臺灣博碩士論文加值系統

本研究以利用噴墨技術來噴墨列印所合成之奈米墨水，並可進一步金屬化得到所需的金屬線路，奈米墨水所需的材料為分散性佳的奈米粒子，此研究利
用磺化( Sulfonation )來改善高分子奈米貴金屬粒子間之分散問題，以達到均勻分散且穩定性高等要求。首先使用所合成的聚苯乙烯寡分子( Polystyrene Oligomer ) 與貴金屬金(Au3+)、銀(Ag+)、鈀(Pd2+) 等離子反應，並使貴金屬離子溶液在未添加還原劑的狀況下，藉由聚苯乙烯寡分子本身鏈端所含官能基(SO4-)行還原反應，進而沉析奈米貴金屬粒子在聚苯乙烯寡分子上，形成聚苯乙烯奈米貴金屬粒子複合材料，由於此複合材料屬於高疏水性，所以主要應用於有機溶劑系統中，可均勻分且散穩定性佳。為了使高分子奈米貴金屬粒子複合材料於水溶液中有較佳分散性，所以進一步利用磺化後之聚苯乙烯寡分子來與貴金屬金、銀、鈀等離子反應，並藉此改善高分子複合奈米貴金屬材料之特性。再藉由霍氏紅外線光譜儀(FT-IR)與1H-NMR分析檢定表面官能基改變的狀況，並利用穿透式電子顯微鏡(TEM)來證明磺化前後聚苯乙烯寡分子還原金屬後的分散狀況與型態。將已磺化之聚苯乙烯寡分子沉析上奈米貴金屬粒子後，可藉由磺酸根來增加聚苯乙烯奈米貴金屬粒子於水溶液中的分散性，加上高分子還原上奈米貴金屬粒子後具備特殊的催化活性，可做為金屬化奈米墨水使用，藉由電腦與繪圖軟體的控制，可設計出不同的線路，並利用噴墨列印的方式將奈米墨水噴印在非導體基材上，可將非導體基材進一步金屬化，即可快速，方便且低成本的條件下得到所需的金屬線路。

A novel method for the preparation of selfassembly polymer-metal nanocomposites has been developed where by the selfassembly polymers, snlfonated polystyrene oligomer, be used as the reductant, and their no used for external reducing agent. By the chemical reduction method, noble metal (Au﹐Ag, Pd ) particles were formed and deposited on the surface of microspheres to form polymer/metal nanocomposite. These sulfonated polystyrene was characterized with H-NMR, FTIR to confirm polymer composition and quantity sulfonation, and those selfassembly polymer-metal nanocomposites were characterized by electron microscopy ( TEM and SEM ), FTIR, ESCA and TGA as well. However﹐ ink-jet printing by water-based inks requires significant development efforts aimed at achieving well-dispersion of polymer-metal nanocomposites in water. In order to carry out well-dispersion and good adhesion on the substrates requirement, we prepare the sulfonated polymers containing hydrophilic groups to stabilize clusters of polymer-metal nanocomposte in an aqueous environment and adhere on different flexible substrates. In addition, a commercially available ink-jet printer was used in this work. In this study, the water-based nanocomposite used as ink was directly printed onto various flexible substrate surfaces with self-assembled structure, followed by a typical electroless plating technique to form metallic wire.

誌 謝 ii
摘要 iii
ABSTRACT iv
目錄 v
圖目錄 vii
表目錄 x
1. 前言 1
2.文獻回顧 3
2.1聚苯乙烯磺化反應 3
2.2噴墨印刷技術回顧與應用 5
2.3研究動機 16
3.實驗 18
3.1實驗藥品與設備 18
3.1.1實驗藥品 18
3.1.2實驗設備 19
3.1.3檢測方式 20
3.2實驗流程 22
3.2.1聚苯乙烯寡分子之合成 22
3.2.2磺化苯乙烯寡分子之合成 23
3.2.3磺化後聚苯乙烯寡分子還原奈米貴金屬粒子之製備 24
3.2.4奈米墨水之噴墨列印與金屬化程序 26
3.2.5噴墨列印導線之表面型態與電性量測 28
4.結果與討論 29
4.1 聚苯乙烯寡分子之磺化與鑑定 29
4.2 磺化後之聚苯乙烯寡分子還原奈米貴金屬粒子 35
4.3奈米墨水製作與特性分析 46
4.4噴墨列印導線的表面型態觀察 58
5.結論 69
參考文獻 70
自傳 77

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