臺灣博碩士論文加值系統

合成free-base mono(4-aniline-ethynyl)biphenylporphine，
free-base bis(4-aniline-ethynyl)biphenylporphine，
free-base mono(2-aniline-ethynyl)biphenylporphine以及free-base bis(2-aniline-ethynyl)biphenylporphine，分別簡稱為H2(4-AE)BPP、H2(4-AE)2BPP、H2(2-AE)BPP以及H2(2-AE)2BPP，並探討它們的電聚合反應。電化學與紫外光可見光譜的實驗結果顯示，當雙取代的H2(4-AE)2BPP及H2(2-AE)2BPP溶在DMF中可以在Pt、GCE、Au以及ITO電極表面進行電聚合反應。這些紫質在ITO表面所形成的電聚合薄膜，其氧化還原及吸收光譜性質與原本紫質溶於溶液中的基本性質沒有大幅度的改變，這建議電聚合反應不會大幅度的影響這些紫質的π共軛系統。反觀，單取代的H2(4-AE)BPP及H2(2-AE)BPP溶在DMF中，不管是使用Pt、GCE或ITO當工作電極，都無法有效的進行電聚合反應。
另外，我們運用代號H2(4-AE)2BPP和H2(2-AE)2BPP的紫質在GCE電極上所形成的電聚合膜在水溶液中偵測汞金屬離子。兩種修飾電極浸在含有HgCl2的水溶液中，可以觀察到增強的汞氧化電流訊號。H2(4-AE)2BPP所形成的修飾電極，其偵測的效果明顯的遠優於H2(2-AE)2BPP所修飾的電極。

Free-base mono(4-aniline-ethynyl)biphenylporphine, free-base bis(4-aniline-ethynyl)biphenylporphine, free-base mono(2-aniline-ethynyl)biphenylporphine and free-base bis(2-aniline-ethynyl)biphenylporphine [abbreviated as H2(4-AE)BPP, H2(4-AE)2BPP, H2(2-AE)BPP and H2(2-AE)2BPP] are synthesized and their electro-polymerization reactions are studied. Electrochemical and UV-Visible experiments show that H2(4-AE)2BPP and H2(2-AE)2BPP can be successfully electro-polymerized onto Pt, GCE, Au and ITO electrodes in DMF solution. The electro- polymerized porphyrin films on indium tin oxide (ITO) surfaces show no significant changes of their redox and spectral properties. This suggests that the π-conjugations system of these porphyrins are not greatly affected upon electro-polymerization. On the other hand, H2(4-AE)BPP and H2(2-AE)BPP can’t be successfully electro-polymerized onto Pt, GCE and ITO electrodes in DMF solution.
In addition, H2(4-AE)2BPP- and H2(2-AE)2BPP-modified GCE electrodes are used to dectect mecury(II) ion in aqueous solution. Upon applying the modified electrodes in HgCl2 solution, intensified redox currents of Hg2+ are detected. The modified electrodes of H2(4-AE)2BPP has better current-enhancement than H2(2-AE)2BPP ones on dectecting mecury(II) ion in aqueous solution.

一、簡介
1-1 紫質簡介及其重要性
1-2 紫質電聚合化學的介紹
1-3 研究方向及偵測汞金屬離子的動機
二、實驗部分
2-1 儀器設備
2-2 藥品
2-3 合成步驟
2-3-1 合成Zn(2-AE)BPP
2-3-2 合成H2(2-AE)BPP
2-3-3 合成Zn(2-AE)2BPP
2-3-4 合成H2(2-AE)2BPP

2-4 化合物鑑定結果 (NMR、Elemental Analysis、Mass)
2-4-1 H2(2-AE)BPP鑑定結果
2-4-2 H2(2-AE)2BPP鑑定結果
三、結果與討論
第一部分 H2(4-AE) BPP、H2(4-AE) 2BPP、H2(2-AE) BPP及H2(2-AE)2BPP的電化學(Cyclic voltammetry)基本性質探討
3-1-1 電化學 (Electrochemistry)
3-1-2 活性的探討
第二部分 H2(4-AE)2BPP及H2(2-AE)2BPP對汞金屬離子的偵測

3-2-1 H2(4-AE)2BPP及H2(2-AE)2BPP 對汞金屬離子的偵測之電聚合條件選擇
3-2-2 H2(4-AE)2BPP的部分
3-2-2-1 不同pH值對偵測汞離子的影響
3-2-2-2 電聚合不等量的紫質對偵測汞離子的影響
3-2-2-3 汞離子濃度對於修飾電極電流強度的測試
3-2-3 H2(2-AE)2BPP的部分
3-2-3-1 不同pH值對偵測汞離子的影響
3-2-3-2 電聚合不等量的紫質對偵測汞離子的影響
3-2-3-3 汞離子濃度對於修飾電極電流強度的測試
3-3 干擾離子的影響
四、結論
參考文獻
附錄一
附錄二

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