臺灣博碩士論文加值系統

本論文主要探討具有雙吡啶醯胺官能基的配位子與金屬的配位化學、結構學和放光性質探討。首先，我們合成兩種具有不同spacer的配位基，分別為N,N''-bis(pyridylcarbonyl)-4,4''-diaminodiphenyl ether (papo)與N,N''-bis(pyridylcarbonyl)-4,4''-diaminodiphenyl thioether (paps)將配位基分別與ZnX2 (X= Cl-, Br-, I-, NO3-, ClO4-)、HgI2和CuI進行反應，我們除了觀察不同陰離子對晶體結構在空間排列上的效應外，也探討不同的養晶溶劑對結構的影響，得到一系列不同的配位高分子化合物。其中有單晶結構的化合物為{[Zn(papo)Cl2]

Crystal engineering has recently been one of the major research topics to understand the intermolecular interactions and packing principles in molecular crystals, which may be helpful in generating the deliberate design of novel materials with targeted structures and properties. Thus, two dipyridyl-amide based ligands, N,N''-bis(pyridylcarbonyl)-4,4''-diaminodiphenyl ether (papo) and N,N''-bis(pyridylcarbonyl)-4,4''-diaminodiphenyl thioether (paps) have been prepared and chosen for the crystal-engineering purpose in this thesis

The coordination polymers of {[Zn(papo)Cl2]

總目錄
圖目錄.......................................................................................................................IV
表目錄....................................................................................................................VIII
附圖目錄..................................................................................................................IX
附表目錄....................................................................................................................X
中文摘要..................................................................................................................XI
英文摘要...............................................................................................................XIII
Self Assembly of Luminescent Transition-Metal (Zn2+, Hg2+, Cu+, and Re+) Complexes Containing N,N''-Bis(pyridylcarbonyl)-4,4''-diamino
diphenyl Ether (papo) and N,N''-Bis(pyridylcarbonyl)-4,4''-diamino
diphenyl Thioether (paps)
第一章 緒論
1-1 配位高分子........................................................................................................1
§1-1-1緒論.....................................................................................................................1
§1-1-2晶體工程.............................................................................................................3
§1-1-3有機-無機配位高分子.......................................................................................5
§1-1-4配位高分子的應用...........................................................................................18
1-2 超分子...............................................................................................................24
§1-2-1緒論...................................................................................................................24
§1-2-2超分子結構的設計...........................................................................................27
§1-2-3超分子化合物的應用.......................................................................................33
1-3 研究動機..........................................................................................................38
第二章 實驗部分..................................................................................................39
§2-1藥品與溶劑……..................................................................................................39
§2-2物理方法鑑定......................................................................................................41
§2-3合成圖..................................................................................................................43
§2-4實驗步驟..............................................................................................................45
§2-4-1合成papo. ........................................................................................................45
§2-4-2合成paps ..........................................................................................................46
§2-4-3合成{[Zn(papo)Cl2]

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