 1H-NMR, 13C-NMR, and FTIR spectroscopy. The membranes were prepared by casting the varied LiCl/PBI solution on a stainless steel cell in 2 wt% (Method I) or on a glass plate in 8 wt% (Method II) using spacer to control the thickness.
From the observation of SEM, the surfaces of the membranes prepared by Method II are smoother than those prepared by Method I. Results show acid doping level and proton conductivities of acid doped PBI membranes prepared by Method II are higher than those prepared by Method I. Proton conductivities of PPII-7.2 and PPII-10.8 are even higher than those of Nafion 117. MEA was prepared by membrane of PPII-7.2 for PEMFC test. The Pt loading were 1 mg/cm2 and 0.5 mg/cm2 at cathode, anode, respectively. At 200 ml/min of oxygen, 200 ml/min of hydrogen, and 70℃, the maximum power density of 100 mW/cm2 and the open circuit potential（OCV）of 0.83 V were obtained.
In conclusion, the conditions which are suitable for the preparation of PBI membranes are：
（1）The molar ratios of LiCl and PBI should be less than 10.8,
（2）The Method II is better for the membranes preparation.

中文摘要……………………………………………………………………..I
英文摘要……………………………………………………………………..II
目錄...................................................IV
圖目錄.................................................VII
表目錄..................................................IX

第一章 序論.............................................1
1.1 前言……………....................................1
1.2 燃料電池簡介…....................................2
1.2.1 發電原理及構造.....................................2
1.2.2 燃料電池的分類與優缺點…………………………………………...4
1.3 質子交換膜簡介………………………………................6
1.4 聚苯咪唑(Polybenzimidazole，PBI)簡介...............8
1.4.1 PBI的合成……………………………………………………………9
1.4.2 PBI在燃料電池上的應用…………………………………………..10
1.5 PBI的磺酸化與PBI-BS的合成………………………………………11
1.6 研究目的………………………………………………………………12

第二章 實驗...........................................13
2.1 實驗架構………………………………………………………………13
2.2 藥品.............................................14
2.3 儀器設備.........................................15
2.4 實驗步驟.........................................17
2.4.1 PBI的合成及鑑定.................................17
2.4.2 PBI-BS 的合成及鑑定..............................18
2.4.3 PBI薄膜製備及性質測試…………………………………………20
2.5 交流阻抗法(AC impedance)..........................27
2.5.1 AC impedance的技術應用...........................27
2.5.2 交流阻抗操作原理..................................27
2.5.3 等效電路元件.....................................30
2.5.4 交流阻抗圖譜分析.................................33

第三章 結果與討論......................................35
3.1 PBI結構鑑定.......................................35
3.1.1 PBI的霍式紅外光譜儀（FTIR）分析...................35
3.1.2 PBI的固態核磁共振光譜儀（S-NMR）分析..............36
3.2 PBI-BS的結構鑑定...............................38
3.2.1 PBI-BS的FTIR光譜................................38
3.2.2 PBI-BS的核磁共振光譜儀（NMR）分析.................40
3.2.3 PBI-BS溶解度測試…………………………………………………43
3.2.4 PBI-BS的元素分析結果………...………………………………….43
3.2.5 示差掃描分析儀（DSC）結果……………………………………….44
3.2.6 熱重分析（TGA）…………………………………………….………46
3.3 PBI薄膜的性質測試....................................47
3.3.1 SEM 觀察膜材表面………………………………………………...47
3.3.2 氣體滲透測試……………………………...………………………..66
3.3.3 含酸率測量………………………………………………………….67
3.3.4 導電度測量………………………………………………………….68
3.3.5 單電池測試………………………………………………………….72


第四章 結論……………………………………………………………….73
4.1 PBI-BS合成…………………………………………………………...73
4.2 PBI 薄膜製備…………………………………………………………73
第五章 參考文獻………………………………………………………….76

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