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目錄
第一部分 卡唑化合物的合成與電化學研究
第一章 前言
1-1 三苯胺化合物………………………………..........……...
1-2 Carbazole化合物…………………………….…..……….
第二章 實驗
2-1 藥品………………………………………………………
2-2 Carbazole衍生物的合成製備…………………….…..…
(1) 9-phenylcarbazole, (1)………..……………………….…
(2) 3,6-dibromo-9-phenylcarbazole, (2)….…………………
(3) 3,6-di-tert-butyl-9-phenylcarbazole, (3)….………..……
(4) 3,6-dinitro-9-phenylcarbazole, (4)………………………
(5) 9-phenylcarbazole-3,6-diamine, (5)…..…………………
(6) 9-(4-methoxyphenyl)carbazole, (6)……………...………
(7) 9-(4-methoxyphenyl)-3,6-dinitrocarbazole, (7)…………
(8) 9-(4-methoxyphenyl)-carbazole-3,6-diamine, (8).………
(9) 9-p-tolylcarbazole, (9)…………………………...………
(10) 3,6-dibromo-9-p-tolylcarbazole, (10)………….…………
(11) 3,6-di-t-butyl-9-p-tolylcarbazole, (11)………………...…
(12) 9-(4-nitrophenyl)carbazole, (12)………….…………..…
(13) 4-(carbazol-9-yl)benzenamine, (13)…….……………..…
(14) 3,6-di-t-butyl-9-(4-t-butylphenyl)carbazole, (14)………..
(15) 9-(4-methoxyphenyl)-3-(9-(4-methoxyphenyl) carbazol-3-yl)carbazole, (15)……………………..…...…
(16) 9-phenyl-3-(9-phenylcarbazol-3-yl)carbazole, (16)…..…
第三章 Carbazoles的電化學及光譜電化學研究
3-1 Carbazole的衍生物……………………...………………
(1) 9-phenylcarbazole, (1)………..……………………….…
(2) 3,6-dibromo-9-phenylcarbazole, (2)….…………………
(3) 3,6-di-t-butyl-9-phenylcarbazole, (3)….…………..……
(4) 3,6-dinitro-9-phenylcarbazole, (4)………………………
(5) 9-phenylcarbazole-3,6-diamine, (5)…..…………………
(6) 9-(4-methoxyphenyl)carbazole, (6)……………...………
(7) 9-(4-methoxyphenyl)-3,6-dinitrocarbazole, (7)…………
(8) 9-(4-methoxyphenyl)-carbazole-3,6-diamine, (8).………
(9) 9-p-tolylcarbazole, (9)…………………………...………
(10) 3,6-dibromo-9-p-tolylcarbazole, (10)………….…………
(11) 3,6-di-t-butyl-9-p-tolylcarbazole, (11)…………...………
(12) 9-(4-nitrophenyl)carbazole, (12)………….…………..…
(13) 4-(carbazol-9-yl)benzenamine, (13)…….……………..…
(14) 3,6-di-tert-butyl-9-(4-tert-butylphenyl)carbazole, (14).…
(15) 9-(4-methoxyphenyl)-3-(9-(4-methoxyphenyl) carbazol-3-yl)carbazole, (15)……………………..…...…
(16) 9-phenyl-3-(9-phenylcarbazol-3-yl)carbazole, (16)…..…
第四章 結論………………………………………………..
第二部分 樹枝狀卡唑化合物的合成與電化學研究
第五章 前言
5-1 有機發光元件……………………………………………
5-2 價間電子傳導(Intervalence charge transfer, IVCT)…....
5-3 研究目的…………………………………………………
第六章 實驗
6-1 藥品………………………………………………………
6-2 Carbazole樹枝狀衍生物合成……………….………..…
(a)N3,N3,N6,N6-tetrakis(4-methoxyphenyl)-9-phenyl-9H-
carbazole-3,6-diamine……………………..………………
(b)9-phenyl-N3,N3,N6,N6-tetrap-tolyl-9H-carbazole-3,6-
diamine…………………………………………………..
(c)N3,N3,N6,N6,9-pentaphenyl-9H-carbazole-3,6-diamine….....
(d)N3,N3,N6,N6-tetrakis(4-nitrophenyl)-9-phenyl-9H-carbazole
-3,6-diamine………………………………………………..
(g)9-(4-methoxyphenyl)-N3,N3,N6,N6-tetrakis(4-nitrophenyl)
-9H-carbazole-3,6-diamine………………………………...
(e)N3,N3,N6,N6,9-pentakis(4-methoxyphenyl)-9H-carbazole-3,
6-diamine…………………………………………………..
(f)9-(4-methoxyphenyl)-N3,N3,N6,N6-tetraphenyl-9H-
carbazole-3,6-diamine……………………………………..
第七章 樹枝狀carbazoles的電化學及光譜電化學研究
7-1 Carbazole的樹枝狀衍生物…………………………..….
(a)N3,N3,N6,N6-tetrakis(4-methoxyphenyl)-9-phenyl-9H-
carbazole-3,6-diamine……………………..………………
(b)9-phenyl-N3,N3,N6,N6-tetrap-tolyl-9H-carbazole-3,6-
diamine…………………………….……………………..
(c)N3,N3,N6,N6,9-pentaphenyl-9H-carbazole-3,6-diamine….....
(d)N3,N3,N6,N6-tetrakis(4-nitrophenyl)-9-phenyl-9H-carbazole
-3,6-diamine………………………………………………..
(e)N3,N3,N6,N6,9-pentakis(4-methoxyphenyl)-9H-carbazole-3,
6-diamine…………………………………………………..
(f) 9-(4-methoxyphenyl)-N3,N3,N6,N6-tetra-p-tolyl-9H-
carbazole-3,6-diamine….………………………………….
(g)9-(4-methoxyphenyl)-N3,N3,N6,N6-tetraphenyl-9H-
carbazole-3,6-diamine……………………………………..
(h)9-(4-methoxyphenyl)-N3,N3,N6,N6-tetrakis(4-nitrophenyl)
-9H-carbazole-3,6-diamine………………………………...
第八章 結論………………………………………………..
參考文獻…………………………………………….....................
圖目錄
第一部分 卡唑化合物的合成與電化學研究
Scheme 1-1-1 The electrochemical dimerization of TPA………….
Scheme 1-1-2 The electrochemical cyclization reaction…………..
Scheme 1-2-1 The ECE mechanism of carbazole……….………...
Fig. 3-1-1 Cyclic voltammograms of 1 mM compound 1 in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE.………...………….
Scheme 3-1-1 The electrochemical oxidation of 1………………...
Fig. 3-1-2 Spectral changes of compound 1 during the first oxidation at +1.10 V in CH3CN containing 0.2 M TBAP. (a)0.00 V, 0 min﹔(b)+1.10 V, 1﹔(c)3﹔(d)5﹔(e)7﹔(f)9﹔(g)11﹔(h)13﹔(i)16 min…......
Fig. 3-1-3 Spectral changes of compound 1 during the second oxidation at +1.16V in CH3CN containing 0.2 M TBAP. (a) +1.10 V, 16 min﹔(b) +1.16V, 1﹔(c)2﹔(d)3﹔(e)4﹔(f)5﹔(g)6﹔(h)7﹔(i)12 min…
Fig. 3-1-4 Spectral changes of compound 1 during the reduction recovery procedure at applied potential back to 0.00V in CH3CN containing 0.2 M TBAP. (a)+1.61 V, 1 min﹔(b)0.00 V, 1﹔(c)2﹔(d)3﹔(e)4﹔(f)5﹔(g)6﹔(h)7 min………………………
Fig. 3-1-5 Spectral changes of compound 1 during the first oxidation at +1.24 V in CH3CN containing 0.2 M TBAP. (a)0.00 V, 0 min﹔(b)+1.24V, 3﹔(c)6﹔(d)9﹔(e)12﹔(f)15 min…………………………...
Fig. 3-1-6 Spectral changes of compound 1 during the second oxidation at +1.34 V in CH3CN containing 0.2 M TBAP. (a)1.24 V, 15 min﹔(b)+1.34 V, 3﹔(c)6 min………………………………………………...
Fig. 3-1-7 Cyclic voltammograms of 1 mM compound 2 in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 3-1-8 Spectral changes of compound 2 during the first electron oxidation at +1.30 V in CH3CN containing 0.2 M TBAP. (a) 0.00 V, 0 min﹔(b) +1.30V, 0.5﹔(c)1.5﹔(d)2﹔(e)2.5﹔(f)3 min……
Fig.3-1-9 Cyclic voltammograms of 1 mM compound 3 in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 3-1-10 Spectral changes of compound 3 during the first electron oxidation at +1.11 V in CH3CN containing 0.2 M TBAP. (a)0.00 V 0 min﹔(b) +1.11 V, 0.5﹔(c)1﹔(d)1.5﹔(e)2﹔(f)2.5﹔(g)3﹔(h)3.5﹔(i)4 min………………………….………..
Fig. 3-1-11 Cyclic voltammograms of 1 mM compound 4 in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 3-1-12 Cyclic voltammograms of 1 mM compound 5 in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 3-1-13 Cyclic voltammograms of 1 mM N-p-diaminotriphenylamine in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE……….………………………………………
Fig. 3-1-14 Cyclic voltammograms of 1 mM compound 6 in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Scheme 3-1-2 The electrochemical oxidation of 6………………...
Fig. 3-1-15 Spectral changes of compound 6 during the first oxidation at +0.80 V in CH3CN containing 0.2 M TBAP. (a)0.00 V, 0min﹔(b) +0.80 V, 0.5﹔(c)1﹔(d)1.5﹔(e)2﹔(f)2.5﹔(g)3﹔(h)3.5﹔(i)4﹔(j)4.5﹔(k)5 min…………………………………...
Fig. 3-1-16 Spectral changes of compound 6 during the reduction recovery procedure at applied potential back to 0.00 V in CH3CN containing 0.2 M TBAP. (a)0.90 V, 11 min﹔(b) 0.00 V, 1﹔(c)2﹔(d)3﹔(e)4﹔(f)5﹔(g)6﹔(h)7﹔(i)8 min…………..……
Fig. 3-1-17 Spectral changes of compound 6 during the first oxidation at +1.00 V in CH3CN containing 0.2 M TBAP. (a)0.00 V, 0min﹔(b)+1.00 V, 3﹔(c)6﹔(d)9﹔(e)12﹔(f)15﹔(g)18﹔(h)21min.……..…...
Fig. 3-1-18 Spectral changes of compound 6 during the second oxidation at +1.02 V in CH3CN containing 0.2 M TBAP. (a) +1.00 V, 21 min﹔(b) +1.02 V, 3﹔(c)6﹔(d)9﹔(e)12﹔(f)15 min…………………….
Fig. 3-1-19 Cyclic voltammograms of 1 mM compound 7 in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 3-1-20 Cyclic voltammograms of 1 mM compound 8 in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 3-1-21 Cyclic voltammograms of 1 mM compound 9 in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 3-1-22 Spectral changes of compound 9 during the first oxidation at +0.97 V in CH3CN containing 0.2 M TBAP. (a)0.00 V, 0 min﹔(b) +0.97 V, 1﹔(c) 2﹔(d)3﹔(e)4﹔(f)5 min……………………………...
Fig. 3-1-23 Spectral changes of compound 9 during the second oxidation at +0.97 V in CH3CN containing 0.2 M TBAP. (a) +0.97 V, 4﹔(b)5﹔(c)6﹔(d)7﹔(e)8﹔(f)9﹔(g)10﹔(h)11 min…………………………...
Fig. 3-1-24 Cyclic voltammograms of 1 mM compound 10 in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 3-1-25 Spectral changes of compound 10 during the first electron oxidation at +1.40V in CH3CN containing 0.2 M TBAP. (a)0.00 V, 0 min﹔(b)+1.40 V, 1﹔(c)1.5﹔(d)2﹔(e)2.5﹔(f)3﹔(g)3.5﹔(h)4 min…..
Fig. 3-1-26 Cyclic voltammograms of 1 mM compound 11 in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 3-1-27 Spectral changes of compound 11 during the first electron oxidation at +1.21V in CH3CN containing 0.2 M TBAP. (a)0.00 V, 0 min﹔(b) +1.21 V, 0.5﹔(c)1﹔(d)1.5﹔(e)2﹔(f)2.5﹔(g)3 min……………
Fig. 3-1-28 Cyclic voltammograms of 1 mM compound 12 in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 3-1-29 Cyclic voltammograms of 1 mM compound 13 in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 3-1-30 Cyclic voltammograms of 1 mM diphenyl-p-phenylenediamine in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE………………………….
Fig. 3-1-31 Cyclic voltammograms of 1 mM compound 14 in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE……….……………
Fig. 3-1-32 Spectral changes of compound 14 during the first electron oxidation at +1.16 V in CH3CN containing 0.2 M TBAP. (a) +0.00 V, 0 min﹔(b) +1.16 V, 0.5﹔(c)1﹔(d)1.5﹔(e)2﹔(f)2.5﹔(g)3﹔(h)3.5﹔(i)4﹔(j)4.5﹔(k)5﹔(l)5.5 min…………..
Fig. 3-1-33 Cyclic voltammograms of 1 mM compound 15 in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 3-1-34 Spectral changes of compound 15 during the first oxidation at +0.91 V in CH3CN containing 0.2 M TBAP. (a)0.00 V, 0 min﹔(b) +0.91 V, 1﹔(c)2﹔(d)3﹔(e)4﹔(f)5﹔(g)6﹔(h)7﹔(i)8﹔(j)9﹔(k)10 min………………………………………………...
Fig. 3-1-35 Spectral changes of compound 15 during the second oxidation at +1.11 V in CH3CN containing 0.2 M TBAP. (a)0.91 V, 10 min﹔(b) +1.11 V, 1﹔(c)2﹔(d)3﹔(e)4﹔(f)5﹔(g)6 min…................................
Fig. 3-1-36 Spectral changes of compound 15 during the first oxidation at +1.00 V in CH3CN containing 0.2 M TBAP. (a)0.00 V, 0 min﹔(b) +0.90V, 3 min﹔(c) +1.00 V, 3﹔(d)6﹔(e)9﹔(f)12﹔(g)15 min………
Fig. 3-1-37 Spectral changes of compound 15 during the second oxidation at +1.21V in CH3CN containing 0.2 M TBAP. (a)+1.00V, 15 min﹔(b) +1.21 V 3﹔(c)6 min﹔(d) +1.26 V, 3 min………………………….
Fig. 3-1-38 Cyclic voltammograms of 1 mM compound 16 in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 3-1-39 Spectral changes of compound 16 during the first electron oxidation at +1.01 V in CH3CN containing 0.2 M TBAP. (a)0.00 V, 0 min﹔(b) +1.01 V, 0.5﹔(c)1﹔(d)1.5﹔(e)2﹔(f)2.5﹔(g)3﹔(h)3.5﹔(i)4﹔(j)4.5﹔(k)5﹔(l)5.5﹔(m)6﹔(n)6.5 min………………………………………………...
Fig. 3-1-40 Spectral changes of compound 16 during the second electron oxidation at +1.11 V in CH3CN containing 0.2 M TBAP. (a)+1.01 V, 6.5 min﹔(b)+1.11 V 0.5﹔(c)1﹔(d)1.5﹔(e)2﹔(f)2.5﹔(g)3 min………………………………………………...
第二部分 樹枝狀卡唑化合物的合成與電化學研究
Fig. 5-1-1 一般常見的電洞傳輸層………………………..….
Fig. 5-1-2 一般常見的電子傳輸層………………………..….
Fig. 5-2-1 Potential energy versus nuclear configuration as a function of λ and HAB ……………………………..
Fig. 7-1-1 Cyclic voltammograms of 1 mM compound a in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 7-1-2 Spectral changes of compound a at various applied potentials in CH3CN containing 0.1 M TBAP. (a) +0.00﹔(b) +0.10﹔(c) +0.18﹔(d) +0.23﹔(e) +0.30﹔(f) +0.36﹔(g) +0.40﹔(h) +0.46﹔(i) +0.50 V……………………………………………
Fig. 7-1-3 Spectral changes of compound a at various applied potentials in CH3CN containing 0.1 M TBAP. (a)+0.55﹔(b)+0.56﹔(c)+0.57﹔(d)+0.58﹔(e)+0.59 V…………………………………………
Fig. 7-1-4 Spectral changes of compound a at various applied potentials in CH3CN containing 0.1 M TBAP. (a) +0.70﹔(b) +0.72﹔(c) +0.74﹔(d) +0.78﹔(e) +0.79﹔(f) +0.80﹔(g) +0.82﹔(h) +0.87 V………
Fig. 7-1-5 Cyclic voltammograms of 1 mM compound b in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 7-1-6 Spectral changes of compound b at various applied potentials in CH3CN containing 0.1 M TBAP. (a) +0.4﹔(b) +0.51﹔(c) +0.54﹔(d) +0.57﹔(e) +0.59﹔(f) +0.61﹔(g) +0.63﹔(h) +0.65﹔(i) +0.67﹔(j) +0.71﹔(k) +0.76 V…………………...
Fig. 7-1-7 Spectral changes of compound b at various applied potentials in CH3CN containing 0.1 M TBAP. (a) +0.71﹔(b) +0.76﹔(c) +0.81﹔(d) +0.83﹔(e) +0.85﹔(f) +0.91﹔(g) +0.93 V…………………...
Fig. 7-1-8 Cyclic voltammograms of 1 mM compound c in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE……………….........
Fig. 7-1-9 Spectral changes of compound c at various applied potentials in CH3CN containing 0.1 M TBAP. (a) +0.55﹔(b) +0.59﹔(c) +0.63﹔(d) +0.67﹔(e) +0.69﹔(f) +0.71 V………………………………..
Fig. 7-1-10 Spectral changes of compound c at various applied potentials in CH3CN containing 0.1 M TBAP. (a) +0.85﹔(b) +0.89﹔(c) +0.92﹔(d) +0.96﹔(e)+0.99 V…………………………………………
Fig. 7-1-11 Cyclic voltammograms of 1 mM compound d in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 7-1-12 Spectral changes of compound d at various applied potentials in CH3CN containing 0.1 M TBAP. (a) +0.50﹔(b) +0.54﹔(c) +0.58﹔(d) +0.60﹔(e) +0.61﹔(f) +0.62﹔(g) +0.63﹔(h) +0.64 V………
Fig. 7-1-13 Spectral changes of compound d at various applied potentials in CH3CN containing 0.1 M TBAP. (a) +0.70﹔(b) +0.80﹔(c) +0.84﹔(d) +0.87﹔(e) +0.8V﹔(f) +0.90﹔(g) +0.91﹔(h) +0.92﹔(i) +0.93﹔(j) +0.94﹔(k) +0.96﹔(l) +0.99﹔(m) +1.00﹔(n) +1.03﹔(o) +1.10﹔(p) +1.14 ﹔(q) +1.17﹔(r) +1.27﹔(s) +1.37 V……………………
Fig. 7-1-14 Cyclic voltammograms of 1 mM compound e in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 7-1-15 Spectral changes of compound e at various applied potentials in CH3CN containing 0.1 M TBAP. (a) +0.00﹔(b) +0.36﹔(c) +0.41﹔(d) +0.43﹔(e) +0.45﹔(f) +0.47﹔(g) +0.49﹔(h) +0.51﹔(i) +0.53﹔(j) +0.55 V………………………………..
Fig. 7-1-16 Spectral changes of compound e at various applied potentials in CH3CN containing 0.1 M TBAP. (a) +0.55﹔(b) +0.58﹔(c) +0.61﹔(d) +0.64﹔(e) +0.67﹔(e) +0.70 V………………………………..
Fig. 7-1-17 Spectral changes of compound e at various applied potentials in CH3CN containing 0.1 M TBAP. (a) +1.31﹔(b) +1.36﹔(c) +1.41﹔(d) +1.51 V………
Fig. 7-1-18 Cyclic voltammograms of 1 mM compound f in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 7-1-19 Spectral changes of compound f at various applied potentials in CH3CN containing 0.1 M TBAP. (a) +0.00﹔(b) +0.50﹔(c) +0.60﹔(d) +0.70﹔(e) +0.75………………………………………………
Fig. 7-1-20 Spectral changes of compound f at various applied potentials in CH3CN containing 0.1 M TBAP. (a) +0.80﹔(b) +0.85﹔(c) +0.90﹔(d) +0.95 V﹔(e) +1.00﹔(f) +1.05 V………………………………..
Fig. 7-1-21 Cyclic voltammograms of 1 mM compound g in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 7-1-22 Spectral changes of compound g at various applied potentials in CH3CN containing 0.1 M TBAP. (a) +0.00﹔(b) +0.50﹔(c) +0.53﹔(d) +0.54﹔(e) +0.55﹔(f) +0.56﹔(g) +0.57﹔(h) +0.58﹔(i) +0.59﹔(j) +0.60 V………………………….…….
Fig. 7-1-23 Spectral changes of compound g at various applied potentials in CH3CN containing 0.1 M TBAP. (a) +0.70﹔(b) +0.72﹔(c) +0.73﹔(d) +0.75 V………
Fig. 7-1-24 Cyclic voltammograms of 1 mM compound h in CH3CN containing 0.1 M TBAP. Scan rate = 0.1 V/s. Working electrode : GCE…………………….
Fig. 7-1-25 Spectral changes of compound h at various applied potentials in CH3CN containing 0.1 M TBAP. (a) +0.00﹔(b) +0.96﹔(c) +0.99﹔(d) +1.01﹔(e) +1.03﹔(f) +1.05﹔(g) +1.07﹔(h) +1.09﹔(i) +1.11﹔(j) +1.13﹔(k) +1.14 V……………………
Fig. 7-1-26 Spectral changes of compound h at various applied potentials in CH3CN containing 0.1 M TBAP. (a) +1.18﹔(b) +1.21﹔(c) +1.26﹔(d) +1.29﹔(e) +1.32﹔(f) +1.35﹔(g) +1.40﹔(h) +1.45 V………
表目錄
第一部分 卡唑化合物的合成與電化學研究
Table 1-1-1 Electroanalytical data for amine oxidations…..........
Table 1-2-1 Electrochemical characteristics of 3,6-disubstitued carbazoles……………………………….…………
Table 3-1-1 Half-wave potential(E1/2, V vs. Ag/AgCl) of carbazole derivatives in CH3CN. Containing 0.1M TBAP. Scan rate = 0.1 V/s…………………...……
Table 3-1-2 Absorption wavelength of the carbazole derivatives in CH3CN………………………………………….
Table 6-1-1 Half-wave potential(E1/2, V vs. Ag/AgCl) of carbazole derivatives in CH3CN. Containing 0.1M TBAP. Scan rate = 0.1V/s…………………………
Table 6-1-2 Absorption wavelength of the carbazole derivatives in CH3CN………………………………………….
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