臺灣博碩士論文加值系統

本研究提出以外加輔助電場的方式製作微米錫球與奈米金屬導線，在微米錫球方面，經由外加的電場可將熔融的不規則錫液迅速地變成球形；在奈米金屬導線上，由於電場之輔助可在模板內快速形成高深寬比之奈米金屬導線。由於文獻上未發現相同的製程應用，為了瞭解可能的成型機制，本研究也設計其他輔助實驗藉以釐清可能的成型原因。本法由於製程簡單、操作容易，未來在微米錫球成型與奈米金屬導線的製作上相當有應用的潛力。

We report on a simple method for forming Bi/In alloy micro-solder balls and metal nanowires. The alloy nanowires are prepared by electro filed assist process into nanopores of anodized aluminum oxide (AAO) template on a silicon substrate. The templates have a narrow distribution of pore sizes from 20 nm to 200nm. Here we have produced high-aspect-ratio alloy nanowire arrays. The nanostructures can be fabricated rapid less than few seconds. Besides, the diameter and height of the nanowires can be controlled using the confining dimensions of the template. The nanowires are characterized using scanning electron microscopy (SEM), atomic force microscopy (AFM), CCD, X-ray diffraction (XRD), and transmission electron microscopy (TEM).

目錄
中文摘要 I
英文摘要 II
謝誌 III
目錄 IV
表目錄 VII
圖目錄 VIII
第一章 序論
1-1 前言
1-2 研究動機與目的
1-3 研究成果與貢獻
第二章 文獻回顧與研究重點
2-1 錫球製作法
2-1-1 錫球成型簡介
2-2 微機電系統之驅動機制
2-2-1 電毛細力
2-2-2 連續電濕潤機制
2-2-3 電濕潤機制與應用
2-3 奈米線製造
2-3-1 氣－液－固三相轉換法
2-3-2 氣－固生長法
2-3-3 電化學沉積法
2-3-4 液相化學成長法
2-4 本文之傳承與創新
第三章 實驗架構、流程及儀器介紹
3-1 實驗設計與目標
3-2 實驗架構
3-2-1 微小合金錫球製造
3-2-2 奈米合金導線製造
3-3 實驗用品
3-3-1 實驗藥品
3-3-2 實驗儀器
3-4 實驗流程
3-4-1 基板備製
3-4-2 電場輔助裝置之製備
3-4-3 微米合金錫球製造實驗
3-4-4 奈米合金導線製作
第四章 合金球體成型
4-1 電場輔助法
4-2 電場輔助結合模板法
4-3 濕性化學溶液輔助成型
第五章 奈米合金導線之製作
5-1 電場輔助結合AAO模板法成型合金奈米線
5-2 奈米線成型原因探討
5-2-1 電極穢韘鼽m對於奈米線成型之影響
5-2-2 奈米線成型可能機制
5-2-3 不同電解液對於合金奈米線成長之影響
第六章 結論與建議
6-1 結論
6-2 未來建議
參考文獻
附錄
A.專利
B.低溫合金成份
碩士論文口試之口試委員問題回覆

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