臺灣博碩士論文加值系統

常見的CD-R或DVD-R光碟片其寫入資料前後之反射率皆是由高到低（High-to-low）的變化，在本研究中我們採用一般市面上常見的CD-R染料（Super-Green）成功地做出了資料寫入前後反射率由低到高變化（Low-to-high）的新型態DVD-R光碟片。
在實驗中，我們藉由改變染料膜厚、基板溝軌深度、反射層材料及寫入功率等參數，來探討其對於此新型態DVD-R光碟片之特性有何影響，並採用DVD碟片動態測試機、光學膜層模擬軟體、原子力顯微鏡、光學密度測試儀來驗證Low-to-high現象之發生，並探討其發生機制。由實驗中我們歸納出較適合此新型態Low-to-high光碟片的製程參數，而且得到的CNR值可達到一般DVD-R光碟片基本要求的物理特性值（CNR≧45dB）。

The commercial recordable compact disc (CD-R) and recordable digital versatile disc (DVD-R) have the high-to-low change in reflectivity before and after recording. We adopt the commercial dye (super-green) for CD-R to produce the DVD-R disc and the reflectance has the low-to-high phenomenon.
In this study, we probed into the effect of the low-to-high DVD-R by varying the optical density, writing power, reflective layer and the groove depth of the substrate. To understand the phenomenon of the low-to-high polarity, we test the experimental disc by using the DDU-1000, optical density tester (ETA-RT), atomic force microscope (AFM) and the thin film design software (TFCalc). We also generalize a better parameter for manufacturing the low-to-high DVD-R disc. And the CNR value of the disc can satisfy with the requirement of the DVD-R media (CNR≧45dB).

中文摘要 i
英文摘要 ii
誌謝 iii
目錄 iv
表目錄 vi
圖目錄 vii
第一章 緒論 1
1.1 前言 1
1.2 研究動機及目的 3
第二章 文獻回顧與理論基礎 4
2.1 光碟技術的發展沿革 4
2.1.1 CD（Compact Disc） 5
2.1.2 CD-R（CD-Recordable） 5
2.1.3 DVD-R（DVD-Recordable） 5
2.1.4 下世代DVD（Blu-ray Disc、HD-DVD） 7
2.2 光儲存染料的發展沿革 9
2.2.1 Cyanine Dye 10
2.2.2 Azo Metal Complex Dye 12
2.2.3 Phthalocyanine Dye 13
2.2.4 Phthalocyanine Dye之其他應用 16
2.3 可錄式光碟片構造 18
2.3.1 基板 19
2.3.2 記錄層 21
2.3.3 反射層 23
2.3.4 保護層 24
2.3.5 黏著層 24
2.3.6 資料結構 25
2.4 光碟記錄與讀取原理 26
2.4.1 唯讀型光碟記錄原理 27
2.4.2 可記錄型光碟記錄原理 28
2.4.3 可覆寫型光碟記錄原理 30
2.5 光碟容量增加機制 31
第三章 實驗器材與研究方法 36
3.1 實驗藥品與設備 36
3.2 實驗流程圖 38
3.3 材料選擇 39
3.4 碟片製作 39
3.5 碟片分析 41
3.5.1 動態測試 41
3.5.2 原子力顯微鏡（AFM）量測 43
3.5.3 光學分析 44
3.5.4 膜層模擬 46
第四章 結果與討論 48
4.1 Super-green染料物理性質量測 48
4.1.1 吸收光譜 48
4.1.2 熱分析 51
4.2 動態測試 51
4.2.1 溝軌深度160 nm 52
4.2.2 溝軌深度120 nm 54
4.2.3 溝軌深度30 nm 55
4.2.4 類比示波器信號圖 61
4.3 基板表面微結構觀測 63
4.3.1 光學顯微鏡（OM）量測 63
4.3.2 原子力顯微鏡（AFM）量測 64
4.4 反射層材料之影響 72
4.5 寫錄功率之影響 76
4.6 記錄層之複折射率變化 84
4.7 膜層設計軟體模擬 87
第五章 結論 93
參考文獻 95
附錄
A 實驗參數說明 101

[1]T. Iwamura, Y. Sabi, M. Oyamada, H. Watanabe, S. Tamada and S. Tamur, "Organic write once disc for a blue laser diode", International Symposium on Optical Memory 2001, Taipei, Taiwan, 2001, pp. 218-219.
[2]D. P. Gregg, "Process for making a video record disc", US Patent 3430966, 1969.
[3]K. Compaan and P. Kramer, "The Philips `VLP` System", Philips Technical Review, vol. 33, no. 7, 1973, pp. 178-180.
[4]Sony Corp., N. V. Philips, Compact Disc Digital Audio System Description, 1982.
[5]R. T. Young, D. Strand, J. Gonzalez-Hernadez and S. R. Ovshinsky, "Effects of transition-metal elements on tellurium alloys for reversible optical-data storage", J. Apply. Phys., vol. 60, no. 12, 1986, pp. 4319-4322.
[6]Y. Maeda, H. Andoh, I. Ikuta and H. Minemura, "Reversible phase-chanbe optical data storage in InSbTe alloy films", J. Appl. Phys., vol. 64, no. 4, 1988, pp. 1715-1719.
[7]M. Takenaga, N. Yamada, M. K. Nishiuchi, N. Akira, T. Ohta, S. Nakamura and T. Yamashita, "TeOx thin films for an optical disc memory", J. Appl. Phys., vol. 54, no. 9, 1983, pp. 5376-5380.
[8]K. Nishiuchi, H. Kitaura and N. Akahira, "Dual-layer optical disk with Te-O-Pd phase-change film", Jap. J. Appl. Phys., vol. 37, part. 1, N4B, 1998, pp. 2163-2167.
[9]E. Hamada, Y. Shin and T. Ishiguro, "CD-compatible write-once disc with high reflectivity", Proc. SPIE, vol. 1078, 1989, pp. 80-87.
[10]DVD specifications for read-only disc: Part 1 Physical specifications Version 1.0, 1996
[11]DVD specifications for recordable disc for authoring: Part 1 Physical specifications Version 2.0, 1998.
[12]DVD+R 4.7 Gbytes basic format specifications Version 1.0, 2002
[13]Y. Sabi, S. Tamada, T. Iwamura, M. Oyamada, F. Bruder, R. Oser, H. Berneth and K. Hassenruck, "Development of organic recording media for blue-high NA optical disc system", International Symposium on Optical Memory and Optical Storage Topical Meeting 2002, Waikoloa, Hawaii, 2002, pp. 428-429.
[14]Y. Usami, T. Kakuta, T. Ishida, H. Kubo, N. Saito and T. Watanabe, "Blue-violet laser write-once optical disc with spin-coated dye-based recording layer", Proc. SPIE, vol. 5069, 2003, pp. 182-189.
[15]D. Gu, Q. Chen, J. Shu, X. Tang, F. Gan, S. Shen, K. Liu and H. Xu, "Optical recording performance of thin films of phthalocyanine compounds", Thin Solid Films, vol. 257, 1995, pp. 88-93.
[16]A. T. Hu, H. J. Lee, J. L. Huang, J. C. Chang, S. J. Ye, D. R. Huang, D. Y. Chiang, W. Y. Liao, T. R. Jeng and J. S. Chen, "Cyanine dyes mixture as optical recording media", US Patent 5900348, 1999
[17]K. Venkataraman, The Chemistry of Synthetic Dyes, Vol.II, New York: Academic Press, 1952, pp. 1143-1186.
[18]F. M. Hamer, The Cyanine Dyes and Related Compounds, New York: Interscience Publishers, 1964, pp. 116-147.
[19]A. Hohsaka, D. Matsuura, T. Kawata and S.Yasui, "Cyanine dyes", US Patent 6743568, 2004.
[20]S. Maeda, S. Imamnra, K. Mitsuhashi and T. Tsukahara, "Optical recording medium comprising a dye-incorporated composition", US Patent 5389419, 1995.
[21]J. Griffiths, Colour and Constitution of Organic Molecules, London: Academic Press, 1976.
[22]L. Shuttleworth, C. H. Weidner and M. P. Cunningham, "Optical recording elements having recording layers containing cationic azo dyes", US Patent 5547727, 1996.
[23]S. Shibata, M. Furukawa and R. Nakashima, "Syntheses of azo dyes containing 4,5-diphenylimidazole and their evaluation as analytical reagents", Analytica Chimica Acta, vol. 81, no. 1, 1976, pp. 131-141.
[24]T. Ochiai, Y. Kurose, T. Nagao, T. Tsukahara and S. Imamura, "Azo metal chelate compound", US Patent 5532342, 1996.
[25]U. Takuya and I. Satoru, "Optical Recording Media", JP Patent 07-251567, 1995.
[26]M. Shuichi, "Optical Recording Media and data recording method", JP Patent 09-193545, 1997.
[27]O. Bekaroglu, "Phthalocyanines Containing Macrocycles", Applied Organometallic Chemistry, Vol. 10, 1996, pp. 605-622.
[28]T. Fukuda, S. Homma and N. Kobayashi, "Deformed Phthalocyanines: Synthesis and Characterization of Zinc Phthalocyanines Bearing Phenyl Substituents at the 1-, 4-, 8-, 11-, 15-, 18-, 22-, and/or 25-Positions", Chem. Eur. J., Vol. 11, No. 18, 2005, pp. 5205 – 5216.
[29]A. Braun and J. Tcherniac, "Phthalocyanines: Synthesis", Chem. Ber., vol. 40, 1907, pp. 2709.
[30]H. de Diesbach and E. von der Weid, "Quelques sels complexes des o-dinitriles avec le cuivre et la pyridine", Helvetica Chimica Acta, Vo. 10, 1927, pp. 886-888.
[31]A. G. Dandridge, H. A. E. Drescher and J. Thomas, "Improvements in and relating to the manufacture and use of colouring matters", British Pattent GB322169, 1929.
[32]R. P. Linstead, "Phthalocyanines. Part I. A new type of synthetic colouring matters", J. Chem. Soc., 1934, pp. 1016-1017.
[33]G. T. Byrne, R. P. Linstead and A. R. Lowe, "Phthalocyanines. Part II. The preparation of phthalocyanine and some metallic derivatives from o-cyanobenzamide and phthalimide", J. Chem. Soc., 1934, pp. 1017-1021.
[34]R. P. Linstead and A. R. Lowe, "Phthalocyanines. Part III. Preliminary experiments on the preparation of phthalocyanines from phthalonitrile", J. Chem. Soc., 1934, pp. 1022-1026.
[35]C. E. Dent and R. P. Linstead, "Phthalocyanines. Part IV. Copper phthalocyanines", J. Chem. Soc., 1934, pp.1027-1030.
[36]R. P. Linstead and A. R. Lowe, "Phthalocyanines. Part V. The molecular weight of magnesium phthalocyanine", J. Chem. Soc., 1934, pp.1031-1032.
[37]C. E. Dent, R. P. Linstead and A. R. Lowe, "Phthalocyanines. Part VI. The structure of the phthalocyanines", J. Chem. Soc., 1934, pp. 1033-1038.
[38]J. M. Robertson, "An X-ray study of the structure of the phthalocyanines. Part I. The metal-free, nickel, copper, and platinum compounds", J. Chem. Soc., 1935, 615-620.
[39]J. M. Robertson, "An X-ray study of the phthalocyanines. Part II. Quantitative structure determination of the metal-free compound", J. Chem. Soc., 1936, pp. 1195-1209.
[40]J. M. Robertson and I. Woodward, "An X-ray study of the phthalocyanines. Part III. Quantitative structure determination of nickel phthalocyanine", J. Chem. Soc., 1937, pp. 219-232.
[41]H. Wolleb, "Process for the preparation of brominated, alkoxy-substituted metal phthalocyanines", US Patent 5594128, 1997.
[42]H. Wolleb, H. Preiswerk, B. Schmidhalter and H. Spahni, "Phthalocyanines substituted by phosphorus-containing groups", US Patent 5641879, 1997.
[43]H. Wolleb, "Mixtures of isomeric substituted phthalocyanines, and process for their preparation", US Patent 5663326, 1997.
[44]M. J. Cook, "Phthalocyanine thin films", Pure Appl. Chem., Vol. 71, No. 11, 1999, pp. 2145-2151.
[45]F. H. Moser and A. L. Thomas, The Phthalocyanines: Manufacture and Applications, Boca Raton: CRC Press, 1983.
[46]T. Y. Zhang and C. L. Zhou, "Properties of Copper Phthalocyanine Blue (C.I. Pigment Blue 15:3) Treated with Poly(ethylene glycol)s", Dyes and Pigments, Vol. 35, No. 2, 1997, pp. 123-130.
[47]M. Kimura, T. Nishigaki, T. Koyama, K. Hanabusa and H. Shirai, "Functional metallomacrocycles and their polymers, Part 34. Catalytic oxygenation of cyclohexene by water-soluble polymer containing manganese phthalocyanine complex", Reactive and Functional Polymers, Vol. 29, No. 2, 1996, pp. 85-90.
[48]R. F. Parton, P. E. Neys, P. A. Jacobs, R. C. Sosa and P. G. Rouxhet, "Iron-Phthalocyanine Immobilized on Activated Carbon Black: A Selective Catalyst for Alkane Oxidation", Journal of Catalysis, Vol. 164, Iss. 2, 1996, pp. 341-346.
[49]P. Gregory, High-technology Applications of Organic Colorants, New York: Plenum Press, 1991, Chap. 2
[50]S. A. Van Slyke, C. H. Chen and C. W. Tang, "Organic electroluminescent devices with improved stability", Appl. Phys. Lett., Vol. 69, Iss. 15, 1996, pp. 2160-2162.
[51]C. W. Tang and S. A. Van Slyke, "Organic electroluminescent diodes", Appl. Phys. Lett., Vol. 51, Iss. 12, 1987, pp. 913-915.
[52]C. W. Tang, S. A. Van Slyke and C. H. Chen, "Electroluminescece of doped organic thin films", J. Appl. Phys., Vol. 65, Iss. 9, 1989, pp. 3610-3616.
[53]C. H. Liao, M. T. Lee and C. H. Tsai, "Highly efficient blue organic light-emitting devices incorporatinga composite hole transport layer", Appl. Phys. Lett., Vol. 86, Iss. 20, 2005, pp. 203507.
[54]F. J. Kampas, K. Yamashita and J. Fajet, "Photoelectrochemical properties of metalloporphyrins", Nature, Vol. 284, 1980, pp. 40-42.
[55]G. A. Chamberlain, P. J. Cooney and S. Dennison, "Photovoltaic properties of merocyanine solid-state photocells", Nature, Vol. 289, 1981, pp. 45-47.
[56]T. Kume, S. Hayashi and K. Yamamoto, "Enhancement of photoelectric conversion efficiency in copper phthalocyanine solar cell by surface plasmon excitation", Jpn. J. Appl. Phys., Vol. 32, No. 8, 1993, pp. 3486-3492.
[57]T. Kume, S. Hayashi, H. Ohkuma1 and K. Yamamoto, "Enhancement of photoelectric conversion efficiency in copper phthalocyanine solar cell: white light excitation of surface plasmon polaritons ", Jpn. J. Appl. Phys., Vol. 34, No. 12A, 1995, pp. 6448-6451.
[58]K. Murata, S. Ito, K. Takahashi and B. M. Hoffman, "Long-lived excited state of C60 in C60/phthalocyanine heterojunction solar cell", Appl. Phys. Lett., Vol. 68, Iss. 3, 1996, pp. 427-429.
[59]B. Z. Zmudzka, A. G. Strickland, J. Z. Beer and E. Ben-Hur, "Photosensitized decontamination of blood with the silicon phthalocyanine Pc4: No activation of the human immunodeficiebcy promoter", Photochem. Photobiol, Vol. 65, Iss. 3, 1997, pp. 461-464.
[60]C. Z. Gu, L.Y. Sun, T. Zhang, T. J. Li and X. Zhang, "High-sensitivity phthalocyanine LB film gas sensor based on field effect transistors", Thin Solid Films, Vol. 329, 1998, pp. 383-386.
[61]J. C. Hsieh, C. J. Liu and Y. H. Ju, "Response characteristics of lead phthalocyanine gas sensor: effects of film thickness and crystal morphology", Thin Solid Films, Vol. 322, 1998, pp. 98-103.
[62]A. K. Ray, A. V. Nabok, A. K. Hassan, J. Silver, P. Marsh and T. Richardson, "Optical studies on composite Langmuir-Blodgett films containing ytterbium bis-phthalocyanine", Philosophical Magazine B, Vol. 79, No. 7, 1999, pp. 1005-1019.
[63]C. J. Liu, J. C. Hsieh and Y. H. Ju, "Response characteristics of lead phthalocyanine gas sensor: Effect of operating temperature and postdeposition annealing", Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 14, Iss. 3, 1996, pp. 753-756.
[64]R. O. Loutfy, A. M. Hor, C. K. Hsiao, G. Baranyi and P. Kazmaier, "Organic photoconductive materials", Pure & Appl. Chem., Vol. 60, No. 7, 1988, pp. 1047-1054.
[65]W. Y. Liao, M. C. Li, A. T. Hu and S. Lee, "Quencher-free optical recording materials: Photofading experimental and antiphotofading mechanism studies", Jpn. J. Appl. Phys.. Vol. 42, No. 6A, 2003, pp. 3447-3451.
[66]Y. Suzuki, M. Horie, Y. Okamoto, Y. Kurose and S. Maeda, "Thermal and Optical Properties of Metal Azo Dyes for Digital Video Disc-Recordable Discs", Jpn. J. Appl. Phys., Vol. 37, No. 4B, 1998, pp. 2084-2088.
[67]N. Takahashi, H. Sato, H. Osawa, K. Nagai, H. Isobe and I. Kasuga, "Digital video disk/Compact disk (DVD/CD)-Compatible pickup head with dual lens rotating actuator", Jpn. J. Appl. Phys.,Vol. 36, No. 1B, 1997, pp. 467-473.
[68]DVD specifications for recordable disc for general: Part 1 Physical specifications Version 2.0, May 2000.
[69]S. Q. Sun, P. Chen, D. S. Zheng, O. Tsuneki and H. Masaaki, "Optical and thermal properties of some indolenine cyanine dyes used as optical recording materials", Proc. SPIE, vol. 3526, 1998, pp. 11-16.
[70]H. Nishiwaka, K. Kitono, H. Nakajima, E. Muramatsu, S. Taniguchi, A. Inoue, F. Yokogawa, M. Horie, K. Kiyono, T. Miyazawa and Y. Kurose, "Organic dye 25GB write-once disc with in-groove structure", Jpn. J. Appl. Phys.,Vol. 45, No. 2B, 2006, pp. 1452-1455.
[71]S. Q. Sun, P. Chen, D. S. Zheng, O. Tsuneki and H. Masaaki, "Spectroscopic and optical properties of cyanine dye film used in a digital versatile disc recordable (DVD-R)", The imaging science journal, vol. 46, 1998, pp. 99-102.