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研究生:張鈺杰
研究生(外文):Yu-Chieh Chang
論文名稱:含2-胺基-5-鹵素嘧啶配位基與一價銅化合物之合成與結構探討
論文名稱(外文):Synthesis and structures of Cu(I) complexes containing 2-amino-5-halopyrimidine
指導教授:陳志德
指導教授(外文):Jhy-Der Chen
學位類別:碩士
校院名稱:中原大學
系所名稱:化學研究所
學門:自然科學學門
學類:化學學類
論文種類:學術論文
論文出版年:2008
畢業學年度:96
語文別:英文
論文頁數:103
中文關鍵詞:嘧啶一價銅鹵素
外文關鍵詞:Cu(I)2-amino-5-halopyrimidine
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利用過渡金屬鹽類CuCl和CuBr與配位基2-胺基-5-鹵素嘧啶配位基pymX (X = I, Br, Cl) ,分別與HCl以及HBr水溶液反應,可得到{[CuCl2(HpymI)] • H2O}n, 1,{[CuBr2(HpymI)] • H2O}n, 2,{[CuCl2(HpymBr)] • H2O}n, 3,{[CuBr2(HpymBr)] • H2O}n, 4 和 {[CuCl2(HpymCl)] • H2O}n, 5 。化合物[(HpymCl)CuBr3(HpymCl)], 6, 為利用CuBr 與pymCl在甲醇溶液中再加入HBr反應而得到,以上這些結構已經利用X-ray鑑定。

化合物1 - 5 為利用鹵素進行橋接的鋸齒鏈化合物,再利用X---X的鹵素作用力以及N-H---X,N-H---O以及O-H---X氫鍵作用力形成超分子結構。而化合物6則是單核的金屬錯化合物,再利用N-H---Br以及C-H---Br氫鍵作用力形成超分子鏈。而這些超分子鏈則利用Br---Cl 鹵素作用力以及C-H---Br氫鍵作用力連接並形成3-D的超分子結構。
A series of copper(I) complexes {[CuCl2(HpymI)] • H2O}n (pymI = 2-Aimo-5-iodopyrimidine), 1, {[CuBr2(HpymI)] • H2O}n, 2 , {[CuCl2(HpymBr)] • H2O}n (pymBr = 2-Aimo-5-boropyrimidine), 3, {[CuBr2(HpymBr)] • H2O}n, 4, and {[CuCl2(HpymCl)] • H2O}n (pymCl = 2-Aimo-5-choropyrimidine), 5 have been prepared by the reactions of CuCl and CuBr with 2-Amino-5-halopyrimidine in solution of HCl and HBr, respectively. [(HpymCl)CuBr3(HpymCl)], 6, was prepared by the reaction of CuBr and pymCl in solution of HBr. These complexes have been structurally characterized by X-ray crystallography.
In complexes 1 - 5, the zigzag chains are interacted through X---X (X = Cl, Br, I) interaction and N-H---X, N-H---O and O-H---X hydrogen bonds. Complex 6 is mononuclear, and the molecules are interacted through Br---Cl interaction, C-H---Br and C-H---Br hydrogen bonds.
摘要…………………………….………………………………………… I
Abstract………………………………………………………………...... II
謝誌………………………………………………………………........... III
Contents…………………………………………………………….….... IV
Table contents………………………………………………………….....V
Figure contents………………………………………………………….VII
Appendix table contents……..……………………………………… XI
Introduction……………………………………………………………… 1
Experimental……….…………………………………………………… 10
X-ray crystallography………………………………………………… 13
Results and discussions……………………………………………… 26
Conclusions……………………………………………………………… 64
References……………………………………………………………… 66
Appendix………………………………………………………………… 70
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