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研究生:林志軒
研究生(外文):Lin, Chih-Hsuan
論文名稱:鐵乙炔苯胺紫質之電化學、電聚合反應及其應用
論文名稱(外文):Electrochemistry and Application of Electropolymerized Iron 4-Aniline-Ethynyl Porphyrins
指導教授:林敬堯林敬堯引用關係
指導教授(外文):Lin, Ching-Yao
學位類別:碩士
校院名稱:國立暨南國際大學
系所名稱:應用化學系
學門:自然科學學門
學類:化學學類
論文種類:學術論文
論文出版年:2007
畢業學年度:95
語文別:中文
論文頁數:65
中文關鍵詞:鐵金屬紫質電化學電聚合一氧化氮電催化
外文關鍵詞:Ironporphyrinelectrochemistryelectropolymerizenitric oxideelectrocatalysis
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本論文主要是合成 Iron(III) bis(4-aniline-ethynyl)biphenylporphyrin chloride 以及 iron(III) mono(4-aniline-ethynyl)biphenylporphyrin chloride,分別簡稱為 Cl-Fe(4-AE)2BPP與 Cl-Fe(4-AE)BPP,並且研究它們的電聚合反應。電化學的實驗結果,Cl-Fe(4-AE)2BPP 及 Cl-Fe(4-AE)BPP 溶在 CH2Cl2 中可以在Pt、GCE與Au電極表面進行電聚合反應。所形成的電聚合膜,其氧化還原性質與原本紫質溶於溶液中的基本性質沒有太大的差異。
接著我們利用 Cl-Fe(4-AE)2BPP 和 Cl-Fe(4-AE)BPP 的電聚合膜修飾 GCE電極,在水溶液中催化偵測一氧化氮 (NO)。將 NaNO2 溶在酸性溶液中可以得到一氧化氮(NO)。兩種修飾電極在含有 NaNO2的酸性水溶液中,可以偵測到有增強的 NO 還原催化電流訊號。Cl-Fe(4-AE)2BPP形成的修飾電極偵測效果稍優於 Cl-Fe(4-AE)BPP的修飾電極。兩種修飾電極皆具有不錯的再現性。
Iron(III) bis(4-aniline-ethynyl)biphenylporphyrin chloride and iron(III)
mono(4-aniline-ethynyl)bisphenylporphyrin chloride [abbreviated as Cl-Fe(4-AE)2BPP and Cl-Fe(4-AE)BPP] are synthesized and their electropolymerization reactions are studied. Electrochemical experiments show that Cl-Fe(4-AE)2BPP and Cl-Fe(4-AE)BPP can be electropolymerized onto Pt, GCE and Au electrodes in CH2Cl2 solutions. The redox properties of the electropolymerized porphyrin films are not significantly changed.
In addition, Cl-Fe(4-AE)2BPP and Cl-Fe(4-AE)BPP are electropolymerized onto GCE to catalyze nitric oxide in the aqueous solutions. Upon applying two modified electrodes in NaNO2 solution, the enhancement reductive currents of the nitric oxide are detected. The modified electrodes of Cl-Fe(4-AE)2BPP has better current-enhancement than Cl-Fe(4-AE)BPP ones on detecting nitric oxide in aqueous solutions. Both modified electrodes of Cl-Fe(4-AE)2BPP and Cl-Fe(4-AE)BPP have good reproducibility.
目錄
謝誌 i
中文摘要 ii
英文摘要 iii
目錄 iv
圖表目錄 v
一、簡介 1
1-1 紫質介紹及其重要性 1
1-2 紫質電聚合化學的介紹 3
1-3 研究方向以及偵測 nitric oxide (NO) 的動機 10
二、實驗部分 16
2-1 儀器設備 16
2-2 藥品 17
2-3 合成步驟 18
2-4 化合物鑑定結果 (Elemental Analysis、Mass、NMR) 18
2-4-1 Cl-Fe(4-AE)2BPP 鑑定結果 18
2-4-2 Cl-Fe(4-AE)BPP 鑑定結果 18
三、結果與討論
第一部分 Cl-Fe(4-AE)2BPP 及 Cl-Fe(4-AE)BPP 的電化學及
光譜基本性質探討 21
3-1-1 電化學 (Electrochemistry) 22
3-1-2 UV-Vis 光譜 34
3-1-3 電聚合膜活性的探討 35
第二部分 Cl-Fe(4-AE)2BPP 及 Cl-Fe(4-AE)BPP 電聚合膜對 nitric oxide (NO) 的偵測 38
3-2-1 Cl-Fe(4-AE)2BPP、Cl-Fe(4-AE)BPP 催化NO之電聚合條件選擇 39
3-2-2 Cl-Fe(4-AE)2BPP 部分 39
3-2-2-1 不同 scan rate 對於偵測 NO 的影響 40
3-2-2-2 不同pH值對偵測 NO 的影響 41
3-2-2-3 不同圈數的膜對偵測 NO 的影響 42
3-2-2-4 NaNO2 濃度對偵測 NO 的影響 43
3-2-3 Cl-Fe(4-AE)BPP 部分 44
3-2-3-1 不同 scan rate 對於偵測 NO 的影響 45
3-2-3-2 不同pH值對偵測 NO 的影響 46
3-2-3-3 不同圈數的膜對偵測 NO 的影響 47
3-2-3-4 NaNO2 濃度對偵測 NO 的影響 48
3-2-4 電聚合膜的電流增加倍數 (enhancement) 以及再現性 49
四、結論 52
參考文獻 53
附錄一 58
附錄二 59
附錄三 65
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