臺灣博碩士論文加值系統

本研究實驗主要可分為三部份，第一部分為分散劑(十二烷基苯磺
酸鋅鋅鹽)之製備，透過WXRD、POM、TGA 研究鋅鹽自我組裝之梳
狀結構，探討其層狀結構、結晶型態和熱性質。第二部份為由導電聚
苯胺加鋅鹽及奈米黏土製成的導電聚苯胺色母之製備方法，透過
WXRD、UV-Vis、TGA、ESCA 來分析導電聚苯胺色母，探討其奈米
黏土插層、共軛度、熱性質和束縛能變化。第三部份為將色母與一般
高分子混合而成為導電聚掺合物之製備。利用 WXRD 、 TGA 、
SEM 、微歐姆計來討論色母和一般高分子間的相容性、熱穩定性、表
面型態的變化、導電度變化。

The experiments of this study were divided into three parts : the first was
to prepare the Zinc dodecyl benzenesulfonate( Zn(DBS)2 ).This composites
prepared from Zn(DBS)2 and polyaniline will create a comb-shaped structure
and properties of the complex composite was investigated by WXRD, POM,
TGA, to analyze the layer structure, crystal structure, and thermal properties.
The second was to prepare the conducting nanocomposites of polyanilne and
clay at master batch. We analyzed the conducting master batch with WXRD,
UV-vis, TGA, ESCA, to characterize the intercalation, conjugated structure of
polyaniline , thermal properties, and the binding energy changes. Finally, it
was to prepare the conducting polyblends prepared from master batch and
regular organic polymers with WXRD, TGA, SEM, Miliohm meter were used
to analyze the compatibility, thermal properties, morphology, electrical
conductivity of the polyblends.
Keywords : Polyaniline 、 nanocomposites 、 Conducting polyblends

中文摘要------------------------------------------------------------------------- I
英文摘要------------------------------------------------------------------------- Ⅱ
致謝------------------------------------------------------------------------------- Ⅲ
目錄------------------------------------------------------------------------------- Ⅳ
表目錄---------------------------------------------------------------------------- Ⅶ
圖目錄---------------------------------------------------------------------------- Ⅷ
第一章 緒論
1-1 研究動機與背景-------------------------------------------------------- 1
1-2 研究目的----------------------------------------------------------------- 3
第二章 文獻回顧
2-1 導電高分子------------------------------------------------------------- 5
2-1-1 導電高分子的發展史----------------------------------------------- 5
2-1-2 導電原理和能帶理論----------------------------------------------- 10
2-1-3 摻雜原理及方法----------------------------------------------------- 14
2-1-4 導電高分子的種類-------------------------------------------------- 15
2-2 導電高分子聚苯胺----------------------------------------------------- 16
2-3 無機層材分散相簡介-------------------------------------------------- 20
2-4 奈米複合材料簡介----------------------------------------------------- 24
2-4-1 奈米複合材料的定義------------------------------------------------ 24
2-4-2 有機/無機混成複合材料之種類----------------------------------- 26
2-4-3 插層法( Intercalation )介紹---------------------------------------- 29
2-5 混煉機構與原理------------------------------------------------------ 31
2-5-1 分配式混煉機構---------------------------------------------------- 32
2-5-2 分散式混煉機構---------------------------------------------------- 33
2-5-3 配合(compounding)與融和(fluxing)----------------------------- 34
2-6 熱可塑性聚胺基甲酸酯（TPU）---------------------------------- 35
2-6-1 熱塑性聚胺基甲酸酯之介紹------------------------------------- 35
2-6-2 TPU 之聚合原理與製程------------------------------------------- 36
2-6-3 TPU之特性----------------------------------------------------------- 40
2-6-4 TPU之加工----------------------------------------------------------- 40
第三章 實驗------------------------------------------------------------------- 41
3-1 實驗藥品--------------------------------------------------------------- 41
3-2 儀器設備--------------------------------------------------------------- 43
3-3 分散劑鋅鹽之合成與特性鑑定實驗------------------------------ 46
3-4 聚苯胺導電色母的製備與特性鑑定實驗------------------------- 48
3-4-1 聚苯胺導電色母之方法A製備----------------------------------- 48
3-4-2 聚苯胺導電色母之方法B製備----------------------------------- 49
3-5 導電聚掺合物之製備------------------------------------------------ 51
第四章 結果與討論---------------------------------------------------------- 53
4-1 分散劑鋅鹽之最適反應重量比與特性鑑定---------------------- 53
4-2 最佳聚苯胺導電色母之物性與結構鑑定------------------------- 60
4-2-1 方法A 製備而成聚苯胺導電色母之分析--------------------- 61
4-2-2 方法B 製備而成聚苯胺導電色母之分析---------------------- 63
4-3 導電性聚掺合物之特性與結構鑑定------------------------------ 79
第五章 結論------------------------------------------------------------------101
第六章 參考文獻------------------------------------------------------------103

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